The Investigation of Combustible Hazard by Measurement of Flash Point and Autoignition Temperature of n-Dodecane

노말도데칸의 인화점과 최소발화온도 측정에 의한 연소위험성 고찰

  • 하동명 (세명대학교 보건안전공학과)
  • Received : 2011.01.24
  • Accepted : 2011.04.08
  • Published : 2011.04.30

Abstract

For the safe handling of n-dodecane, the explosion limits were investigated and the lower flash points and AITs (autoignition temperatures) by ignition delay time were experimented. By using the literatures data, the lower and upper explosion limits of n-dodecanee recommended 0.6 Vol.% and 4.7 Vol.%, respectively. The lower flash points of n-dodecane by using closed-cup tester were experimented $77^{\circ}$ and $80^{\circ}C$. The lower flash points of n-dodecane by using open cup tester were experimented $84^{\circ}C$ and $87^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for n-dodecane. The experimental AIT of n-dodecane was $222^{\circ}C$.

노말도데칸의 안전한 취급을 위해서 25에서 폭발한계를 고찰하였고, 하부인화점과 발화지연시간에 의한 발화온도를 측정하였다. 공정의 안전을 위해서 노말도데칸의 폭발하한계는 0.60Vol.%, 상한계는 4.7Vol.%를 추천하였고, 하부인화점은 밀폐계에서 $77^{\circ}C$$80^{\circ}C$와 개방식에서 $84{\sim}87^{\circ}C$로 측정되었다. ASTM E659-78 장치를 사용하여 자연발화온도와 발화지연시간을 측정하였고, 최소자연발화온도는 $222^{\circ}C$ 측정되었다.

Keywords

References

  1. F.P. Lees, "Loss Prevention in the Process Industries", Vol.2, 2nd ed., Butterworth-Heinemann(1996).
  2. J.M. Hughes, D.R. Hardy, and E.J. Beal, "A Flash Point Value for n-Dodecane based on the Manual Pensky-Martens Closed-cup Method", Energy and Fuel, Vol.10, pp.1276-1277(1996). https://doi.org/10.1021/ef960002y
  3. R.E. Montemayor, J.E. Rogerson, J.C. Colbert, and S.B. Schiller, "Reference Verification Fluids for Flash Point Determination", J. of Testing and Evaluation, Vol.27, No.6, pp. 423-427(1999). https://doi.org/10.1520/JTE12171J
  4. R.E. Montemayor, M.A. Collier, and G.G. Lazarczyk, "Precision and Equivalence of Automatic and Manual Flash Point Apparatus", J. of Testing and Evaluation, Vol.30, No.1, pp.74-84(2002). https://doi.org/10.1520/JTE12291J
  5. J.C. Jones and J. Godefroy, "A Reappraisal of the Flash Point of Formic Acid", J. of Loss Prevention in the Process Industries, Vol.15, pp.241-243(2002). https://doi.org/10.1016/S0950-4230(01)00063-8
  6. L.G. Britton, "Two Hundred Years of Flammable Limits", Process Safety Progress, Vol.12, No.1, pp.1-11(2002).
  7. D.M. Ha, "The Measurement and Investigation of Fire and Explosion Properties for Acetone", J. of the Korean Society of Safety, Vol.25, No.4, pp.30-35(2010).
  8. M.G. Zabetakis, A.L. Furno, and G.W. Jones, "Minimum Spontaneous Ignition Temperature of Combustibles in Air", Industrial and Engineering Chemistry, Vol.46, No.10, pp.2173-2178(1954). https://doi.org/10.1021/ie50538a047
  9. F.Y. Hshieh, D.B. Hirsh, and J.H. Willams, "Autoignition Temperature of Trichlorosilanes", Fire and Materials, Vol.26, pp.289-290(2002). https://doi.org/10.1002/fam.804
  10. D.M. Ha and S.J. Lee, "Measurement of Autoignition Temperature of Ethylbenzene + n-hexanol and Ethylbenzene + n-propionic acid Systems", T. of the Korean Institute of Fire Sci. & Eng., Vol.21, No.2, pp.33-40(2007).
  11. NFPA, "Fire Hazard Properties of Flammable Liquid, Gases, and Volatile Solids", NFPA 325M, NFPA(1991).
  12. SFPE, "SFPE Handbook of Fire Protection Engineering", 2nd ed., SFPE(1995).
  13. V. Babrauskas, "Ignition Handbook", Fire Science Publishers, SFPE(2003).
  14. S.M. Stephenson, "Flash Points of Organic and Organometallic Compounds", Elsevier(1987).
  15. R.E Lenga and K.L. Votoupal, "The Sigma Aldrich Library of Regulatory and Safety Data, Volume I-III", Sigma Chemical Company and Aldrich Chemical Company Inc.(1993).
  16. 柳生昭三, "蒸氣の爆發限界", 安全工學協會(1979).
  17. R.J. Lewis, "Sax's dongerous Properties of Industrial Materials", 11th ed., john Wiley & Son, Inc., New Jersey(2004).
  18. R. Mallampati et al., "Evaluation of EpiDerm Full Thickness-300 (EFT-300) as in Vitro Model for Skin Irritation: Studies on Aliphatic Hydrocarbons", Toxicology in Vitro, Vol.24, pp.669-676(2010). https://doi.org/10.1016/j.tiv.2009.08.019
  19. G.S. Scott, G.W. Jones, and F.E. Scott, "Determination of Ignition Temperature of Combustible Liquids and Gases", Analytical Chemistry, Vol.20, No.3, pp.238-241(1948). https://doi.org/10.1021/ac60015a015
  20. C.J. Hilado and S.W. Clark, "Autoignition Temperature of Organic Chemicals", Chemica Engineering, Vol.4, pp.75-80(1972).
  21. C.E. Frank and A.U. Blackham, "Spontaneous Ignition of Organic Compounds", Industrial and Engineering Chemistry, Vol.44, No.4, pp.862-867 (1952). https://doi.org/10.1021/ie50508a044
  22. J. Gmehing, U. Onken, and W. Arlt, "Vapor-Liquid Equilibrium Data Collection", DECHEMA(1980).
  23. N.N. Semenov, "Some Problems in Chemical kinetics and Reactivity, Vol. 2", Princeton University Press, Princeton, N.J.(1959).