Journal of Conservation Science (보존과학회지)

The Korean Society Of Conservation Science For Cultural Heritage (한국문화재보존과학회)
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Analysis of Dyes and Mordants of 16~17th Century Textiles Excavated from Daejeon

16~17세기 출토염직품의 염료와 매염제 분석

  • Baek, Young-Mee (The Korean Traditional Costume Research Institute, Pusan National University) ;
  • Kwon, Young-Suk (Department of Clothing and Textiles, Pusan National University) ;
  • Goto-Doshida, Sumiko (Department of Home Economics, Aikoku Gakuen Junior College) ;
  • Saito, Masako (Department of Textile and Clothing, Kyoritsu Women's University)
  • 백영미 (부산대학교 한국전통복식연구소) ;
  • 권영숙 (부산대학교 의류학과) ;
  • ;
  • Received : 2012.04.03
  • Accepted : 2012.05.25
  • Published : 2012.06.20
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Abstract

Excavated textiles provide very important research data on the costume culture of the Joseon dynasty. In particular, dyed textiles are indispensable for textile conservation research and for restoration of remains as well as for general costume culture research. Unfortunately, a prolonged burial environment causes the colors to change and gradually fade after excavation. Therefore, it is very difficult to identify the original color. In this study, natural dyed samples of red, yellow, purple and blue were prepared and analyzed using HPLC-PDA. Dyes of colorants extracted from excavated textile remains were analyzed by HPLC. In addition, mordants were analyzed using (SEM-EDX) in order to estimate the original color. The 16~17th Century's three samples were analyzed, sample 1, and 2 from Eunjin Song's Song Mun-Chang excavated at the Songchon-dong in Daejeon, and sample 3 from Yeosan Song's Song, Hee-Jong excavated at the Mokdal-dong in Daejeon. From the HPLC results, alizarin, purpurin, and indigo were detected on sample 1, alizarin and purpurin on sample 2, ellagic acid and indigo on sample 3. Therefore they were dyed with madder and indigo (sample 1), madder (sample2), pomagranted and indigo (sample 3). Al mordant was identified on three samples.

출토복식은 조선시대 복식문화를 알 수 있는 중요한 자료들이다. 그 중에서도 염직물들은 복식의 문화사적 연구뿐만 아니라 보존과학적 연구 및 유물복원을 위해 꼭 필요한 자료들이다. 그러나 매장환경에서 오랜 기간 동안 영향을 받으면서 색은 변퇴색되었으며 발굴 후에도 점차 퇴색되어가므로 본래의 색을 추정하기가 어렵다. 이에 본 연구에서는 적색, 황색, 자색, 청색의 천연염색포 표준시료를 제작하여 고속액체크로마토그래피(High Performance Liquid Chromatography with Photodiode Array Detector, 이하 HPLC-PDA)에 의해 분석하고, 같은 방법으로 출토염직물에 남아있는 색소를 추출하여 분석함으로써 출토직물의 염료분석을 시행하였으며 당시의 색을 추정하기 위해 전자현미경(Scanning electron microscope 이하 SEM)에 연결된 에너지 분산형 원소분석장치(Energy Dispersive X-ray Spectroscopy 이하 EDX)를 이용하여 매염제 분석을 시행하였다. 본 실험을 위해 16~17세기 출토직물편으로 대전시 송천동 출토 은진송씨 송문창 출토직물 2점과 대전시 목달동 출토 여산송씨 송희종 출토직물 1점 등 3점을 사용하였으며, 분석결과 alizarin, purpurin, indigo, ellagic acid 등의 색소가 검출되어 꼭두서니-쪽의 중복염색, 꼭두서니 염색, 석류-쪽의 중복염색 등의 결과를 얻을 수 있었으며 매염제로는 모든 유물에서 Al이 검출되었다.

