Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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A carbon electrode fabricated using a poly(vinylidene fluoride) binder controlled the Faradaic reaction of carbon powder

  • Choi, Ji-Young (Department of Chemical Engineering, Kongju National University) ;
  • Choi, Jae-Hwan (Department of Chemical Engineering, Kongju National University)
  • Received : 2009.07.24
  • Accepted : 2009.08.18
  • Published : 2010.05.25
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Abstract

A carbon electrode for capacitive deionization (CDI) was fabricated by casting a slurry that was a mixture of activated carbon powder (ACP) and poly(vinylidene fluoride) (PVdF) dissolved in di-methylacetamide (DMAc) on the current collector. Electrochemical properties and adsorption/desorption behaviors of the carbon electrodes prepared with different PVdF contents (9-18 wt%) were characterized using cyclic voltammetry, chronoamperometry, and impedance spectroscopy methods. From the SEM images, carbon powders were coated with the PVdF binder and bound together. Capacitances of carbon electrodes were estimated in the range of 75.3-69.6 F/g, decreasing in tandem with PVdF contents, but the decrease was not significant. From cyclic voltammetric and chronoamperometricmeasurements, the electrochemical behaviors of the carbon electrodes were dependent not only on the electric double layer capacitance, but also on Faradaic reactions. However, Faradaic currents resulted from an electrochemical redox reaction of carbon surface controlled by the polymer binder. These results indicate that the electrochemical reaction on the carbon surface was suppressed due to the PVdF binder.

Keywords

References

  1. T. Younos, K.E. Tulou, J. Contemp. Water Res. Educ. 132 (2005) 3
  2. C.H. Shin, R. Johnson, J. Ind. Eng. Chem. 15 (2009) 613. https://doi.org/10.1016/j.jiec.2009.09.030
  3. H. Strathmann, Ion-Exchange Membrane Separation Processes, Elsevier, Amsterdam, 2004
  4. J.Y. Lee, T.S. Kwon, K. Baek, J.W. Yang, J. Ind. Eng. Chem. 15 (2009) 354. https://doi.org/10.1016/j.jiec.2008.12.007
  5. K.C. Leonard, J.R. Genthe, J.L. Sanfilippo, W.A. Zeltner, M.A. Anderson, Electrochim. Acta 54 (2009) 5286. https://doi.org/10.1016/j.electacta.2009.01.082
  6. Y. Oren, H. Tobias, A. Soffer, J. Electroanal. Chem. 162 (1984) 87.
  7. J.C. Farmer, D.V. Fix, G.C. Mack, R.W. Pekala, J.F. Poco, J. Electrochem. Soc. 143 (1996) 159. https://doi.org/10.1149/1.1836402
  8. J.C. Farmer, D.V. Fix, G.C. Mack, R.W. Pekala, J.F. Poco, J. Appl. Electrochem. 26 (1996) 1007.
  9. P. Xu, J.E. Drewes, D. Heil, G. Wang, Water Res. 42 (2008) 2605. https://doi.org/10.1016/j.watres.2008.01.011
  10. L. Zou, L. Li, H. Song, G. Morris, Water Res. 42 (2008) 2340. https://doi.org/10.1016/j.watres.2007.12.022
  11. T.Y. Ying, K.L. Yang, S. Yiacoumi, C. Tsouris, J. Colloid Interface Sci. 250 (2002) 18. https://doi.org/10.1006/jcis.2002.8314
  12. L. Zou, G. Morris, D. Qi, Desalination 225 (2008) 329. https://doi.org/10.1016/j.desal.2007.07.014
  13. M.W. Ryoo, J.H. Kim, G. Seo, J. Colloid Interface Sci. 264 (2003) 414. https://doi.org/10.1016/S0021-9797(03)00375-8
  14. J.A. Lim, N.S. Park, J.S. Park, J.H. Choi, Desalination 238 (2009) 37. https://doi.org/10.1016/j.desal.2008.01.033
  15. T.J. Welgemoed, C.F. Schutte, Desalination 183 (2005) 327. https://doi.org/10.1016/j.desal.2005.02.054
  16. E. Ayranci, B.E. Conway, Anal. Chem. 73 (2001) 1181. https://doi.org/10.1021/ac000736e
  17. M.W. Ryoo, G. Seo, Water Res. 37 (2003) 1527. https://doi.org/10.1016/S0043-1354(02)00531-6
  18. E. Ayranci, B.E. Conway, J. Electroanal. Chem. 100 (2001) 513.
  19. H. Li, Y. Gao, L. Pan, Y. Zhang, Y. Chen, Z. Sun, Water Res. 42 (2008) 4923. https://doi.org/10.1016/j.watres.2008.09.026
  20. Y. Gao, L. Pank, Y.P. Zhang, Y.W. Chen, Z. Sun, Surf. Rev. Lett. 14 (2007) 1033. https://doi.org/10.1142/S0218625X07010597
  21. C.J. Gabelich, T.D. Tran, I.H. Suffet, Environ. Sci. Technol. 36 (2002) 3010. https://doi.org/10.1021/es0112745
  22. H.H. Jung, S.W. Hwang, S.H. Hyun, K.H. Lee, G.T. Kim, Desalination 216 (2007) 377. https://doi.org/10.1016/j.desal.2006.11.023
  23. K. Yang, T. Ying, S. Yiacoumi, Langmuir 17 (2001) 1961. https://doi.org/10.1021/la001527s
  24. K.K. Park, J.B. Lee, P.Y. Park, S.W. Yoon, J.S. Moon, H.M. Eum, C.W. Lee, Desalination 206 (2007) 86. https://doi.org/10.1016/j.desal.2006.04.051
  25. B.E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer Academic/Plenum Publishers, New York, 1999.
  26. C.T. Hsieh, H. Teng, Carbon 40 (2002) 667. https://doi.org/10.1016/S0008-6223(01)00182-8
  27. H. Pro¨bstle, M. Wiener, J. Fricke, J. Porous Mater. 10 (2003) 213.
  28. K.L. Yang, S. Yiacoumi, C. Tsouris, J. Electroanal. Chem. 540 (2003) 159. https://doi.org/10.1016/S0022-0728(02)01308-6
  29. K. Kinoshita, Carbon: Electrochemical and Physicochemical Properties, Wiley, New York, 1988.
  30. E. Gileadi, Electrode Kinetics for Chemists, Chemical Engineers, and Materials Scientists, Wiley–VCH, New York, 1993.
  31. S.H. Yoon, J.W. Lee, T.H. Hyeon, S.M. Oh, J. Electrochem. Soc. 147 (2000) 2507.
  32. H. Probstle, C. Schmitt, J. Fricke, J. Power Sources 105 (2002) 189. https://doi.org/10.1016/S0378-7753(01)00938-7

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