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Preparations Purified Cellulose from Rice Hull

왕겨기반 고순도 셀룰로오스의 제조

  • Lee, Young-Ju (Dept. of Biobased Materials, College of Agriculture and Life Science, Chungnam Natl. Univ.) ;
  • Sung, Yong-Joo (Dept. of Biobased Materials, College of Agriculture and Life Science, Chungnam Natl. Univ.)
  • 이영주 (충남대학교 농업생명과학대학 환경소재공학과) ;
  • 성용주 (충남대학교 농업생명과학대학 환경소재공학과)
  • Received : 2012.06.05
  • Accepted : 2012.06.20
  • Published : 2012.06.30

Abstract

In this study, purified cellulose was prepared from rice husk which is one of the major agricultural residues in Korea. The various bleaching processes such as ozone bleaching, $ClO_2$ bleaching and $H_2O_2$ bleaching were applied to remove residual lignin and impurities. In order to increase the contents of ${\alpha}$-cellulose contents, the effects of acid and alkali treatments were evaluated. Although the multi stages of the bleaching processes resulted in less than 0.5 % residual lignin contents, the application of ozone leaded to the decrease in DP(degree in Polymerization) and ${\alpha}$-cellulose contents. The alkali treatment after bleaching processes resulted in pure cellulose which showed more than 98% of ${\alpha}$-cellulose contents.

Keywords

References

  1. 김용진, 윤정준, 김상현, 신명교, 김경수, 해양바이오 에너지, BT Newsm 16(1) :6-33 (2009).
  2. Samir, A.S.A.S., Fannie Alloin, F., Dufresne, A., Review of Recent Research into Cellulosic Whiskers, Their Properties and Their Application in Nanocomposite Field, Biomacromolecules, 6(2) : 612-626 (2005). https://doi.org/10.1021/bm0493685
  3. Henriksson, G., Christiernin, M., Agnemo, R., Monocomponent endoglucanase treatment increases the reactivity of softwood sulphite dissolving pulp, Journal of Industrial Microbiology & Biotechnology, 32(5): 211-214 (2005) https://doi.org/10.1007/s10295-005-0220-7
  4. Christov, L.P., Akhtar, M., Prior, B.A., The potential of biosulfite pulping in dissolving pulp production, Enzyme and Microbial technology 23(1): 70-74 (1998). https://doi.org/10.1016/S0141-0229(98)00017-9
  5. He, J., Cui, S., Wang, S.-Y., Preparation and crystalline analysis of high-grade bamboo dissolving pulp for cellulose acetate, J. of Applied Polymer Science, 107(2):1029-1038 (2008). https://doi.org/10.1002/app.27061
  6. Montanea, D., Farriola, X., Salvadoa, J., Jollezb, P., Chornetb, E., Fractionation of Wheat Straw by Steam-Explosion Pretreatment and Alkali Delignification. Cellulose Pulp and Byproducts from Hemicellulose and Lignin, Journal of Wood Chemistry and Technology 18(2): 171-191 (1998). https://doi.org/10.1080/02773819809349575
  7. Sung, Y.J., Shin, S.J., Oh M-T., Chemical Composition of Rice Hull and Morphological Properties of Rice Hull Fibers, Journal of Korea TAPPI 41(3): 22-28 (2009).
  8. Paik, K-H., Kim, D.H., Kang, C-H., Alkaline Sulfite Pulping with the addition of anthraquinone and methanol(III), Journal of Korea TAPPI, 27(1): 23-31 (1995).
  9. Kang-Jae Kim., Tae-Jin Eom., Chemical Characteristics of Ozone Treated Pine Wood Meal, Journal of Korea TAPPI 43(1): 23-28 (2011).
  10. Lee, M.W., Park, J.S., Park, D.H., Seo, Y.B., Comparison of cellulose DP measurements using the CED (Cupriethylene diamine) and NMMO (N-methylmorpholine-N-oxide), Journal of Korea TAPPI 42(5): 62-65(2010).