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Analysis of Electrical and Physical Property of the PU/MWNT Film and Dispersion Characteristics of MWNT According to the Solvent

용매에 따른 MWNT의 분산특성과 제조된 PU/MWNT 필름의 전기적·물리적 특성 분석

  • 김정현 (영남대학교 섬유패션학부) ;
  • 마혜영 (영남대학교 섬유패션학부) ;
  • 양성용 (영남대학교 섬유패션학부) ;
  • 김승진 (영남대학교 섬유패션학부)
  • Received : 2011.11.30
  • Accepted : 2012.02.03
  • Published : 2012.03.27

Abstract

This paper surveys the physical properties of the MWNT dispersion solution dispersed with the three types of solvents and of the polyurethane composite film for improvement of mechanical properties and electrical characteristics of PU/MWNT composite film. For this purpose, the MWNT dispersed solution was mixed with three types of solvent such as IPA, MEK and Toluene and then mixed with polyurethane (100part) with variation of loading content (0, 10, 20, 30, 40, 50 part) of MWNT dispersed solution in the ultrasonic wave dispersion apparatus. And eighteen PU/MWNT composite films were prepared as specimens. The various physical properties of these PU/MWNT films were measured and discussed with the loading content of three types of MWNT dispersed solutions. The highest absorbancy among the three types of dispersed solutions was shown in the IPA/MWNT solution. But the absorbancy of PU/MWNT films was not same as the solution. The low electrical surface and volume resistivity of PU/MWNT film were shown at the condition of 20 and 10 parts loading of IPA/MWNT dispersed solution, respectively. The low triboelectricity of PU/MWNT film was shown at the condition of above 30part loading of IPA/MWNT dispersed solution. The breaking strength and strain of PU/MWNT film prepared with IPA/MWNT dispersed solution were decreased with increasing loading content of IPA/MWNT from 10 to 40 parts. The maximum breaking strength and breaking strain according to the dispersion solution were shown on the IPA/MWNT dispersed solution. The uniform dispersion of PU/MWNT film according to the loading content of MWNT solution was shown by surface image analysis on the films dispersed with IPA.

Keywords

References

  1. G. W. Lee and J. T. Han, Dispersion of Carbon Nanotubes(CNTs) and CNT-based Transparent Conductive Films, KIC News, 10(4), 8-19(2007).
  2. D. O. Kim and J. D. Nam, Polymeric Carbon Nanotube Nanocomposites, Prospectives of Industrial Chemistry, 9(6), 3-13(2006).
  3. J. Liu, A. G. Rinzler, H. J. Dai, J. H. Hafner, R. K. Bradley, P. J. Boul, A. Lu, T. Iverson, K. Shelimov, C. B. Huffman, F. Rodriguez Macias, Y. S. Shon, T. R. Lee, D. T. Colbert, and R. E. Smalley, Fullerene Pipes, Science, 280, 1253-1256 (1998). https://doi.org/10.1126/science.280.5367.1253
  4. S. H. Kim, X. Wang, S. C. Lee, and B. G. Min, Rhelogical Properties and Eletrospinning of PVA/ CNT Aqueous Solution, Textile Science and Engineering (J. Korean Fiber Society), 43, 251-256(2006).
  5. J. W. Kim, Y. C. Jung, and J. W. Cho, Carbon Nanotube-Polyurethane Nanocomposites Having Characteristics of Electroactive Shape Recovery, Textile Science and Engineering(J. Korean Fiber Society), 42, 270-276(2005).
  6. J. Y. Won, M. H. Jee, S. H. Park, Y. G. Jeong, and D. H. Baik, Preparation and Characterization of CNT-coated Conductive Fibers, Textile Science and Engineering(J. Korean Fiber Society), 46, 1-7 (2009).
  7. M. Jung and J. H. Cho, Mechanical, Thermal and Electrical Properties of Carbon Nanotube-Polyurethane Nanocomposites, Textile Science and Engineering(J. Korean Fiber Society), 41, 73-79(2004).
  8. M. S. Kang, S. M. Kwon, D. Y. Kim, H. S. Kim, and H. J. Jin, Preparation of Electrospun Poly (hexamethylene sebacamide)/Multiwalled Carbon Nanotube Nanofibrous Membranes, Textile Science and Engineering(J. Korean Fiber Society), 45, 159- 165(2008).
  9. H. Kitano, K. Tachimoto, and Y. Anraku, Functionalization of Single-walled Carbon Nanotube by the Covalent Modification with Polymer Chains, J. Colloid Interface Sci., 306, 28-33(2007). https://doi.org/10.1016/j.jcis.2006.10.034
  10. S. Musso, S. Porro, M. Vinante, L. Vanzetti, R. Ploeger, M. Giorcelli, B. Possetti, F. Trotta, C. Pederzolli, and A. Tagliaferro, Modification of MWNTs Obtained by Thermal- CVD, Diamond & Related Materials, 16, 1183-1187(2007). https://doi.org/10.1016/j.diamond.2006.11.087
  11. T. Saito, K. Matsushige and K. Tanaka, Chemical Treatment and Modification of Multiwalled Carbon Nanotubes, Physical B, 323, 280-283(2002). https://doi.org/10.1016/S0921-4526(02)00999-7
  12. A. Hirsch, Functionalization of Single-Walled Carbon Nanotubes, Angew Chem. Int. Ed., 41, 1853-1859 (2002). https://doi.org/10.1002/1521-3773(20020603)41:11<1853::AID-ANIE1853>3.0.CO;2-N
  13. M. Olek, M. Hilgendorff, and M. Giersig, A Simple Route for the Attachment of Colloidal Nanocrystals to Noncovalently Modified Multiwalled Carbon Nanotubes, Colloids and Surfaces A: Physicochem Eng. Aspects, 292, 83-85(2007). https://doi.org/10.1016/j.colsurfa.2006.05.014
  14. I. Kumar, S. Rana, C. V. Rode, and W. Cho, Functionalization of Single-Walled Carbon Nanotubes with Azides Derived from Amino Acids Using Click Chemistry, Journal of Nanoscience and Nanotechnology, 8, 1-6(2008). https://doi.org/10.1166/jnn.2008.N03
  15. Y. Noguchi, T. Fujigaya, Y. Niidome, and N. Nakashima, Single-walled Carbon Nanotubes/DNA Hybrids in Waterare Highly Stable, Chemical Physics Letters, 455, 249-251(2008). https://doi.org/10.1016/j.cplett.2008.02.089
  16. K. S. Park, S. J. Kim, J. H. Kim, J. H. Park, and O. K. Kwon, Modification of Carbon Nanotube for the Improvement of Dispersion and the Dispersion Characteristics of Carbon Nanotube in Polyurethane, Textile Coloration and Finishing(J. of Korean Soc. Dyers & Finishers), 22(1), 43-50(2010). https://doi.org/10.5764/TCF.2010.22.1.043
  17. J. H. Kim, J. H. Park and S. J. Kim, The Physical Property of MWNT/PU Composite Films, Textile Coloration and Finishing(J. of Korean Soc. Dyers & Finishers), 22(3), 246-256(2010). https://doi.org/10.5764/TCF.2010.22.3.246
  18. J. H. Park, J. H. Kim and S. J. Kim, Manufacturing and Characteristics Analysis of PU/MWNT Composite Film for Forming, Textile Coloration and Finishing(J. of Korean Soc. Dyers & Finishers), 22(4), 362-372(2010). https://doi.org/10.5764/TCF.2010.22.4.362

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