Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Preparation of Silver Nanoparticles in Ultrasonic Vibration-Induced Nanodroplets of Isopropyl Alcohol in Combination with Ionic Liquids

  • Shin, Ueon-Sang (Department of Nanobiomedical Science & WCU Research Center, Dankook University Graduate School) ;
  • Hong, Hyun-Ki (Department of Nanobiomedical Science & WCU Research Center, Dankook University Graduate School) ;
  • Kim, Hae-Won (Department of Nanobiomedical Science & WCU Research Center, Dankook University Graduate School) ;
  • Gong, Myoung-Seon (Department of Nanobiomedical Science & WCU Research Center, Dankook University Graduate School)
  • Received : 2010.07.19
  • Accepted : 2011.03.21
  • Published : 2011.05.20
Download PDF
⟨ Previous Next ⟩

Abstract

Silver nanoparticles (<10 nm) were prepared in ultrasonic vibration-induced nanodroplets of isopropyl alcohol (IPA) in combination with hydrophobic room temperature ionic liquids (RTILs). The Ag-precursor used were silver (I) complex, Ag$_2$(ehac)$_2$(eha)$_2$ (ehac = 2-ethylhexylammonium carbamate; eha = 2-ethylhexylamine), in IPA, while 1-butyl-3-methylimidazolium-based ionic liquids bearing $SbF_6^-$, $PF_6^-$ and $NTf_2^-$ as counter anions were used as RTILs. During sonication for 10-90 min at room temperature, uniform silver nanoparticles with mean sizes of 2 to 8 nm were rapidly synthesized. Transmission electron micrographs also confirmed that silver nanoparticles have a spherical shape and diverse sizes depending on the reaction time (10-90 min).

Keywords

References

  1. Singh, M.; Sinha, K.; Mandal, R. K. Mater. Lett. 2009, 63, 425. https://doi.org/10.1016/j.matlet.2008.10.067
  2. Yon, J. N.; Jamie, R. L. Sci. Total. Enviro. 2008, 1-3, 396.
  3. Jeon, H. J.; Yi, S. C.; Oh, S. G. Biomaterials 2003, 24, 4921. https://doi.org/10.1016/S0142-9612(03)00415-0
  4. Cohen, M. S.; Stern, J. M.; Vanni, A. J.; Kelley, R. S.; Baumgart,. E.; Field, D.; Libertino, J. A.; Summerhayes, I. C. Surg. Infect. (Larchmt) 2007, 8, 397. https://doi.org/10.1089/sur.2006.032
  5. Fu, J.; Ji, J.; Fan, D.; Shen, J.; Biomed, J. Mater. Res. A 2006, 79, 665.
  6. Miura, N.; Shinohara, Y. Biochem. Biophys. Res. Commun. 2009, 390, 733. https://doi.org/10.1016/j.bbrc.2009.10.039
  7. Lewinski, N.; Colvin, V.; Drezek, R. Small 2008, 4, 26. https://doi.org/10.1002/smll.200700595
  8. Gopinath, P.; Gogoi, S. K.; Sanpui, P.; Paul, A.; Chattopadhyay, A.; Ghosh, S. S. Colloid. Surf. B Biointerf. 2010, 77, 240. https://doi.org/10.1016/j.colsurfb.2010.01.033
  9. Wang, J.; Rahman, M. F.; Duhart, H. M.; Newport, G. D.; Patterson, T. A.; Murdock, R. C.; Hussain, S. M.; Schlager, J. J.; Ali, S. F. NeuroToxicology 2009, 30, 926. https://doi.org/10.1016/j.neuro.2009.09.005
  10. Wang, R.; Yuan, L.; Macartney, D. H. Chem. Commun. 2006, 2908.
  11. Ott, L. S.; Cline, M. L.; Deetlefs, M.; Seddon, K. R.; Finke, R. G. J. Am. Chem. Soc. 2005, 127, 5758. https://doi.org/10.1021/ja0423320
  12. Herrmann, W. A.; Kocher, C. Angew. Chem. Int. Ed. 1997, 36, 2162. https://doi.org/10.1002/anie.199721621
  13. Aggarwal, A.; Lancaster, N. L.; Sethi, A. R.; Welton, T. Green Chem. 2002, 4, 517. https://doi.org/10.1039/b206472c
  14. Dupont, J.; Fonseca, G. S.; Umpierre, A. P.; Fichtner, P. F. P.; Teixeira, S. R. J. Am. Chem. Soc. 2002, 124, 4228. https://doi.org/10.1021/ja025818u
  15. Choi, D. S.; Kim, D. H.; Shin U. S; Deshmukh, R. R.; Lee, S. G.; Song, C. E. Chem. Commun. 2007, 3467.
  16. Kim, Y. J.; Streitwieser, A. J. Am. Chem. Soc. 2002, 124, 5757. https://doi.org/10.1021/ja025628j
  17. The silver 2-ethylhexylcarbamate complex solution (silver content, 10%) was supplied from Inktec Co. Ltd. (Korea). Alessio, R.; Dell'Amico, D. B.; Calderazzo, F.; Englert, U.; Guarini, A.; Labella, L.; Strasser, P. Helv. Chim. Acta 1998, 81, 219. https://doi.org/10.1002/hlca.19980810204
  18. Jeon, Y.-M.; Gong, M.-S. Macromol. Res. 2009, 17, 2. https://doi.org/10.1007/BF03218592

