DOI QR코드

DOI QR Code

Preparation of mesoporous carbon using ion exchange

이온 교환을 이용한 메조기공 활성탄의 제조

  • Lee, Jong-Dae (Department of Chemical Engineering College of Engineering, Chungbuk National University) ;
  • Kang, Chae-Yoen (Department of Chemical Engineering College of Engineering, Chungbuk National University) ;
  • Kang, Min-Goo (Department of Chemical Engineering College of Engineering, Chungbuk National University)
  • 이종대 (충북대학교 화학공학과) ;
  • 강채연 (충북대학교 화학공학과) ;
  • 강민구 (충북대학교 화학공학과)
  • Published : 2009.09.30

Abstract

Recently, much interest on mesoporous carbon has been shown in their use for both hydrogen and methane storage and as an electrode material for electric double layer capacitors. The mesoporous active carbons by ion exchange were prepared and physical properties such as specific surface area and pore structure of active carbon were investigated using BET. In this study, active carbons with mesopore fraction of $60{\sim}90%$ were obtained. The Fe/Ca-exchanged active carbons showed a greater mesoporosity compared with Fe-exchanged carbons. The mean mesopore size in active carbons using Ca- and Fe-exchange was about $5.5{\sim}6.0nm$ and was approximately 1nm higher than that of the Fe-exchanged active carbon.

Keywords

References

  1. T. Kyotani, Control of pore structure III carbon, Carbon, 38(2), 269 (2000) https://doi.org/10.1016/S0008-6223(99)00142-6
  2. F. Rodriguez-reinoso, The role of carbon materials in heterogeneous catalysis, Carbon, 36(3), 159 (1998) https://doi.org/10.1016/S0008-6223(97)00173-5
  3. J S. Yu, S. Kang, S. B. Yoon and G. Chai, Fabrication of ordered uniform porous carbon networks and their application to a catalyst supporter, J. Am Chem Soc., 124(32), 9382 (2002) https://doi.org/10.1021/ja0203972
  4. C. Morenocastilla, M. A. Ferrogarcia, J P. joly, I. Bautistatoledo, F. Carrascomarin and J. Riverautrilla, Activated carbon surface modifications by nitric-acid, hydrogen-peroxide, and ammonium peroxydisulfate treatments, Langmuir, 11(11), 4386 (1995) https://doi.org/10.1021/la00011a035
  5. G. Gryglewicz, J. Machnikowski, E. Lorenc-Grabowska, G. Lota and E. Frackowiak, Effect of pore size distribution of coal-based activated carbons on double layer capacitance, Electrochimiro Acta, 50(5), 1197 (2005) https://doi.org/10.1016/j.electacta.2004.07.045
  6. O. Barbieri, M. Hahn, A. Herzog and R. Katz, Capacitance limits of high surface area activated carbons for double layer capacitors, Carbon, 43(6), 1303 (2005) https://doi.org/10.1016/j.carbon.2005.01.001
  7. J. Ozaki, N. Endo, W. Ohizumi, K. Igarashi, M. Nakahara, A. Oya, S. Yoshida and T. Iizuka, Novel preparation method for the production of mesoporous carbon fiber from a polymer blend, Carbon, 35(7), 1031 (1997) https://doi.org/10.1016/S0008-6223(97)89878-8
  8. Z. Liu, L. Ling, W. Qiao and L. Liu, Effect of hydrogen on the mesopore development of pitch-based spherical activated carbon containing iron during activation by steam, Carbon, 37(12), 2063 (1999) https://doi.org/10.1016/S0008-6223(99)00058-5
  9. C. Lin and J. A. Ritter, Effect of synthesis pH on the structure of carbon xerogels, Carbon, 35(9), 1271 (1997) https://doi.org/10.1016/S0008-6223(97)00069-9
  10. L. Li, H. Song and X. Chen, Ordered mesoporous carbonization silicaltriblock carbons from the of sulfuric-add-treated copolymer/sucrose composites, Microporous and Mesoporous Materials, 94(1-3), 9 (2006) https://doi.org/10.1016/j.micromeso.2006.03.021
  11. K. Kinoshita, Carbon : Electrochemical and physicochemical properies, Wiley, 465 (1988)
  12. E. Lorenc-Grabowska, G. Gryglewicz and S. Gryglewicz, Development of mesoporosity in activated carbons via coal modification using Ca- and Fe-exchange, Microporous and Mesoporous Materials, 76(1-3), 193 (2004) https://doi.org/10.1016/j.micromeso.2004.08.012
  13. I. Sutherland, E. Sheng, R. H. Bradley and P. K. Freakley, Effects of orone oxidation on carbon black surfaces, J. Mater. Sci., 31(21), 5651 (1996) https://doi.org/10.1007/BF01160810
  14. K. S. W. Sing, D. H. Everett, R. Haul, L. Moscou, R. A. Pierotti, J. Rouquerol and T. Siemieniewska, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure and Applied Chem, 54(11), 2201 (1982) https://doi.org/10.1351/pac198254112201
  15. H. Li, H. Xi, S. Zhu, A. Wen and R. Wang, Preparation, structural characterizatioin, and electrochemical properties of chemically modified mesoporous carbon, Microporous and Mesoporous Materials, 96(1-3), 357(2006) https://doi.org/10.1016/j.micromeso.2006.07.021
  16. P. Karandikar, K. R. Patil, A. Mitra, B. Kakade and A. J. Chandwadkar, Synthesis and characterization of rnesoporous carbon through inexpensive mesoporous silica as template, Microporous and Mesoporous Materials, 98(1 -3), 189 (2007) https://doi.org/10.1016/j.micromeso.2006.09.003
  17. A. Tomita, Y. Yuhki, K. Higashiyama, T. Takarada and Y. Tamai, Nenryo Kyokaishi(J. Fuel Soc. Jpn), 64, 402 (1985) https://doi.org/10.3775/jie.64.402