DOI QR코드

DOI QR Code

Chemical Characteristics and Particle Size Distribution of PM10 in Iron and Steel Industrial Complex

포항철강공단 미세먼지(PM10)의 입경분포 및 화학적 특성

  • Jung, Jong-Hyeon (Faculty of Health Science, Daegu Haany University) ;
  • Lee, Hyung-Don (Department of Civil and Environmental Engineering, Pusan National University) ;
  • Jeon, Soo-Bin (Department of Civil and Environmental Engineering, Pusan National University) ;
  • Yoo, Jeong-Kun (Dept. of Chemical Engineering, Hanseo University) ;
  • Shon, Byung-Hyun (Dept. of Environmental Engineering, Hanseo University)
  • 정종현 (대구한의대학교 보건학부) ;
  • 이형돈 (부산대학교 사회환경시스템공학과) ;
  • 전수빈 (부산대학교 사회환경시스템공학과) ;
  • 유정근 (한서대학교 화학공학과) ;
  • 손병현 (한서대학교 환경공학과)
  • Received : 2012.07.30
  • Accepted : 2012.11.08
  • Published : 2012.11.30

Abstract

The fine particulate matter($PM_{10}$) concentrations and contents were measured to check the health and environment influential factors in Pohang Iron and Steel Industrial Complex and its vicinities. In addition, the $PM_{10}$ distribution for each year and season was surveyed using the regional air quality monitoring stations. The measuring on the $PM_{10}$ inside the industrial complex showed $61.3{\pm}12.1{\mu}g/m^3$ for average concentration of $PM_{10}$ which was measured by Dongil Industry and $44.3{\pm}8.1{\mu}g/m^3$ measured by steel manufacturing industry complex management office. Both of them satisfied the environmental air quality standard. The percentage of $SO_4{^2}$, $NO_3{^-}$, $NH_4{^+}$ which are the secondary ions created out of the $PM_{10}$ in Dongil Industry and steel manufacturing industry complex management office was checked and it was revealed that the percentage of ${SO_4}^{2-}$ was high and it is considered that the pollution source related with the sulfides exist at the industrial complex. They were in order of ${SO_4}^{2-}$ > $Cl^-$ > $NO_3{^-}$ > $F^-$ > $NH_4{^+}$ in Dongil Industry and ${SO_4}^{2-}$ > $Cl^-$ > $NO_3{^-}$ > $NH_4{^+}$ > $F^-$ in steel manufacturing industry complex management office.

본 논문은 포항철강공단 및 주변지역의 보건 및 환경영향 인자를 확인하기 위하여 미세먼지($PM_{10}$) 농도와 성분을 측정 및 분석하였다. 또한 지역대기자동측정망 자료를 이용하여 연별, 계절별 $PM_{10}$ 농도분포를 조사하였다. 공단지역 내 $PM_{10}$을 측정한 결과, 동일산업에서 측정된 $PM_{10}$ 평균농도는 $61.3{\pm}12.1{\mu}g/m^3$, 철강공단관리사무소에서 측정된 $PM_{10}$ 평균농도는 $44.3{\pm}8.1{\mu}g/m^3$으로 나타나 대기환경기준을 만족하였다. 공단지역 동일산업과 철강공단관리사무소에서 측정된 $PM_{10}$ 중 이차생성 이온인 ${SO_4}^{2-}$, $NO_3{^-}$, $NH_4{^+}$의 분율을 확인한 결과, ${SO_4}^{2-}$의 분율이 높게 나타났고, 황산염과 관련된 오염원이 철강공단지역에 존재하는 것으로 판단된다. 전체적으로 동일산업 지점에서는 ${SO_4}^{2-}$ > $Cl^-$ > $NO_3{^-}$ > $F^-$ > $NH_4{^+}$ 순으로 나타났고, 철강공단관리사무소 지점에서는 ${SO_4}^{2-}$ > $Cl^-$ > $NO_3{^-}$ > $NH_4{^+}$ > $F^-$ 순으로 나타났다.

