DOI QR코드

DOI QR Code

Relationship between Structure and Optical Properties in the $CdO-B_2O_3-SiO_2$ Glass System

  • Kim, Taehee (Department of Materials Science and Engineering, Pusan National University) ;
  • Gwoo, Donggun (Department of Materials Science and Engineering, Pusan National University) ;
  • Kim, Jonghwan (Department of Materials Science and Engineering, Pusan National University) ;
  • Choi, Wongyu (Department of Materials Science and Engineering, Pusan National University) ;
  • Han, Kyungseok (Department of Materials Science and Engineering, Pusan National University) ;
  • Kee, Kyungbum (Department of Materials Science and Engineering, Pusan National University) ;
  • Hwang, Chawon (Department of Materials Science and Engineering, Pusan National University) ;
  • Ryu, Bong-Ki (Department of Materials Science and Engineering, Pusan National University)
  • Published : 2012.12.20

Abstract

To study the compositional dependence of the optical properties and atomic structure of glasses, the $CdO-B_2O_3-SiO_2$ ternary glasses, which are known as highly photoconductive glasses, have been investigated. The photoconductivity of glasses containing CdO was investigated in a previous study, because of their potential applications in photoelectronic devices. The thermo-mechanical analysis and the Fourier transform infrared (FT-IR) spectra of the glass samples were measured to determine the structural variation of these glasses. Using transmittance measurements, we calculated the optical energy band gap. This paper presents results for control of the optical energy band gap 3.8 ~ 3.2 eV in cadmium-borosilicate glass system while the structural properties undergo monotonic changes.

Keywords

References

  1. E. P. Denton, H. Rawson, and J. E. Stanworth, Nature 173, 1030 (1954).
  2. Bh. V. Janakirama-rao, J. Amer. Ceram. Soc. 48, 311 (1965). https://doi.org/10.1111/j.1151-2916.1965.tb14748.x
  3. K. W. Hanson, J. Electrochem. Soc. 112, 994 (1965). https://doi.org/10.1149/1.2423358
  4. T. N. Kennedy and J. D. Mackenzie, Phys. Chem. Glass 8, 169 (1967).
  5. D. W. Strickler and R. Roy, J. Mater. Sci. 6, 200 (1971). https://doi.org/10.1007/BF00550013
  6. F. M. Nazar, M. A. Ghauri, and W. H. Bokhari, Int. J. Electron. 50, 193 (1981). https://doi.org/10.1080/00207218108901245
  7. N. F. Mott and E. A. Davis, Electronic Processes in Non- Crystalline Materials, p. 370, Clarendon Press, Oxford (1970).
  8. F. Urbach, Phys. Rev. 92, 1324 (1953).
  9. N. Kenny, C. R. Kannewurf, and D. H. Whitemore, J. Phys. Chem. Solids. 27, 1237 (1966). https://doi.org/10.1016/0022-3697(66)90007-2
  10. M. A. Ghauri, F. M. Nazar, and W. H. Bokhari, J. Non-Cryt. Solids. 46, 197 (1981). https://doi.org/10.1016/0022-3093(81)90160-5
  11. N. Kim, S. Im, D. Kim, D. Yoon, and B. Ryu, Electron. Mater. Lett. 6, 103 (2010). https://doi.org/10.3365/eml.2010.09.103
  12. D. Kim, C. Hwang, D. Gwoo, T. Kim, N. Kim, and B. Ryu, Electron. Mater. Lett. 7, 343 (2011). https://doi.org/10.1007/s13391-011-0710-x
  13. E. Rivera, L. E. Celaya, and J. Ma. Rincon, Mater. Lett. 5, 185 (1987). https://doi.org/10.1016/0167-577X(87)90005-X
  14. T. D. Lonsdale and A. Whitaker, J. Mater. Sci. 13, 1503 (1978). https://doi.org/10.1007/BF00553206
  15. V. Caslavska, D. Strickler, D. Gibbon, and R. Roy, J. Mater. Sci. 3, 440 (1968). https://doi.org/10.1007/BF00550989
  16. F. M. Nazar, Int. J. Electron. 54, 369 (1983). https://doi.org/10.1080/00207218308938735
  17. F. M. Nazar, M. A. Ghauri, and W. H. Bokhari, Int. J. Electron. 54, 583 (1983). https://doi.org/10.1080/00207218308938758

Cited by

  1. Structural, Optical, and Chemical Properties of Cadmium Phosphate Glasses vol.52, pp.2, 2012, https://doi.org/10.4191/kcers.2015.52.2.128
  2. Physical, structural and optical characterization of silicate modified bismuth-borate-tellurite glasses vol.1127, pp.None, 2012, https://doi.org/10.1016/j.molstruc.2016.08.033