Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Thermal and Mechanical Properties of the PVA/Collagen Blend Fibers

PVA/콜라겐 블렌드 섬유의 열적 및 기계적 특성

  • Park, Jac-Ky (Department of Textile Material Engineering, Chonbuk National University) ;
  • Kim, Dong-Hwan (Department of Textile Material Engineering, Chonbuk National University) ;
  • Chung, Yong-Sik (Department of Textile Material Engineering, Chonbuk National University) ;
  • Kim, Hwan-Chul (Department of Textile Material Engineering, Chonbuk National University)
  • 박제기 (전북대학교 섬유소재시스템공학과) ;
  • 김동환 (전북대학교 섬유소재시스템공학과) ;
  • 정용식 (전북대학교 섬유소재시스템공학과) ;
  • 김환철 (전북대학교 섬유소재시스템공학과)
  • Published : 2009.08.31
⟨ Previous Next ⟩

Abstract

PVA/collagen blend fibers were produced by air-gap spinning method, and were successfully spun to blend fiber. Maximum collagen content to produce the fiber was 30%, above which the fiber was found to be broken in the drawing process. Thermal and mechanical properties of the fibers were investigated by changing blend ratios of the PVA to collagen. Melting point of PVA was decreased with the increase of the amount of collagen. The strength and the elongation of the fiber were also decreased due to the inhomogeneous structure of the blend fiber. Hot water resistance was endowed by the heat treatment after drawing process, and when the fiber was treated at $230^{\circ}C$ for 10 minutes, it was neither swelled nor broken in boiling water.

Keywords

References

  1. I. Sakurada, 'Polyvinyl Alcohol Fibers', Marcel Dekker Inc., New York and Basel, 1985, pp.113-115
  2. 최수영, '폴리비닐알콜 섬유의 이해와 제조 기술', 섬유기술과 산업, 2002, 6, 83-95
  3. B. C. Kim, S. G. Kim, B. G. Min, C. J. Lee, and T. W. Son, 'A Study on the Polyvinyl Alcohol Fiber(I)', J Korean Fiber Soc, 1994, 31, 531-536
  4. H. Fujiwara, M. Shibayama, J. H. Chen, and S. Nomura, 'Preparation of High-strength Poly(vinyl Alcohol) Fibers by Crosslinking Wet Spinning', J Appl Polym Sci, 1989, 37, 1403-1414 https://doi.org/10.1002/app.1989.070370522
  5. K. S. Hwang, C. A. Lin, and C. H. Lin, 'Preparation of High-strength and High-modulus Poly(Vinyl Alcohol) Fibers by Crosslinking Wet Spinning/Multistep Drawing Method', J Appl Polym Sci, 1994, 52, 1181-1189 https://doi.org/10.1002/app.1994.070520902
  6. W. I. Cha, S. H. Hyon, and Y. Ikada, 'Gel Spinning of Poly(vinyl Alcohol) from Dimethyl Sulfoxide/Water Mixture', J Polym Sci, Part B, Polym Phys, 1994, 32, 297-304 https://doi.org/10.1002/polb.1994.090320211
  7. S. Nayar and A. Sinha， 'Systematic Evolution of a Porous Hydroxyapatite-poly(vinyl alcohol)-gelatin Composite', Colloids and Surfaces B: Biointerfaces, 2004, 35, 29-32 https://doi.org/10.1016/j.colsurfb.2004.01.013
  8. C. H. Park and T. W. Park, 'Emulsion Graft Copolymerization of Methyl Methacrylate onto Gelatin(II)', J Korean Fiber Soc, 1987, 24, 563-569
  9. R. A. Carvalho， T. M. C. Maria， I. C. F. Moraes, P. V. A. Bergo, E. S. Kamimura, A. M. Q. B. Habitante, and P. J. A. Sorbral, 'Study of Some Physical Properties of Biodegradable Films Based on Blends of Gelatin and Poly(vinyl alcohol Using a Response-surface Methodology', Mater Sci Eng C, 2009, 29, 485-491 https://doi.org/10.1016/j.msec.2008.08.030
  10. B. Sarti and M. Scandola, 'Viscoelastic and Thermal Properties of Collagen/poly(vinyl alcohol) Blends', Biomaterial, 1995, 16, 785-792 https://doi.org/10.1016/0142-9612(95)99641-X
  11. H. Fujiwara, M. Shibayama, J. H. Chen, and S. Nomura, 'reparation of High-strength Poly(vinyl alcohol) Fibers by Crosslinking Wet Spinning', J Appl Polym Sci, 1989, 37, 1403-1414 https://doi.org/10.1002/app.1989.070370522
  12. L. Xiao, W. Xiao, Q. Liu, and X. Xu, 'Studies on Fibers Spun from Poly(vinyl alcohol-b-acrylonitrile) Emulsions Prepared by Ultrasonic Technique', J Appl Polym Sci, 2001, 79, 979-988 https://doi.org/10.1002/app.1180
  13. I. Sakurada, 'Polyvinyl Alcohol Fibers', Marcel Dekker Inc., New York and Basel, 1985, 187-229
  14. M. Shibayama, M. Sato, Y. Kimura, H. Fujiwara, and S. Nomura, '$^{11}B$ N.M.R. Study on the Reaction of Poly(vinyl Alcohol) with Boric Acid', Polymer, 1988, 29, 336-340 https://doi.org/10.1016/0032-3861(88)90343-6