Investigation of Physical Property Change in Modified Corn Starch by Ultra Fine Pulverization

초미세분쇄를 이용한 옥수수 변성전분의 물리적 특성 변화 구명

  • Received : 2009.10.21
  • Accepted : 2009.11.18
  • Published : 2009.11.30

Abstract

This study was performed to analyze changes in the molecular structural and physical properties of modified corn starch, in which particle structure was broken using high impact planetary mill and ultra fine pulverizing techniques. The average diameter and specific surface area of the modditied corn starch after pulverization decreased 50% and increased 567%, respectively. Content of low molecular substances mersured using gel permeation chromatography (GPC) increased from 21.0% to 86.5% after pulverizing corn starch. Damaged starch content also increased from 9.63% to 83.57% after pulverizing corn starch. After pulverization, gel formation capacity corn starch was reduced compared to that of control by structure breakdown.

본 연구는 초미세분쇄기술을 이용하여 옥수수전분의 입자구조파괴가 이루어졌을 때 분자구조적, 물리적 변화가 어떻게 이루어지는지를 구명하고자 하였다. 초미세 분쇄처리 후 옥수수전분의 평균직경은 약 50% 감소가 이루어졌으며 비표면적은 567% 증가하였다. 초미세분쇄처리 전 후의 옥수수전분에 대한 분자량분포를 GPC로 측정한 결과 분쇄 후 저분자량의 Peak II의 면적이 21.0%에서 86.5%로 상승하였다. 손상전분 함량은 각각 9.63%와 83.57%로 초미세분쇄처리에 의하여 크게 증가하였다. 옥수수전분의 경우는 겔(gel)을 형성하였으나 초미세분쇄처리 후에는 전분의 분쇄과정에서 전분입자파괴와 아울러 옥수수전분의 분자량이 저분자화 되면서 겔 형성능력이 크게 저하되었다.

Keywords

Acknowledgement

Supported by : 한국과학재단

References

  1. AACC. 1992. Approved Methods of Analysis of AACC. 8th ed.American Association of Cereal Chemists, St. Paul, MN, USA
  2. Cho SY, Tak SH, Rhee C. 2001. Effect of extraction rate ofkorean wheat flour on rheological and raw noodle-making properties.Food Sci. Biotechnol. 10: 246-250
  3. Han XZ, Campanella OH, Mix NC, Hamaker BR. 2002. Consequenceof starch damage on rheological properties of maizestarch pastes. Cereal Chem. 79: 897-901 https://doi.org/10.1094/CCHEM.2002.79.6.897
  4. Han MR, Chang MJ, Kim MH. 2007. Investigation of physicalproperty change in modified rice starch by ultra fine pulverization.J. Korean Soc. Appl. Biol. Chem. 50: 160-166
  5. Huang ZQ, Lu JP, Li XH, Tong ZF. 2007. Effect of mechanicalactivation on physico-chemical properties and structure of cassavastarch. Carbohydr. Polym. 68: 128-135 https://doi.org/10.1016/j.carbpol.2006.07.017
  6. Joo OS, Jung YM. 2001. Effects of attrition milling in wheat flouron starch damaged of dough and bread baking properties.Korean J. Postharvest Sci. Technol. 8: 434-441
  7. Kim KH, Lee IH, Lee HS, Park JK. 2003. R&D trend and informationanalysis of nanoparticles. Prospectives of IndustrialChemistry 6: 46-61
  8. Kim KY. 2004. A study on the molecular distribution of starch.Korean J. Food Preserv. 11: 496-502
  9. Kim CS, Kim CS, Kim HI. 2009. Physicochemical properties ofnon-waxy rice flour affected by grinding methods and steepingtimes. J. Korean Soc. Food Sci. Nutr. 38: 1076-1083 https://doi.org/10.3746/jkfn.2009.38.8.1076
  10. Knutson CA, Grove MJ. 1994. Rapid method for estimation ofamylose in maize starches. Cereal Chem. 71: 469-471
  11. Ku KH, Park DJ. 1998. Cowpea starch extraction process usingmicroparticulation/air classification technology. Korean J. FoodSci. Technol. 30: 118-124
  12. Lee EYC, Carter JH, Nielsen LD, Fischer EH. 1970. Purificationand properties yeast amylo-1,6-glucosidase-oligo-1,4→1,4-glucan-transferase. Biochemistry 9: 2347-2355 https://doi.org/10.1021/bi00813a019
  13. Lim ST. 1997. Modified starch using a food. Bulletin Food Technol.10: 51-67
  14. Meuser F, Klinger RW, Niedeck EA. 1978. Characterization ofmechanically modified starch. Starch/Stàrke 30: 376-384 https://doi.org/10.1002/star.19780301105
  15. Morrison WR, Tester RF. 1994. Properties of damaged starchgranules. IV. Composition of ball-milled wheat starches and offractions obtained on hydration. J. Cereal Sci. 20: 69-77 https://doi.org/10.1006/jcrs.1994.1046
  16. Park DJ, Ku KH, Mok CK. 1995. Characteristics of glutiniousrice fractions and improvement of yoogwa processing by microparticulation/air-classification. Korean J. Food Sci. Technol. 27:1008-1012
  17. Sekino T, Etoh S, Kondo H, Choa YH. 1998. Transition metaldispersed oxide ceramic nanocomposities with multiple functions.Ceram. Soc. Japan Series 2: 489-492
  18. Sim CH. 2005. Change in angle of repose of potato starch byplanetary milling. Food Eng. Prog. 9: 97-103
  19. Suzuki A, Hizukuri S, Takeda Y. 1981. Physicochemical studies ofkuzu starch. Cereal Chem. 58: 266-272
  20. Yin XS, Stark JR. 1988. Molecular modification of barley starchgranules by different types of physical treatment. J. Cereal Sci.8: 17-28 https://doi.org/10.1016/S0733-5210(88)80045-6