Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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Characteristics of β--cyclodextrin Finished Nylon and PET Fabrics

β-cyclodextrin 가공 나일론 직물과 PET 직물의 특성

  • Chung, Hae-Won (Department of Clothing and Textiles, Inha University) ;
  • Hwang, Na-Won (Department of Clothing and Textiles, Inha University)
  • Received : 2012.02.10
  • Accepted : 2012.03.31
  • Published : 2012.04.30
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Abstract

${\beta}$-CD is produced from starch through enzymatic degradation, and therefore it is an eco-friendly material and isn't harmful to the body. Nylon and PET fabrics are being increasingly used in active wear, as customers prefer this more comfortable and multifunctional material, as it provides antimicrobial properties and the removal of body malodor. That being said, ${\beta}$-CD is a proper material for these purposes. The ${\beta}$-CD was applied to a nylon 66 fabric and a PET fabric which were not pre-modified, and also applied to the fabrics that were modified with $O_2$ plasma or alkaline solution in order to increase surface roughness. The characteristics of these fabrics were studied. The PET fabric, which was pretreated with a NaOH solution, gains more weight than the PET fabric without pretreatment by the ${\beta}$-CD finishing. A crosslink between nylon 66 or the PET fiber and the ${\beta}$-CD finishing agent was not formed; however, the crosslink was formed in cotton fibers. This was confirmed using FT-IR and TGA analysis. The whiteness decreased little, the value of WT and MIU decreased, and that of B and RT increased with the ${\beta}$-CD finish. All of the ${\beta}$-CD finished fabrics had washing fastness after 10 washing cycles, even though nylon 66 and the PET fibers were not crosslinked with the ${\beta}$-CD finishing agent.

Keywords

References

  1. H.-J. Buschmann, D. Knittel, and E. Schollmeyer, "New Textile Applications of Cyclodextrins", J Incl Phenom Macrocycl Chem, 2001, 40(3), 169-172. https://doi.org/10.1023/A:1011892600388
  2. J. Szejtli, J. L. Atwood, and J.-M. Lehn, Ed., "Comprehensive Supramolecular Chemistry", Vol. 3, Pergamon, New York, 1996, p.190.
  3. B. Martel, D. Ruffin, M. Weltrowski, Y. Lekchiri, and M. Morcellet, "Water-Soluble Polymers and Gels from the Polycondensation between Cyclodextrins and Poly(carboxylic acid)s: A Study on the Preparation Parameters", J Appl Polym Sci, 2005, 97, 433-442. https://doi.org/10.1002/app.21391
  4. B. Voncina, V. Vivod, and W. Chen, "Surface Modification of PET Fibers with the Use of ${\beta}$-Cyclodextrin", J Appl Polym Sci, 2009, 113(6), 3891-3895. https://doi.org/10.1002/app.30400
  5. B. Vocina and A. Marechal, "Grafting of Cotton with ${\beta}$-Cyclodextrin via Poly(carboxylic acid)", J Appl Polym Sci, 2005, 96, 1323-1328. https://doi.org/10.1002/app.21442
  6. I. Shown and C. N. Murthy, "Grafting of Cotton Fiber by Water-Soluble Cyclodextrin Based Polymer", J Appl Polym Sci, 2009, 111, 2056-2061. https://doi.org/10.1002/app.29162
  7. J. Ko, Y. Park, J. Kim, and Y. Kim, "Synthesis of ${\beta}$-Cyclodextrin Derivative Containing Cyanuric Chloride Moiety and Its Application to Fragrant Finish of Textiles", Text Sci Eng, 2007, 44(4), 183-188.
  8. E. Kumbasar, R. Atav, and A. Yurdakul, "Equalizing Effect of ${\beta}$-Cyclodextrin on Dyeing of Polyamide 6,6 Woven Fabrics with Acid Dyes", J Appl Polym Sci, 2009, 103, 2660-2668.
  9. L. Ducoroy, M. Bacquet, B. Martel, and M. Morcellet, "Removal of Heavy Metals from Aqueous Media by Cation Exchange Nonwoven PET Coated with ${\beta}$-Cyclodextrin- Polycarboxylic Moieties", Reactive Functional Polymers, 2008, 68(2), 594-600. https://doi.org/10.1016/j.reactfunctpolym.2007.10.033
  10. N. Blanchemain, T. Laurent, F. Chai, C. Neut, S. Haulon, V. Krump-konvalinkova, M. Morcellet, B. Martel, C. J. Kirkpatrick, and H. F. Hildebrand, "Polyester Vascular Prostheses Coted with a Cyclodextrin Polymer and Activated with Antibiotics: Cytotoxicity and Microbiological Evaluation", Acta Biomaterialia, 2008, 4(6), 1725-1733. https://doi.org/10.1016/j.actbio.2008.07.001
  11. Y. E. Ghoul, N. Blanchemain, and T. Laurent, "Chemical, Biological and Microbiological Evaluation of Cyclodextrin Finished Polyamide Inguinal Meshes", Acta Biomaterialia, 2008, 4(5), 1392-1400. https://doi.org/10.1016/j.actbio.2008.02.019
  12. A. Fathi-Azarbayjani and S. Chan, "Single and Multi-Layered Nanofibers for Rapid and Controlled Drug Delivery", Chem Pharm Bull, 2010, 58(2), 143-146. https://doi.org/10.1248/cpb.58.143
  13. R. Gref, C. Amiel, K. Molinard, S. Daoud-Mahammed, B. Sebille, B. Gillet, J. Beloeil, C. Ringard, V. Rosilio, J. Poupaert, and P. Couvreur, "New Self-assembled Nanogels based on Host-guest Interactions: Charaterization and Drug Loading", J Controlled Release, 2006, 111, 316-324. https://doi.org/10.1016/j.jconrel.2005.12.025
  14. L. Martha, Y. Kamath, S. Wesson, and S. Ruetsch, "Surface Energetics of Nylon 66 Fibers", J Colloid Interface Sci, 1996, 177, 579-588. https://doi.org/10.1006/jcis.1996.0072
  15. Z. Zhu and M. Kelley, "IR Spectroscopic Investigation of the Effect of Deep UV Irradiation on PET Films", Polymer, 2005, 46(20), 8883-8891. https://doi.org/10.1016/j.polymer.2005.05.135
  16. L. Ducoroy, B. Martel, M. Bacquet, and M. Morcellet, "Cation Exchange Finishing of Nonwoven Polyester with Polycarboxylic Acids and Cyclodextrins", J Appl Polym Sci, 2007, 103, 3730-3738. https://doi.org/10.1002/app.25249
  17. A. A. Okeil, "Citric Acid Crosslinking of Cellulose Using $TiO_2$ Catalyst by Pad-Dry-Cure Method", Polymer-Plastics Tech Eng, 2008, 47, 174-179. https://doi.org/10.1080/03602550701816126
  18. S. Y. Yang, H. Kim, and S. J. Kim, "The Synthesis of Onestep Type Hydrophilic Non-porous Polyurethane Resin and the Physical Property of Its Coated Fabric for the Garment", Text Coloration Finishing, 2011, 23(2), 131-139. https://doi.org/10.5764/TCF.2011.23.2.131
  19. Y. H. Kim and J. W. Choi, "Antimicrobial Finishes of Textiles with Poly(hexamethylene guanidine hydrochloride) Containing Silicone Reactive Groups-Effects of Treatment Methods and Kind of Fibers on the Laundering Durability-", J Korean Fiber Soc, 2001, 38(8), 410-419.

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