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Experimental Study on PSA Process for High Purity CH4 Recovery from Biogas

바이오가스로부터 고순도 CH4 회수를 위한 PSA 공정의 실험적 연구

  • Received : 2010.09.20
  • Accepted : 2011.02.25
  • Published : 2011.04.10

Abstract

The objective of this study is to optimize the four-bed six-step pressure swing adsorption(PSA) process for high purity $CH_4$ recovery from the biogas. The effects of P/F(purge to feed) ratio and cycle time on the process performance were evaluated. The cyclic steady-states of PSA process were reached after 12 cycles. The purity and recovery rate of product gas, pressure and temperature changes were constant as the cycle repeated. It was shown that the P/F ratio gave significant effect on the product recovery rate by increasing the amount of purge gas in purge and regeneration step. The optimal P/F ratio was found to be 0.08. As the cycle time increased, the product purity decreased by increasing the feed gas flow rate. It was found that the optimal operating conditions were P/F ratio of 0.08 and total cycle time of 1,440 seconds with the purity of 97%.

Keywords

References

  1. US Department of Energy, 2007, Project considerations for distributed generation using opportunity fuels.
  2. Lee, J. G., 2009, Trend of biogas injection in the natural gas grid, Journal of the Korea Gas Union, Autumn, pp. 32-40.
  3. Lee, J. Y., Yeom, S. W., Kim, Y. S., and Jung, C. K, 2008, A study on the biomethane purification method, Proceedings of the KSEE 2008 Autumn Annual Conference, pp. 572-575.
  4. Kirn. J. C., 2008, Carbon dioxide capture and storage, Cheong Moon Gak.
  5. Kelly, A. S., 2006, Technical and economic feasibility of upgrading dairy manure-derived biogas for natural gas pipeline, Master of Science Thesis, Cornell University, USA.
  6. Kim, E. S., 2009, A study on purifying technology of biogas and their applications, Master of Science Thesis, Hanyang University, Korea.
  7. Skarstrom, C. W., 1960, Method and apparatus for fractionating gaseous mixtures by adsorption, U.S. Patent No. 2944627.
  8. Yang, R. T., 1987, Gas separation by adsorption processes, Butterworths, Boston.
  9. Nam, G. M., Jeong, B. M., Kang, S. H., Lee, C. H., Lee, B. K, and Choi, D. K., 2005, Experiment and simulation of 2-bed PSA for hydrogen separation from $H_{2}O$/$CH_{4}O$ gas mixture, Korean Chern. Eng. Res., Vol. 43, No.2, pp. 249-258.
  10. Jeon, J. K, Park, Y. K. and Chue, K. T., 2004, Study of PSA process for carbon dioxide recovery over zeolite adsorbent : Effect of rince rate on process performance, Journal of Korean Society for Atmospheric Environment, Vol. 20, No.1, pp. 99-110.
  11. Choi, J. W. and Na, B. K., 2009, Development of PSA process for medical oxygen generator, Clean Technology, Vol. 15, No.2, pp. 75-80.
  12. Seo, S. J. and Suh, S. S., 2007, A study on purge efficiency of PSA process for air separation, Applied Chemistry, Vol. 11, No.1, pp. 253-256.
  13. Yang, R. T., 2003, Adsorbents : Fundamentals and applications, Wiley-interscience, New Jersey.
  14. Peiling, C. and Yang, R. T., 1986, Bulk gas separation by pressure swing adsorption, Ind. Eng. Chern. Fundam., Vol. 25, No.4, pp. 758-767. https://doi.org/10.1021/i100024a047
  15. Chihara, K. and Suzuki, M., 1983, Simulation of nonisothermal pressure swing adsorption, J. Chern. Eng. Jpn., Vol. 16, No.1, pp. 53-61. https://doi.org/10.1252/jcej.16.53
  16. Lee, C. H., Yang, J. Y. and Ahn, H. W., 1999, Effects of carbon-to-zeolite ratio on layered bed $H_{2}O$ PSA for coke oven gas, AICHE J., Vol. 45, No.3, pp. 535-545. https://doi.org/10.1002/aic.690450310
  17. Yang, R. T. and Doong, S. J., 1985, Gas separation by pressure swing adsorption: A porediffusion model for bulk separation, AICHE J., Vol. 31, No. 11, pp. 1829-1985. https://doi.org/10.1002/aic.690311109