Cited by

  1. Positively Charged Silver Nanoparticles Threaded on Carbon Nanotube for the Efficient Delivery of Negatively Charged Biomolecules vol.32, pp.10, 2011, https://doi.org/10.5012/bkcs.2011.32.10.3581
  2. Facile Preparation of Nanosilver-decorated MWNTs Using Silver Carbamate Complex and Their Polymer Composites vol.33, pp.2, 2012, https://doi.org/10.5012/bkcs.2012.33.2.483
  3. Ionic liquids and ultrasound in combination: synergies and challenges vol.43, pp.23, 2014, https://doi.org/10.1039/C4CS00193A
  4. Cationic effect of an ionic copolymer with a temperature-responsive charateristic on the LCST value: A broad LCST spectrum of 35 to 46 °C vol.23, pp.11, 2015, https://doi.org/10.1007/s13233-015-3143-9
  5. Silver loading on poly(ethylene terephthalate) fabrics using silver carbamate via thermal reduction vol.23, pp.6, 2015, https://doi.org/10.1007/s13233-015-3069-2
  6. Ionic thermo-responsive copolymer with multi LCST values: easy and fast LCST-change through anion exchange vol.27, pp.4, 2015, https://doi.org/10.1002/pat.3695
  7. Preparation of silver-coated silk fabrics with antibacterial activity using silver carbamate and hydrogen reduction vol.25, pp.8, 2017, https://doi.org/10.1007/s13233-017-5087-8
  8. A new approach for deposition of silver film from AgCl through successive ionic layer adsorption and reaction technique vol.24, pp.12, 2017, https://doi.org/10.1007/s11771-017-3693-4
  9. Acridine Fluorescence Behaviors in Different Polymeric Microenvironments Directed by C2-Proton-Acidity of Imidazolium-Based Ionic Liquids vol.33, pp.8, 2012, https://doi.org/10.5012/bkcs.2012.33.8.2489
  10. Preparation of Highly Stabilized Silver Nanopowders by the Thermal Reduction and Their Properties vol.33, pp.12, 2011, https://doi.org/10.5012/bkcs.2012.33.12.3987
  11. Facile Preparation of Silver Nanoparticles and Application to Silver Coating Using Latent Reductant from a Silver Carbamate Complex vol.34, pp.2, 2011, https://doi.org/10.5012/bkcs.2013.34.2.505
  12. Ionic liquid-assisted sonochemical synthesis of SnS nanostructures vol.588, pp.None, 2011, https://doi.org/10.1016/j.jallcom.2013.11.051
  13. Combination of Ionic Liquid and Sonication: a Fast, Mild and Green Way to Fabricate Europium–doped Lanthanide Nanophosphates vol.1, pp.15, 2016, https://doi.org/10.1002/slct.201600816
  14. Surface Modification of Polyester Fibers by Thermal Reduction with Silver Carbamate Complexes vol.17, pp.8, 2011, https://doi.org/10.1007/s12221-016-5786-3
  15. Ultrasound in Combination with Ionic Liquids: Studied Applications and Perspectives vol.374, pp.4, 2016, https://doi.org/10.1007/s41061-016-0055-x