DOI QR코드

DOI QR Code

Characteristics Evaluation of Conversion Coating of Acid Pickling AZ31 Magnesium Alloy by a Chromium-Free Phosphate-Permanganate Solution

비크롬계 인산-과망간산 용액을 이용한 AZ31 마그네슘 합금의 산처리에 따른 화성 피막의 특성 평가

  • Kim, Myung-Hwan (Department of Chemical Engineering, Pukyong National University) ;
  • Kwag, Sam-Tag (Department of Industrial Chemistry, Pukyong National University) ;
  • Moon, Myung-Jun (Department of Industrial Chemistry, Pukyong National University)
  • Received : 2010.04.13
  • Accepted : 2010.04.29
  • Published : 2010.04.30

Abstract

A chromium-free conversion coating for AZ31 magnesium alloy has been obtained by using a permanganatephosphate solution, which has been developed with acid pickling. Examination have been carried out on the conversion coatings for morphology, composition and corrosion resistance. The morphology of the conversion-coated layer was observed using optical microscope and SEM. It was shown that the conversion coatings are relatively uniform and continuous, with thickness 1.8 to 2.7 ${\mu}m$. The chemical composition of conversion coating was mainly consisted of Mg, O, P, K, Al and Mn by EDS analysis. It was found that the corrosion resistance of the AZ31 magnesium alloy has been improved by the permanganate-phosphate conversion treatment from electrochemical polarization.

Keywords

References

  1. A. Atrens, G. L. Song, Adv. Eng. Mater., 1 (1999) 11. https://doi.org/10.1002/(SICI)1527-2648(199909)1:1<11::AID-ADEM11>3.0.CO;2-N
  2. M. Zhao, S. Wu, P. An, J. Luo, Y. Fukuda, H. Nakae, Mater. Chem. Phys., 99 (2006) 54. https://doi.org/10.1016/j.matchemphys.2005.08.078
  3. H. Zhang, G. Yao, S. Wang, Y. Liu, H. Luo Surface & Coatings Tech., 202 (2008) 1825. https://doi.org/10.1016/j.surfcoat.2007.07.094
  4. M. Zhao, S. Wu, P. An, J. Luo, Mater. Chem. Phys., 103 (2007) 475. https://doi.org/10.1016/j.matchemphys.2007.02.058
  5. D. Barbosa, G. Knrnschild, Surface & Coatings Tech., 203 (2009) 1629. https://doi.org/10.1016/j.surfcoat.2008.12.018
  6. J. Y. Yu, J. H. Lim, J. I. Yu, J. H. Kim, C. H. Park, K. H. Kim, J. of Kor. Vac. Soc., 16(3) (2007) 231. https://doi.org/10.5757/JKVS.2007.16.3.231
  7. Z. Liu, W. Gao. Appl. Surf. Sci. 253 (2006) 2988. https://doi.org/10.1016/j.apsusc.2006.05.058
  8. W. Zhang, Z. He, Z. Jiang, J. Lian, Surface & Coatings Tech., 201 (2007) 4594. https://doi.org/10.1016/j.surfcoat.2006.09.312
  9. C. Gu, J. Lian, G. Li, L. Niu, Z. Jiang, J. of Alloys and Compounds 391 (2005) 104. https://doi.org/10.1016/j.jallcom.2004.07.083
  10. M. Zhao, S. Wu, J. Luo, Y. Fukuda, H. Nakae, Surface & Coatings Tech., 200 (2006) 5407. https://doi.org/10.1016/j.surfcoat.2005.07.064
  11. T. Ishizaki, I. Shigematsu, N. Saito, Surface & Coatings Tech., 203 (2009) 2288. https://doi.org/10.1016/j.surfcoat.2009.02.026
  12. U. Nwaogu, C. Blawert, N. Scharnagl, W. Dietzel, K. Kainer, Corros. Sci., 51 (2009) 2544. https://doi.org/10.1016/j.corsci.2009.06.045
  13. H. H. Elsentriecy, K. Azumi, H. Konno Surface & Coatings Tech., 202 (2007) 532. https://doi.org/10.1016/j.surfcoat.2007.06.033
  14. K. Chong, T. Shih, Mater. Chem. Phys., 80 (2003) 191. https://doi.org/10.1016/S0254-0584(02)00481-9
  15. Denny A. Jones, Principles and Prevention of Corrosion, Prentice Hall (1999) 199.
  16. A. Abdel Aal, J. Mater. Sci., 43 (2008) 2947. https://doi.org/10.1007/s10853-007-1796-2

Cited by

  1. Characteristics of Conversion Coating of AZ31 Magnesium Alloy Formed in Chromium-Free Cerium-Based Solution vol.49, pp.1, 2016, https://doi.org/10.5695/JKISE.2016.49.1.62
  2. A Blade-Abrading Method for Surface Pretreatment of Mg Alloys vol.48, pp.5, 2015, https://doi.org/10.5695/JKISE.2015.48.5.194