Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Phosphoric Acid Modified Nb2O5: A Selective and Reusable Catalyst for Dehydration of Sorbitol to Isosorbide

  • Tang, Zhen-Chen (College of chemistry and chemical engineering, Nanjing University of Technology) ;
  • Yu, Ding-Hua (College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology) ;
  • Sun, Peng (College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology) ;
  • Li, Heng (College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology) ;
  • Huang, He (College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology)
  • Received : 2010.09.01
  • Accepted : 2010.10.11
  • Published : 2010.12.20
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Abstract

Niobium oxide ($Nb_2O_5$) and phosphated $Nb_2O_5$ were synthesized and used as catalysts for sorbitol dehydration to isosorbide. The characterization results of $N_2$ adsorption, XRD and $NH_3$-TPD revealed that the phosphoric acid modification could well prevent the crystallization of $Nb_2O_5$. And the amorphous phosphated $Nb_2O_5$ catalysts kept the relatively large surface area and stable acidity at high calcination temperature. The catalytic results showed that the selectivity to isosorbide could be dramatically enhanced over phosphated $Nb_2O_5$. The excellent catalytic performance with 100.0% sorbitol conversion and 62.5% isosorbide selectivity were obtained over the 0.8P/NBO-400 catalyst. Comparing with $Nb_2O_5$ catalysts, phosphated $Nb_2O_5$ catalysts regenerated through a simple calcination process showed no significant activity loss after recycling three runs.

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