Journal of the Korean Physical Society

Korean Physical Society (한국물리학회)
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Multiferroic Properties of Ti-doped BiFeO$_{3}$ Ceramics

Kim, S.J.;Han, S.H.;Kim, H.G.;Kim, A.Y.;Kim, J.S.;Cheon, C.I.

  • Published : 20100100
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Abstract

Bi(Fe$_{1-x}$Ti$_{x}$)O$_{3}$ (x = 0, 0.005, 0.01, 0.015) ceramics were prepared by using a conventional solid state reaction method. The influences of Ti doping on the crystal structure and the microstructure and on the dielectric, ferroelectric, and magnetic properties of the BiFeO$_{3}$ ceramics were investigated by using X-ray diffraction, scanning electron microscopy, dielectric measurements, and ferroelectric and magnetic hysteresis measurements. As the amount of Ti substitution was increased, the dielectric loss and the variation in the loss with increasing frequency decreased, and the ferroelectric hysteresis loops changed from rounded to a typical ferroelectric feature. Also, with increasing Ti concentration, the magnetization and the coercive magnetic field increased. Experimental results suggested that partial substitution of high-valance, smaller ionic radius, and nonmagnetic Ti at the Fe site led to a reduction in oxygen vacancies and to a change in the antiferromagnetic structure, resulting in a reduced leakage current and reduced net magnetization, respectively.

Keywords

References

  1. G. A. Smolenskii and I. E. Chupis, Sov. Phys. Usp. 25, 475 (1982) https://doi.org/10.1070/PU1982v025n07ABEH004570
  2. I. G. Ismailzade, Phys. Status Solidi (b) 46, K39 (1971) https://doi.org/10.1002/pssb.2220460156
  3. J. Wang, J. B. Neaton, H. Zheng, V. Nagarajan, S. B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D. G. Schlom, U. V. Waghmare, N. A. Spaldin, K. M. Rabe, M. Wuttig and R. Ramesh, Science 299, 1719 (2003) https://doi.org/10.1126/science.1080615
  4. S. Nakashima, K. Y. Yun, Y. Nakamura and M. Okuyama, J. Korean Phys. Soc. 51, 882 (2007) https://doi.org/10.3938/jkps.51.882
  5. G. L. Yuan, S. W. Or, Y. P. Wang, Z. G. Liu and J. M. Liu, Solid State Commun. 138, 76 (2006) https://doi.org/10.1016/j.ssc.2006.02.005
  6. J. O. Cha, J. S. Ahn and K. B. Lee, J. Korean Phys. Soc. 54, 844 (2009) https://doi.org/10.3938/jkps.54.844
  7. S. R. Das, R. N. P. Choudhary, P. Bhattacharya, R. S. Katiyar, P. Dutta, A. Manivannan and M. S. Seehra, J. Appl. Phys. 101, 034104 (2007) https://doi.org/10.1063/1.2432869
  8. Y. K. Jun, W. T. Moon, C. M. Chang, H. S. Kim, H. S. Ryu, J. W. Kim, K. H. Kim and S. H. Hong, Solid State Commun. 135, 133 (2005) https://doi.org/10.1016/j.ssc.2005.03.038
  9. F. Chang, N. Zhang, F. Yang, S. Wang and G. Song, J. Phys. D: Appl. Phys. 40, 7799 (2007) https://doi.org/10.1088/0022-3727/40/24/031
  10. E. J. Choi, S. S. Kim, J. W. Kim, M. H. Park, H. K Cho, W. J. Kim, S. Yi and D. Yoo, J. Korean Phys. Soc. 51, S138 (2007) https://doi.org/10.3938/jkps.51.138
  11. M. M. Kumar, A. Srinivas and S. V. Suryanarayana, J. Appl. Phys. 87, 855 (2000) https://doi.org/10.1063/1.371953
  12. Z. Chaodan, Y. Jun, Z. Duanming, Y. Bin, W. Yunyi, W. Longhai, W. Yunbo and Z.Wenli, Integr. Ferroelectr. 94, 31 (2007) https://doi.org/10.1080/10584580701755872
  13. M. Kumar, K. L. Yadav and G. D. Varma, Mater. Lett. 62, 1159 (2008) https://doi.org/10.1016/j.matlet.2007.07.075
  14. Y. Xu, Ferroelectric Materials and Their Applications (North-Holland, Amsterdam, 1991)
  15. P. Baettig, C. Ederer and N. A. Spaldin, Phys. Rev. B 72, 214105 (2005) https://doi.org/10.1103/PhysRevB.72.214105
  16. M. Kumar and K. L. Yadav, J. Appl. Phys. 100, 074111 (2006) https://doi.org/10.1063/1.2349491
  17. A. J. Jacobson and B. E. F. Fender, J. Phys. C: Solid State Phys. 8, 844 (1975) https://doi.org/10.1088/0022-3719/8/6/015
  18. S. V. Kiselev, R. P. Ozerov and G. S. Zhdanov, Sov. Phys. Dokl. 7, 742 (1963)
  19. M. M. Kumar, S. Srinath, G. S. Kumar and S. V. Suryanarayana, J. Magn. Magn. Mater. 188, 203 (1998) https://doi.org/10.1016/S0304-8853(98)00167-X
  20. K. Ueda, H. Tabata and T. Kawai, Appl. Phys. Lett. 75, 555 (1999) https://doi.org/10.1063/1.124420

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