Transactions of the Korean hydrogen and new energy society (한국수소및신에너지학회논문집)

The Korean Hydrogen and New Energy Society (한국수소및신에너지학회)
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Hydrogen Generation from $NaBH_4$ Hydrolysis on Co-Ni-P-B/Ni Foam Catalyst

Co-Ni-P-B/Ni foam 촉매에서 $NaBH_4$ 가수분해를 통한 수소 발생

  • Park, Da-Ill (Department of Aerospace Engineering, Chosun Univ.) ;
  • Kim, Tae-Gyu (Department of Aerospace Engineering, Chosun Univ.)
  • 박대일 (조선대학교 항공우주공학과) ;
  • 김태규 (조선대학교 항공우주공학과)
  • Received : 2010.07.30
  • Accepted : 2010.10.20
  • Published : 2010.10.31
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Abstract

Co-B, Co-P-B, Co-Ni-B and Co-Ni-P-B catalysts supported on Ni foam were prepared using electroless plating in the present study. The surface morphology of the catalysts/Ni foam was observed using SEM and EDS analysis. The Co-Ni-P-B/Ni foam catalyst showed the superior performance on hydrogen generation due to the uniform formation of catalyst particles on the Ni foam surface. The characteristics of hydrogen generation with Co-Ni-P-B/Ni foam catalyst was investigated at the variety of $NaBH_4$ and NaOH concentrations. Durability test was performed, resulting in the stable hydrogen generation for 6 hours.

Keywords

References

  1. 김태규, 이기성, 권세진, "연료전지 무인항공기 설계 및 시험결과", 한국 항공우주학회 2009년도 춘계학술대회 논문집, pp. 508-511.
  2. H.I. Schlesinger, H.C. Brown, A.E. Finholt, J.R. Gilbreath, H.R. Hockstra, and E.K. Hyde, "Sodium borohydride, its hydrolysis and use as a reducing agent and in the generation of hydrogen", J. Am. Chem. Soc. Vol. 75, 1953, pp. 215-219. https://doi.org/10.1021/ja01097a057
  3. S.C. Amendola, S.L. Sharp-Goldman, M.S. Janjua, M.T. Kelly, P.J. Petillo, and M. Binder : "An Ultrasafe Hydrogen Generator: Aqueous, Alkaline Borohydride Solution and Ru Catlayst", J. Power sources, Vol. 85, 2000, pp. 186-189. https://doi.org/10.1016/S0378-7753(99)00301-8
  4. S.C. Amendola, S.L. Sharp-Goldman, M.S. Janjua, N.C. Spencer, M.T. Kelly, P.J. Petillo, and M. Binder, "A Safe, Portable, Hydrogen Gas Generator Using Aqueous Borohydride Solution and Ru Catalyst", Iny. J. Hydrog. Energy, 25, 2000, pp. 969-975. https://doi.org/10.1016/S0360-3199(00)00021-5
  5. G. Guella, C. Zanchetta, B. Patton, A. Miotello, "New Insights on the Mechanism of Palladium-Catalyzed Hydrolysis of Sodium Borogydride from 11B NMR Measurements", J. Phys. Chem. B 110, 2006, pp. 17024-17033. https://doi.org/10.1021/jp063362n
  6. R. Pena-Alonso, A. Sicurelli, E. Callone, G. Carturan, R. Raj, "A picoscale catalyst for hydrogen generation from $NaBH_4$ for fuel cells", J. Power Sources 165, 2007, pp. 315-323. https://doi.org/10.1016/j.jpowsour.2006.12.043
  7. Y. Kojima, K. Suzuki, K. Fukumoto, M. Sasaki, T. Yamamoto, Y. Kawai, H. Hayashi, "Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide", Int. J. Hydrogen Energy, 27, 2002, pp. 1029-1034. https://doi.org/10.1016/S0360-3199(02)00014-9
  8. V.I. Simagina, P.A. Storozhenko, O.V.Netskina, O.V. Komova, G.V. Odegova, T.Y. Samilenko, A.G. Gentsler, "Effect of the nature of the active component and support on the activity of catalysts for the hydrolysis of sodium borohydride", Kinet. Catal. 48, 2007, pp. 168-175. https://doi.org/10.1134/S0023158407010223
  9. B.H. Liu, Z.P. Li, S. Suda, "Nickel- and cobalt-based catalysts for hydrogen generation by hydrolsis of borogydride", J. Alloy Compk. 415, 2006, pp. 288-293. https://doi.org/10.1016/j.jallcom.2005.08.019
  10. H. Dong, H.X. Yang, X.P. Ai, C.S. Cha, "Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst", Int. J. Hydrogen Energy 28, 2003, pp. 1095-1100. https://doi.org/10.1016/S0360-3199(02)00235-5
  11. 조근우, 엄광섭, 권혁상, "Sodium Borohydride의 수소 발생을 위한 다공성 Co-P 촉매", 한국수소 및 신에너지 학회논문집, Vol. 17, No. 4, 2006, pp. 448-453.
  12. R. Femandes, N. Patel, A. Miotello, "Efficient catalytic properties of Co-Ni-P-B catalyst powders for hydrogen generation by hydrolysis of alkaline solution of $NaBH_{4}$", Intemational Journal of Hydrogen Energy, Volume 34, Issue 7, April 2009, pp. 2893-2900.
  13. Yan Liang Ping Wang, Hong-Bin Dai, "Hydrogen bubbles dynamic template preparation of a porous Fe-Co-B/Ni foam catalyst for hydrogen generation from hydrolysis of alkaline sodium borohydride solution", Journal of Alloys and Compounds, Volume 491, Issues 1-2, 18 February 2010, pp. 359-365. https://doi.org/10.1016/j.jallcom.2009.10.183
  14. 박대일, 김태규, "$NaBH_{4}$ 수용액에서의 수소발생을 위한 Co-Ni-P-B/Ni foam 촉매의 연구", 2010 한국수소 및 신에너지 학회 춘계학술대회 논문집, 2010, pp. 29-32.