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Natural Indigo Dyeing by Using Glucose Reduction

포도당 환원을 이용한 천연 인디고 염색

  • Shin, Youn-Sook (Department of Clothing and Textiles / Human Ecology Research Institute, Chonnam National University) ;
  • Cho, A-Rang (Department of Clothing and Textiles / Human Ecology Research Institute, Chonnam National University) ;
  • Yoo, Dong-Il (School of Applied Chemical Engineering, Chonnam National University)
  • 신윤숙 (전남대학교 의류학과 / 생활과학연구소) ;
  • 조아랑 (전남대학교 의류학과 / 생활과학연구소) ;
  • 류동일 (전남대학교 응용화학공학부)
  • Published : 2009.06.27

Abstract

Dyeing process of the natural indigo powder onto ramie and silk fabrics was investigated by using glucose and calcium hydroxide as a reducing system. Effect of reduction and dyeing conditions such as temperature and time of reduction/dyeing, and concentrations of glucose and calcium hydroxide on the dyeing process were explored. Indigo powder was obtained by drying the conventional niram paste in an oven at $50^{\circ}C$. Color strength of the dyed fabrics was evaluated by K/S value measured at the wavelength of maximum absorption(${\lamda}$max). Munsell color coordinates(H V/C) were used to compare fabric colors of ramie and silk. Ramie fabric showed purple-blue color for all the temperature and time. On the contrary, silk fabric showed wide range of color including brown, brown-green, green at the different temperature. With the increase of K/S value, the coordinate of value(lightness) decreased for both of ramie and silk fabrics. The coordinate of hue(shade) changed drastically with the increase of K/S value for silk fabric, compared with that of ramie fabric which showed nearly constant value at the whole range of K/S value. Optimum concentrations of calcium hydroxide were for 6 g/L for ramie and 4 g/L for silk at $60^{\circ}C$ and 50 min. K/S value increased with the indigo concentration. Maximum K/S value was shown at $10{\sim}12$ g/L of glucose concentration. For both of ramie and silk fabrics, the colorfastness of washing and light was lower than that of rubbing. All the colorfastness values were improved with the increase of color strength.

Keywords

References

  1. 이종남, '우리가 정말 알아야 할 천연 염색', 현암사, 서울, 2004
  2. 조경래, '규합총서에 나타난 전통염색법해설', 한국학술정보(주), 파주, 2007
  3. A. Roessler, D. Crettenand, O. Dossenbach, W. Marte, and P. Rys, Direct electrochemical reduction of indigo, Electrochimica Acta, 47, 1989-1995(2002) https://doi.org/10.1016/S0013-4686(02)00028-2
  4. A. Roessler, O. Dossenbach, and P. Rys, Electrocatalytic Hydrogenation of Indigo; Process Optimization and Scale-Up in a Flow Cell, J. Electrochem. Soc., 150(1), D1-D5(2003) https://doi.org/10.1149/1.1521757
  5. A. Vuorema, P. John, M. Keskitalo, M. A. Kulandainathan, and F. Marken, Electrochemical and sonoelectrochemical monitoring of indigo reduction by glucose, Dyes and Pigments, 76, 542-549(2008) https://doi.org/10.1016/j.dyepig.2006.06.044
  6. K. G. Stoker, D. T. Cooke, and D. J. Hill, An Improved Method for the Large-Scale Processing of Woad(Isatis tinctoria) for Possible Commercial Production of Woad Indigo, J. Agric. Engng. Res., 71, 315-320(1998) https://doi.org/10.1006/jaer.1998.0329
  7. T. Bechtold, A. Turcanu, S. Geissler, and E. Gangberger, Process balance and product quality in the production of natural indigo from Polygonum tinctorium Ait. applying lowtechnology methods, Biores. Technol., 81, 171-177(2002) https://doi.org/10.1016/S0960-8524(01)00146-8
  8. P. Garcia-Macias and P. John, Formation of Natural Indigo Derived from Woad (Isatis tinctoria L.) in Relation to Product Purity, J. Agric. Food Chem., 52, 7891-7896(2004) https://doi.org/10.1021/jf0486803
  9. S. K. Nicholson and P. John, The mechanism of bacterial indigo reduction, Appl. Microbial. Biotechnol., 68, 117-123(2005) https://doi.org/10.1007/s00253-004-1839-4
  10. A. N. Padden, V. M. Dillon, J. Edmonds, M. D. Collins, N. Alvarez and P. John, An indigo-reducing moderate thermophile from a woad vat, Clostridium isatidis sp. nov., Int. J. Syst. Bact., 49, 1025-1031(1999) https://doi.org/10.1099/00207713-49-3-1025
  11. R. S. Blackburn and A. Harvey, Green Chemistry Methods in Sulfur Dyeing:Application of Various Reducing d-Sugars and Analysis of Importance of Optimum Redox Potential, Environ. Sci. Technol., 138 (14), 4034-4039(2004) https://doi.org/10.1021/es0498484
  12. H. K. Routte (Ed.), 'Redox potential, Reducing agents, Encyclopedia of Textile Finishing', Springer-Verlag, Berlin, Vol. 3, pp.1868-1867, 2001
  13. Y. Shin, A. Cho, and D. I. Yoo, Color Character in Natural Indigo Dyeing: the Effect of Reducing Agent, Proceedings of KSDF 20th Anniversary International Conference of on Dyeing and Finishing, pp.126-127, EXCO, Daegu(Korea), March 13, 2009
  14. J. Y. Kang and H. S. Ryu, Natural Indigo Dyeing on Wool Fibers (I), J. Kor. Soc.Dyers and Finishers, 13(4), 15-22(2001)
  15. Y. J. Jung, M. H. Lee, H. W. Choi, and E. P. Lee, A Study on the Dyeing Properties of Natural Indigo Complex Powder and Synthetic Indigo with Natural Fiber, J. Kor. Soc. Dyers and Finishers, 12(3), 16-24(2000)
  16. I. M. Chung and S. O. Woo, Effect of Reducing Agent, Sodium Hydrosulfite on the Natural Indigo Dyeing of Silk Fabric, Korean J. Seric. Sci., 44(2), 93-98(2002)