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Fatty Acids, Amino Acids and Thermal Properties of Specialty Rice Cultivars

특수미 품종의 지방산과 아미노산 조성 및 열적 특성

  • Received : 2010.07.06
  • Accepted : 2010.08.02
  • Published : 2010.09.30

Abstract

The compositions of fatty acid and amino acid of specialty rice which includes colored rice (Heugjinju, Jeugjinju, Josangheugchalbyeo), flavored rice (Heughyangmi, Hyangmi1), and giant embryo rice (Keunnun) were determined and compared to those of regular rice (Ilpumbyeo, Whaseonchalbyeo). Major fatty acids were linoleic acid (C18:2) and oleic acid (C18:1), which were composed of 75~80% of total fatty acids. Major amino acids were glutamic acid and aspartic acid in most cultivars but Jeugjinju in which cysteine (169.61 nmol) and GABA (129.32 nmol) were the most abundant amino acids. Thermal properties measured by differential scanning calorimeter (DSC) revealed that the enthalpy (${\Delta}H$) for starch gelatinization was the highest in Josangheugchalbyeo and Whaseonchalbyeo. It suggests that the starch structure of waxy rice could be more crystallized compared to non-waxy rice, and also that amylopectin could have more impact on starch gelatinization than amylose. The on-set and complete temperature for starch gelatinization were higher in colored rice of Heugjinju and Jeugjinju, and regular rice of Whateonchalbyeo.

특수미 품종인 유색미, 향미, 거대배아미의 지방산 및 아미조산 조성과 호화특성을 분석한 결과는 다음과 같다. 주된 지방산은 linoleic acid, oleic acid, palmitic acid이며, 특히 linoleic acid와 oleic acid가 전체 지방산의 75~80%를 차지하였다. 아미노산은 품종 간에 다소 차이가 있으나, 주요 아미노산은 glutamic acid와 aspartic acid로 분석되었으며, 적진주 품종인 경우는 cysteine과 GABA가 주요 아미노산이었고, 특히, 큰눈에는 cysteine과 GABA가 유의하게 높게 함유되어있는 것으로 나타났다. 특수미의 호화특성을 DSC 분석한 결과, 찰성인 조생흑찰과 화선찰벼가 호화에 필요한 흡열 엔탈피(${\Delta}H$)가 유의적으로 높게 나타났다. 또한, 유색미 품종인 흑진주와 적진주의 열적 특성인 호화개시온도, 최대호화온도 및 호화종결온도가 일반 메성 쌀인 일품현미에 비하여 높게 나타나, 유색미 품종의 취반 특성이 일반 현미에 비하여 낮을 것으로 분석되었다.

Keywords

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