Performance Analysis of Off-Gas/Syngas Combustor for Thermal Management of High Temperature Fuel Cell System

고온형 연료전지 열관리를 위한 배기가스 연소기 성능시험

  • 이상민 (한국기계연구원 신재생청정시스템연구실) ;
  • 이연화 (한국기계연구원 신재생청정시스템연구실) ;
  • 안국영 (한국기계연구원 신재생청정시스템연구실) ;
  • 유상석 (충남대학교 기계공학과)
  • Received : 2010.03.02
  • Accepted : 2010.06.25
  • Published : 2010.06.30

Abstract

Anode off-gas of high temperature fuel cell still contains combustible components such as hydrogen, carbon monoxide and hydrocarbon. In this study, a catalytic combustor has been applied to the high temperature fuel cell so that the combustion of anode-off gas can be boosted up. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study is designed to perform the experimental investigation on the combustion characteristics of the three commercial catalysts with a different composition. Screening tests with three catalysts are preceded before the performance examination since it is necessary to determine the most suitable catalyst for design configuration of the catalytic combustor. The performance analysis shows that methane conversion rate strongly depends on gas hourly space velocity (GHSV) as well as inlet gas temperature. Additionally, the GSHV optimization results show that the optimum GHSV will be in the range between 18,000 $hr^{-1}$ and 36,000 $hr^{-1}$. It is also shown that the minimum inlet temperature of catalytic reaction of methane is from $100^{\circ}C$ to $150^{\circ}C$.

Keywords

References

  1. Williams, M. C., Strakey, J. P., Singhal, S. C., "U.S. distributed generation fuel cell program", Journal of Power Sources, Vol. 131, 2004, pp. 79-85. https://doi.org/10.1016/j.jpowsour.2004.01.021
  2. Bischoff, M., "Large stationary fuel cell systems: status and dynamic requirements", Journal of Power Sources, Vol. 154, 2006, pp. 461-466. https://doi.org/10.1016/j.jpowsour.2005.10.027
  3. R. E. Hayes, S. T. Kolaczkowski, "Introduction to Catalytic Combustion", Gordon and Breach Science Publishers, 1997.
  4. Cocchi, S., Nutini, G., Spencer, M. J., Nickolas, S. G., "Catalytic combustion system for a 10MW class power generation gas turbine", Catalysis Today, Vol. 117, 2006, pp. 419-426. https://doi.org/10.1016/j.cattod.2006.06.042
  5. Betta, R. A. D., Rostrup-Nielsen, T., "Application of catalytic combustion to a 1.5 MW industrial gas turbine", Catalysis Today, Vol. 47, 1999, pp. 369-375. https://doi.org/10.1016/S0920-5861(98)00319-8
  6. Carroni, R., Schmidt, V., Griffin, T., "Catalytic combustion for power generation", Catalysis Today, Vol. 75, 2002, pp. 287-295. https://doi.org/10.1016/S0920-5861(02)00081-0
  7. Hong, D., Kim, C., Kim, M. Y., Lee, S. M., Ahn, K. Y., "A numerical study on the flow characteristics in the mixing region of the catalytic combustor", Journal of Mechanical Science and Technology, Vol 21, 2007, pp. 1791-1798. https://doi.org/10.1007/BF03177434
  8. 이상민, 이영덕, 안국영, 홍동진, 김만영, "MCFC Off-gas 촉매연소기 설계에 관한 연구", 한국수소 및 신에너지학회 논문집, 제18권 제4호,2007, pp. 406-412.
  9. 강성규, "촉매연소의 신기술 동향", 제27회 KOSCO Symposium 논문집, 2003, pp. 299-308.