Keywords

References

  1. M.S. Lee, M.J. Park, S.W. Bae, Y.H. Lee, "Analysis of Buried-Fabrics from the Tomb of Kim HeumJo by Physical, Chemical and Biological Methods". Journal of the Korean Socity of Clothing and Textiles, 23, pp.809-819, (1999).
  2. S. Ushida and Yuka Tanigami, "A Simple Method for Discriminating between Natural Indigo Dyeing and Synthetic Indigo Dyeing by Means of TLC". Japan Society of Home Economics, 49, pp.1129-1130, (1998).
  3. H. Schweppe, "Identification of Red Madder and Insect Dyes by Thin-Layer Chromatography, Historic textile and paper materials II". ACD Symposium Series, 410, p189, (1989).
  4. J. Poulin, "Identification of Indigo and its Degradation Products on a Silk Textile Fragment Using Gas Chromatography-Mass Spectrometry". Journal of the Canadian Association for Conservation, 32, pp.48-56, (2007).
  5. C.S. Ahn, "Analysis of the Degradation Products of Turmeric using GC-MS". Journal of the Korean Society of Clothing and Textiles, 31, pp.859-868, (2007). https://doi.org/10.5850/JKSCT.2007.31.6.859
  6. C.S. Ahn, S. Kay Obendorf, "Analysis of Degradation Products in Madder Dyed Fabrics in Selective Degradation Conditions". Journal of the Korean Society of Clothing and Textiles, 29, pp.1608-1618, (2005).
  7. C.S. Ahn, "Analysis of the Extracted Non-fibrous Matters from the Exhumed Textiles of Milchang-gun Burial of Mapo". The Research Journal of the Costume Culture, 11, pp.902-912, (2003).
  8. Y. Sasaki, K. Fujii, K. Sasaki, "Non-destructive Analysis for 17th Century Traditional Japanese Textile, White Ground Satin with Design of Snow, Crests, and Chrysanthemums". Journal of the Japan Society for the Conservation of Cultural Property, 53, p.35-53, (2008).
  9. H. Yu, E. Yun, Y. Kim, "Analysis of Yellow Tradi- tional Dye using Nondestructive Ultravioletvisible and Fluorescence Spectrophotometry". Conservation Science in Museum, 11, p.61-72, (2010).
  10. Y. Lee, J. Lee, Y. Kim, S. Choi, S. W. Ham, K.J. Kim, "Investigation of natural dyes and ancient textiles from korea using TOF-SIMS". Applied Surface Science, 255, p.1033-1036, (2008). https://doi.org/10.1016/j.apsusc.2008.05.097
  11. B.Y. Lee, "A TOF-SIMS Study on Artificially Aged Fabrics". Seoul National University, (2010).
  12. M. Ishii, I. Nagasaki, N. Ito, M. Saito, "HPLC analysis of natural yellow dyes and the identification of yellow and green dyes in Edo period kosode (Kimono)". Journal of the Japan Society for the Conservation of Cultural Property, 49, p.41-58, (2005).
  13. J. Wouters, "High performance liquid chromatography of anthraquinones: analysas of plant nad insect extracts and dyed textiles". Studies in Conservation, 30, p.119-128, (1985). https://doi.org/10.2307/1505927
  14. A. Serrano, M.M. Sousa, J. Hallett, J. Lopes, M.C. Oliveria, "Analysis of natural red dye(cocheneal) in textiles of historical importance using HPLC and multivariate data analisis". Anal Bioanal Chem, 401, p.735-743, (2011). https://doi.org/10.1007/s00216-011-5094-0
  15. E. Sanz Rodriguez, A. Arteaga Rodriguez, M. A. Garcia Rodriguez, M. del Egido and C. Camara, "Identification of Natural Dyes in Historical Coptic Textile from the National Archaeological Museum of Spain". e-conservation magazine, 15, p.32-45, (2010).
  16. M. Komatsu, F. Nishioka, M. Saito, "Identification of red dyes and mordents used in 12th to 19th centuries Japanese armor". Journal of the Japan Society for the Conservation of Cultural Property, 49, p.25-40, (2005).
  17. M. Ishii, I. Nagasaki, N. Ito, M. Saito, "HPLC analysis of natural yellow dyes and the identification of yellow and green dyes in Edo period kosode (Kimono)". Journal of the Japan Society for the Conservation of Cultural Property, 49, p.41-58, (2005).
  18. Y. Fukuoka, M. Saito, "Scientific Analysis and Historical Context of a Scarlet Woolen Jinbaori (Military Campaign Coat) with a Crest of Janome in the Collection of Kyoritsu Women's University". Costume and Textile, 6, p.21-29, (2005).
  19. Y. Fukuoka, M. Saito, "Colors, Dyes and Mordents on Imported Red Woolen Fabrics Applied for Jinbaori from Edo Period". Journal of the Japan Society for the Conservation of Cultural Property, 51, p38-50, (2006).
  20. N. Kasasaku, N. Ito, M. Saito, "Characterization of early Synthetic Dyes by HPLC and Identification of Red and Violet Dyes on American Antique Quilts". Costume and Textiles, 7, p.35-46, (2006).
  21. M. Ishii, M. Saito, "HPLC Analysis of Natural Yellow Dyes in 18th Century French Silk Textile". Journal of the Japan Society for the Conservation of Cultural Property, 52, p.37-52, (2007).
  22. Y. Fukatsu, N. Kasasaku, M. Saito, "Scientific Analysis of Materials and Techniques in Purple Woolen Fabrics Used for Japanese Campaign Coat from the Edo Period". Journal of the Japan Society for the Conser- vation of Cultural Property, 53, p.20-34, (2008).
  23. D. Cardon, "Natural Dyes-Sources, Tradition, Techno- logy and Science". Archetype Publication Ltd., London, p694, (2007).
  24. K.R. Cho, "Commentary of the Traditional Dye in KYUHAPCHONGSEO". Korea Studies Information Co. Ltd., p.129-130, (2007).
  25. S. Usida, M. Ohta, "Extraction and Analysis of Red Pigments in Sukumo, Japanese Indigo Dye". Journal of Japan Society of Home Economics, 46, p.1167-1171, (1995).
  26. Zvi C. Koren, "HPLC-PDA analysis of brominated indirubinoid, indigoid, and isatinoid dyes, Indirubin, the ed shade of indigo". Life in Progress Editions, Roscoff, France, Ch. 5, p.45-53, (2006).
  27. I.M. Chung, K.G. Lee, G.B. Sung, H.B. Kim, S.H. Nam, I.P. Hong, "Structural Analysis of Natural Indigo Colorants Extracted from Polygonum tinctorium". Korean J. Scric. Sci, 49, p.8-13, (2007).
  28. M. Saito, M. Uehara, K. Yamazaki, "Components of Mordants and the Silk Fabrics Treated with Them". Dyes in History and Archaeology, 20, p.95-101, (2005)

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