Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Determination of trace level carbonate ion in Mg-Al layered double hydroxide:Its significance on the anion exchange behaviour

  • Published : 2012.11.25
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Abstract

The presence of trace level (<1 ppm) carbonate ion in the interlayer space of MgAl-LDH has been estimated by ion chromatography technique using a novel inverse chemical suppression method using 0.5 mM $H_2SO_4$ as mobile phase and 25 mM LiCl as regenerating solution. The presence of carbonate ion in the LDH structure was found to affect the anion exchange capacity of MgAl-LDH. This has been illustrated by carrying out anion exchange of nitrate ion in the MgAl-LDH structure with chloride ion. The importance of this simple but accurate technique for the carbonate ion estimation is demonstrated and reported in this communication.

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