DOI QR코드

DOI QR Code

The optimal volume of a combined system of LNT and SCR catalysts

  • Published : 2011.05.25

Abstract

This paper aims to find the optimal volumes of the LNT (Lean NOx Trap) and SCR (Selective Catalytic Reduction) catalysts for higher de-NOx performance and suppression of $N_2O$ and $NH_3$ in a combined system of LNT + SCR. The basic characteristics of the LNT catalyst were identified first at various space velocities (SV), and then the effects of the variation in volume of the combined system were investigated. The NOx conversion, $NH_3$ production, and $N_2O$ emissions were evaluated of four differently sized LNT-SCR systems. Considering all together the NOx conversion, cost of the precious metal, $NH_3$ slippage, and $N_2O$ generation, the optimal volume ratio of LNT and SCR catalysts was found to be 1:1 for the LNT-SCR system.

Keywords

References

  1. C.H. Lee, B.C. Choi, Int. J. Automot. Technol. 8 (2007) 667.
  2. T.V. Johnson, SAE 2010-01-0301 (2010).
  3. B. Westerberg, C. Kunkel, C.U.I. Odenbrand, Chem. Eng. J. 92 (2003) 27. https://doi.org/10.1016/S1385-8947(02)00118-3
  4. A. Lundstro¨m, B. Andersson, L. Olsson, Chem. Eng. J. 150 (2009) 544. https://doi.org/10.1016/j.cej.2009.03.044
  5. L. Xu, W. Watkins, R. Snow, G. Graham, R. McCabe, SAE 2007-01-1582 (2007).
  6. J.G. Kim, H.M. Lee, J. Ind. Eng. Chem. 14 (2008) 841. https://doi.org/10.1016/j.jiec.2008.06.007
  7. A. Schuler, M. Vostmeier, P. Kiwic, J. Gieshoff, W. Hautpmann, A. Drochner, H. Vogel, Chem. Eng. J. 154 (2009) 333. https://doi.org/10.1016/j.cej.2009.02.037
  8. G.W. Lee, B.H. Shon, J.G. Yoo, J.H. Jung, K.J. Oh, J. Ind. Eng. Chem. 14 (2008) 457. https://doi.org/10.1016/j.jiec.2008.02.013
  9. D.J. Kim, J.W. Kim, S.J. Choung, M. Kang, J. Ind. Eng. Chem. 14 (2008) 308. https://doi.org/10.1016/j.jiec.2008.01.009
  10. W.P. Partridge, J.S. Choi, Appl. Catal. B: Environ. 91 (2009) 144. https://doi.org/10.1016/j.apcatb.2009.05.017
  11. L. Castoldi, L. Lietti, I. Nova, R. Matarrese, P. Forzatti, F. Vindigni, S. Morandi, F. Prinetto, G. Ghiotti, Chem. Eng. J. 161 (2010) 416. https://doi.org/10.1016/j.cej.2009.10.065
  12. N.W. Cant, M.J. Patterson, Catal. Today 73 (2002) 271. https://doi.org/10.1016/S0920-5861(02)00010-X
  13. L. Lietti, P. Forzatti, I. Nova, E. Tronconi, J. Catal. 204 (2001) 175. https://doi.org/10.1006/jcat.2001.3370
  14. R. Snow, D. Dobson, R. Hammerle, S. Katare, SAE 2007-01-0469 (2007).
  15. J. Parks, V. Prikhodko, SAE 2009-01-2739 (2009).
  16. L. Xu, R. McCabe, W. Ruona, G. Cavataio, SAE 2009-01-0285 (2009).
  17. R. Bonzi, L. Lietti, L. Castoldi, P. Forzatti, Catal. Today 151 (2010) 376. https://doi.org/10.1016/j.cattod.2010.02.003
  18. J.R. Theis, J.A. Ura, R.W. McCabe, SAE 2010-01-0300 (2010).
  19. C.K. Seo, H.N. Kim, B.C. Choi, 6th Tokyo Conf. on Advan. Catal. Sci. & Tech./5th Asia Paci. Cong. on Catal., 2010, p. 177.

Cited by

  1. Modeling studies of low‐temperature aerobic NOx reduction by a sequence of LNT‐SCR catalysts vol.59, pp.9, 2011, https://doi.org/10.1002/aic.14171
  2. Volume Optimization of a Combined System of LNT and SCR Catalysts Considering Economic Feasibility and De-NOx Performance vol.17, pp.1, 2011, https://doi.org/10.9726/kspse.2013.17.1.019
  3. Study of the Optimal Calcination Temperature of an Al/Co/Ni Mixed Metal Oxide as a DeNOx Catalyst for LNT vol.21, pp.3, 2015, https://doi.org/10.7464/ksct.2015.21.3.184
  4. LNT 촉매 후단의 NH3 생성 특성 vol.20, pp.1, 2011, https://doi.org/10.9726/kspse.2016.20.1.018
  5. Simultaneous Reduction of CH4 and NOx of NGOC/LNT Catalysts for CNG buses vol.19, pp.6, 2011, https://doi.org/10.5762/kais.2018.19.6.167
  6. Morphology-Oriented ZrO2-Supported Vanadium Oxide for the NH3-SCR Process: Importance of Structural and Textural Properties vol.11, pp.25, 2011, https://doi.org/10.1021/acsami.9b03429
  7. Hybrid Technology for DeNOxing by LNT-SCR System for Efficient Diesel Emission Control: Influence of Operation Parameters in H2O + CO2 Atmosphere vol.10, pp.2, 2011, https://doi.org/10.3390/catal10020228
  8. Novel Preparation of Cu and Fe Zirconia Supported Catalysts for Selective Catalytic Reduction of NO with NH3 vol.11, pp.1, 2011, https://doi.org/10.3390/catal11010055