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Preparation and physical properties of biodegradable polybutylene succinate/polybutylene adipate-co-terephthalate blend monofilament by melt spinning

용융방사에 의한 생분해성 PBS/PBAT 블랜드 모노 필라멘트 제조 및 물리적 특성

  • Park, Seong-Wook (Fisheries System Engineering Division, National Fisheries Research & Development Institute) ;
  • Kim, Seong-Hun (Fisheries System Engineering Division, National Fisheries Research & Development Institute) ;
  • Choi, Hea-Sun (Fisheries System Engineering Division, National Fisheries Research & Development Institute) ;
  • Cho, Hyun-Hok (Division of Organic Material Science and Engineering, Pusan National University)
  • 박성욱 (국립수산과학원 시스템공학과) ;
  • 김성훈 (국립수산과학원 시스템공학과) ;
  • 최혜선 (국립수산과학원 시스템공학과) ;
  • 조현혹 (부산대학교 유기소재시스템공학과)
  • Received : 2010.06.09
  • Accepted : 2010.08.09
  • Published : 2010.08.31

Abstract

In order to improve the breaking strength and elongation of Polybutylene succinate (PBS) monofilament, the monofilament was produced by blending PBS and Polybutlyne adipate-co-terephthalate (PBAT). The PBS/PBAT blend monofilament was prepared by the melt spinning system, and the weight ratios of the compositions of PBS/PBAT was 100/0, 95/5, 90/10 and 85/15, respectively. The breaking strength, elongation, softness and crystallization of PBS/PBAT blend monofilament were analyzed by using a tensionmeter, softness measurement, X-ray diffractometer in the both dry and wet conditions. The PBS/PBAT blend monofilaments were spun in the take-up velocity of 1.19m/sec under the drawing ratio of 6.8:1 condition. The production volumes of PBS/PBAT blend monofilaments showed 20% less than that of Nylon. The breaking strength of PBS/PBAT blend monofilaments were decreased as PBAT contents increased, while elongation and softness were increased. In case of PBAT content were over 5%, the breaking strength, elongation and softness of PBS/PBAT blend monofilaments were not shown to increase in spite of increasing in PBAT contents. Based on these results, it was possible to make the monofilaments with the maximized physical properties when the PBAT contents at 5%.

Keywords

Acknowledgement

Grant : 생분해성 수산자재의 응용기술개발

Supported by : 국립수산과학원

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