Transactions of the Korean hydrogen and new energy society (한국수소및신에너지학회논문집)

The Korean Hydrogen and New Energy Society (한국수소및신에너지학회)
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Study of EfficienCY of Hydrogen Rich Biodiesel as Reductant for HC-SCR over $Al_2O_3$ Supported Ag Catalyst

$Ag/Al_2O_3$ 촉매하의 HC-SCR에서 환원제로서 수소 풍부 바이오디젤의 반응 특성 연구

  • Published : 2009.06.30
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Abstract

$Ag/Al_2O_3$ 촉매하에 디젤 엔진에서 배출되는 NOx를 정화하기 위하여, 수소가 풍부한 바이오디젤을 환원제로 사용하였다. Ag 전구체 함침과정에서 촉매기공이 부분적으로 폐쇄되는 것을 BET 실험을 통하여 관찰하였다. 2% $Ag/Al_2O_3$ 촉매의 형상과 조성은 산처리 과정을 거치더라도 변화하지 않는 것을 SEM과 EDXS 분석으로부터 확인하였다. $Ag/Al_2O_3$ 촉매 표면에서 생성되는 -NCO 와 -CN을 in-Situ DRIFT 방법을 사용하여 관찰하여 HC-SCR에서의 NOx 제거 반응구조를 확인하였다.

Keywords

References

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