Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis and Application for Hydrophilic Polyurethane of Non-swelling Type

Non-swelling type의 Hydrophilic polyurethane 합성 및 응용에 관한 연구

  • Received : 2011.05.19
  • Accepted : 2011.06.15
  • Published : 2011.06.27
Download PDF
⟨ Previous Next ⟩

Abstract

In this study, hydrophilic polyurethane (PU) was synthesized by one shot process to get good non-swelling effect and to keep high breathability using reactive silicone oil of mono terminal and bi-terminal types. We also blended non reactive silicone oil with pure hydrophilic PU to compare non-swelling effect and breathability with hydrophilic PU synthesized by the two types of reactive silicone oils. The hydrophilic films were analyzed by nuclear magnetic resonance (NMR) spectroscopy, scanning electron microscope (SEM), Fourier transform infrared (FT-IR) spectroscopy, X-ray photo electron (XPS) spectroscopy, energy dispersive spectrometry (EDS), breathability, waterproofness, tensile strength, contact angle and swelling effect. The results showed that the film made by hydrophilic PU which was synthesized with mono terminal type silicone oil provided good non-swelling effect and acceptable moisture permeability due to the modified surface properties.

Keywords

References

  1. E. A. Kim and S. J. Yu, Breathable Fabrics and Evaluation Technology, Fiber Technology and Industry, 8(3), 271(2004).
  2. A. Mukhopadhyay and V. K. Midha, A Review on Designing the Breathable Waterproof Fabrics part I : Fundamental Principles and Designing Aspects of Breathable Fabrics, J. Industrial Textiles, 37(3), 224-262(2008).
  3. W. O. Lotens, What Breathability Do you need, Symposium, Breathe, Stratford-upon-Avon, June, 1991.
  4. G. Lomax, Design of Water Proof, Water Vapor Permeable Fabrics, J. Coated Fabrics, 15, 115(1985). https://doi.org/10.1177/152808378501500205
  5. G. Lomax, Hydrophilic Polyurethane Coating, J. Coated Fabrics, 20, 88(1990). https://doi.org/10.1177/152808379002000205
  6. J. H. Yang, Transfer Coating Technology with Non-swelling Type Hydrophilic PU, Dyeing and Finishing, 2, 39-50(2007).
  7. Y. C. Jung, J. W. Cho, and B. C. Chun, Preparation and Characteristics of Smart Water Vapor Permeable Fabrics, J. Korean Fiber Society, 34(2), 462-465(2001).
  8. H. J. Chung and G. S. Cho, Manufacture of Water-proof & Vapor-permeable Fabric Treated with Octadecane Containing Microcapsules, and its Properties, J. Korean Fiber Society, 36(2), 92-95(2003).
  9. J. H. Yang and N. S. Yun, The Effect of the Changing Curing System of Hydrophilic PU Resin on the Durability and Performance of Breathable Fabric, KSDF Spring Seminar, pp.101-107, 2003.
  10. W. Y. Jeong and S. K. An, A Study on Physical and Mechanical Properties of Breathable Waterproof Fabrics Manufactured with PTFE Membrane-fabric Composite, J. Korean Society Clothing and Textiles, 26(12), 1685-1693(2002).
  11. P. A. Dolhan, A Comparison of Apparatus used to Measure Water Vapor Resistance, J. Coated Fabrics, 17(10), 96-109(1987). https://doi.org/10.1177/152808378701700204
  12. B. Farnworth and P. A. Dolhan, Apparatus to Measure the Water-vapor Resistance of Textiles, J. Textile Institute, 76(2), 142-145(1984).
  13. B. Farnworth, W. A. Lotens and P. P. Wittgen, Variation of Water Vapor Resistance of Microphorous and Hydrophilic Films with Relative Humidity, Text. Res. J., 61, 50-53(1993).
  14. A. R. Horrocks and S. C. Anand, "Handbook of Technical Textiles", Woodhead Publishing Ltd, pp.287-288, 2000.

Cited by

  1. Preparation of Yacht Sail Using High Tenacity Polyester and Its Performance Evaluation vol.24, pp.1, 2012, https://doi.org/10.5764/TCF.2012.24.1.54
  2. A Study on Processes and Performance Evaluation for IR Camouflage Printed Selectively Permeable Membrane Fabrics vol.26, pp.1, 2014, https://doi.org/10.5764/TCF.2014.26.1.13