DOI QR코드

DOI QR Code

Corrosion Resistance of Cold Rolled Steel coated Organic/inorganic Hybrid Coating Solution According to Heat Treatment Temperature

유/무기 하이브리드 코팅액에 의한 냉간압연강판의 열처리 온도에 따른 내식특성

  • Nam, Ki-Woo (Materials Science and Engineering, Pukyong National University) ;
  • Kim, Jung-Ryang (Graduate School of MR Interdisciplinary Program of Machanical Engineering, Pukyong National University) ;
  • Choi, Chang-Min (Graduate School of MR Interdisciplinary Program of Machanical Engineering, Pukyong National University)
  • 남기우 (부경대학교 재료공학과) ;
  • 김정량 (부경대학교 대학원 학연협동기계공학과) ;
  • 최창민 (부경대학교 대학원 학연협동기계공학과)
  • Received : 2011.04.28
  • Accepted : 2011.12.23
  • Published : 2011.12.31

Abstract

The demand for cold rolled steel (CR) for structural members is gradually increasing. If no surface treatment (coating for corrosion resistance) for CR is conducted, its use is very limited because CR is vulnerable to corrosion. Therefore, we need to develop a coating solution to provide high corrosion resistance for CR. In this study, an organic/inorganic coating solution with Si and Ti (Si polysilicate 7 wt.% + Urethane 13 wt.% + Ti amorphous 0.5 wt.%; LR-0727(1)) was used to evaluate the corrosion resistance of CR under a salt spray test. The specimens with the LR-0727(1) coating were heat treated in a drying oven at $120{\sim}210^{\circ}C$for 5 min. The corrosion resistance was investigated using a salt spray test of 7 h. In addition, an adhesive test was conducted. Rust showed under a heat treatment of $150^{\circ}C$, but no vestiges were found over $160^{\circ}C$. The specimens with heat treatment at $160^{\circ}C$ or more did not experience delamination. From these results, it is considered that the temperature limit for optimum heat treatment is $160^{\circ}C$ considering energy efficiency.

Keywords

References

  1. 김만, 이종재, 김대영, 박상언, 권식철 (2004). "친환경성 경질 3 가크롬도금의 연구동향", 한국표면공학회지, 제37권, 제3호, pp 179-184.
  2. 김수원, 이철태 (2006). "아연도금용 친환경 3가 크로메이트 표면처리기술", 한국공업화학회지, 제17권, 제5호, pp 433-442.
  3. 김형준 (1993). "고내식성 내지문 EGI 강판 개발", 한국표면공학회지, 제26권, 제6호, pp 307-315.
  4. 박영준 (2007). "Cr-free 처리 용융아연도금강판의 흑변 및 백청 현상 연구", 포스코 연구논문, 제12권, 제1호, pp 106-110
  5. 이종두 (2006). Cr-free 차세대 나노코팅액 개발에 관한 연구 환경부(나노코) 연구보고서.
  6. 이철태 (2007). "3가 크롬황산염의 크로메이트에 의한 아연도금 내식성 증대", 한국공업화학회지, 제18권, 제3호, pp 296-302.
  7. 서현수, 문희준, 김정량, 김종순, 안석환, 문창권, 남기우 (2011). "Si 변성 유/무기 하이브리드 코팅액에 의한 아연도금강판의 내식특성", 한국해양공학회지, 제25권, 제1호, pp 32-38.
  8. 서현수, 문희준, 김종순, 안석환, 문창권, 남기우 (2010a). "Crfree 코팅액에 의한 아연도금강판의 열처리시간에 따른 내식특성", 한국해양공학회지, 제24권, 제5호, pp 67-74.
  9. 서현수, 문희준, 김종순, 안석환, 문창권, 남기우 (2010b). "Cr-free 코팅액에 의한 아연도금강판의 열처리 온도에 따른 내식 특성" 한국해양공학회지, 제24권, 제5호, pp 60-66.
  10. 조남웅, 전중환, 전재호 (2001). 크로메이트 초리 대체기술의 개발동향, RIST 연구보고서, Vol 15, No 1, pp 108-113.
  11. Bajat J.B., Mi skovi'c-Stankovi'c V.B., Bibi'c N, Dra zi'c D.M (2007). "The Influence of Zinc Surface Pretreatment on the Adhesion of Epoxy Coating Electrodeposited on Hot-di p Galvanized Steel", Progress in Organic Coating 58, pp 323-330. https://doi.org/10.1016/j.porgcoat.2007.01.011
  12. Deflorian, F., Rossi, S., Fedrizzi, L. and Bonora, P.L. (2005). "EIS Study of Organic Coating on Zinc Surface Pretreated with Environmentally Friendly Products", Progress in Organic Coatings, Vol 52, pp 271-279. https://doi.org/10.1016/j.porgcoat.2004.04.005
  13. Dobrza'nski, L.A., Brytan, Z., Actis Grande, M. and Rosso, M. (2007). "Corrosion Resistance of Sintered Duplex Stainless Steels in the Salt Fog Spray Test", Journal of Materials Processing Technology, Vol 192-193, pp 443-448. https://doi.org/10.1016/j.jmatprotec.2007.04.077
  14. Duhua Wang, Gordon. P. and Bierwagen (2009). "Sol-.gel Coatings on Metals for Corrosion", Progress in Organic Coatings, Vol 64, pp 327-338. https://doi.org/10.1016/j.porgcoat.2008.08.010
  15. Gillett M, Nsongo T (1995). "Adhesion Characterization of Titanium and Titanium Nitride Thin Coatings on Metals Using the Scratch Test", hit. J. Adhesion am/Adhesives, Vol 15, pp 191-196. https://doi.org/10.1016/0143-7496(95)91631-F
  16. Steven J.H., Lowe C., James T.M. and John F.W (2005). "Migration and Segregation Phenomena of a Silicone Additive in a Multilayer Organic Coating," Progress in Organic Coatings, Vol 54, pp 104-112. https://doi.org/10.1016/j.porgcoat.2005.04.007
  17. Zheludkevich M.L., Miranda Salvado I., Ferreira M.G.S (2005). "Sol-gel Coatings for Corrosion Protection of Metals," J. Mater. Chem, Vol 15, pp 5099-5111. https://doi.org/10.1039/b419153f

Cited by

  1. Development of Organic/Inorganic Hybrid Coating Solution for High Strength Steel Sheet (SPFC780) vol.7, pp.6, 2016, https://doi.org/10.18178/ijcea.2016.7.6.614
  2. Corrosion Resistance of Galvanized Steel by Organic/Inorganic Hybrid Solution with Constant Amount of SiO2 Polysilicate and Melamine vol.22, pp.5, 2018, https://doi.org/10.9726/kspse.2018.22.5.036