Keywords

References

  1. Jung, J. H. : A study on reaction characteristic of $SO_2$/NOx simultaneous removal for alkali absorbent/ additive in FGD and waste incinerator process. Pusan National University, Ph.D Dissertation, 1999.
  2. Jung, J. H. : Effects of air pollutants on the health/environmental risk assessment and weathering of stone cultural properties in Gyeongju and its vicinities. Daegu Haany University, Ph.D Dissertation, 2008.
  3. Choi, B. W., Jung, J. H., Choi, W. J., Jeon, C. J., Shon, B. H. : Distribution Characteristics of Ambient Heavy Metals based on the Pollution Source and their Carcinogenic Risk Assessment in Ulsan, Korea. Korean J. of Environmental Health, Vol. 32, No. 5, pp. 522-531, 2006.
  4. Choi, B. W., Jung, J. H., Choi, W. J., Shon, B. H., Oh, K. J. : Characteristics of the Distribution of High Ambient Air Pollutants with Sources and Weather Condition in Ulsan. Korean J. of Environmental Health, Vol. 32, No. 4, pp. 324-335, 2006.
  5. Jung, J. H. : A study on the cause investigation of increasing fine particles (PM10) and reduction plans in Pohang Steel Industrial Complex, GENTEC, 2009.
  6. National Institute of Environmental Research : The monitoring study on exposure level and biomarker of environmental pollutants in the Pohang industrial complex(2nd annual report), 2007.
  7. Song, X.H., A.V. Polissar, and P.K. Hopke : Source of fine particle composition in the northeastern US, Atmos. Environ., 35(31), 5277-5286, 2001. https://doi.org/10.1016/S1352-2310(01)00338-7
  8. U.S. EPA : Taking Toxics Out of the Air, 3-6, 2000.
  9. National Institute of Environmental Research : The monitoring study on exposure level and biomarker of environmental pollutants in the Pohang industrial complex(4th annual report), 2009.
  10. Lee, H. W., Won, G. M., Bae, S. J. : The prediction and evaluation air pollutants concentration around industrial complex by using atmospheric dispersion models. Journal of the Environmental Sciences, 8(4), 485-490, 2004.
  11. Monthly weather report : http://www.kma.go.kr/, Accessed March 30, 2010.
  12. National Institute of Environmental Research : The monitoring study on exposure level and biomarker of environmental pollutants in the Pohang industrial complex(5th annual report), 2010.
  13. Yoon-Kyeung Heo, Characterization of physical and chemical composition of fine particulate matter in the ambient air of Pohang area, Yeungnam University, M.S. Thesis, pp. 85, 2004.
  14. Byung-Uk Kang, Hak-Seong Lee, Hee-Kang-Kim, A Seasonal Variation of Acidic Gases and Fine Particle Species in Chongju Area, Journal of Korea Air Pollution Research Association, 13(5), pp. 333-343, 1997.
  15. National Institute of Environmental Research : Annual report of air quality in korea 2009, 2010.
  16. Byung-Uk Kang, Hak-Seong Lee, Hee-Kang-Kim, Source Identification of Fine particle ($PM_{2.5}$) in Chongju Using a Chemical Mass Balance Model, Journal of Korean Society for Atmospheric Environment, 16(5), pp. 477-585, 2000.

Cited by

  1. Exposure Assessments of Environmental Contaminants in Ansim Briquette Fuel Complex, Daegu(I) - Effect zone of environmental pneumoconiosis and fugitive dust - vol.25, pp.3, 2015, https://doi.org/10.15269/JKSOEH.2015.25.3.366
  2. Exposure Assessments of Environmental Contaminants in Ansim Briquette Fuel Complex, Daegu(II) - Concentration distribution and exposure characteristics of TSP, PM10, PM2.5, and heavy metals - vol.25, pp.3, 2015, https://doi.org/10.15269/JKSOEH.2015.25.3.380
  3. Exposure Assessments of Environmental Contaminants in Ansim Briquette Fuel Complex, Daegu(III) - Contribution and distribution characteristics of air pollutants according to elemental carbon, crystalline silica, and stable isotope ratio - vol.25, pp.3, 2015, https://doi.org/10.15269/JKSOEH.2015.25.3.392