DOI QR코드

DOI QR Code

Preparation of Dye Sensitized Solar Cell Using Coumarin Dyes Extracted from Plants

식물에서 추출한 천연 쿠마린계 염료를 이용한 염료감응 태양전지의 제조

  • Jung, Onyu (Korean Minjok Leadership Academy) ;
  • Lee, Sang-Soo (Photo-electronic Hybrid Research Center, Korea Institute of Science and Technology)
  • 정온유 (민족사관고등학교) ;
  • 이상수 (한국과학기술연구원 광전하이브리드연구센터)
  • Received : 2012.08.19
  • Accepted : 2012.09.20
  • Published : 2013.02.01

Abstract

Low priced and environment-friendly natural dye from coumarin- containing plants for the dye sensitized solar cell (DSSC) was developed. Dyes were extracted from cinnamon and angelica that contained coumarin derivatives, and DSSCs employing these dyes were prepared. PV efficiency of 0.75% was obtained from cinnamon dye, which is comparable to the highest efficiency reported in precedent studies about natural dye DSSC. It was confirmed by UV-visible and FT-IR spectroscopy that coumarin derivatives in the plants acted as photosensitive material.

쿠마린 성분이 포함된 식물로부터 염료감응 태양전지에 사용되는 저렴하고 친환경적인 천연 염료를 개발하였다. 염료는 쿠마린 유도체가 포함된 계피와 당귀로부터 추출하였으며 이를 이용하여 염료감응 태양전지를 제작하였다. 계피염료로부터 0.75%의 태양전지 효율을 얻었으며, 이는 기존 천연염료 태양전지에 관한 연구 결과와 비교하여 최고 수준임을 확인하였다. 아울러 자외선-가시광선 분광분석 및 푸리에변환 적외선 분석을 이용하여 식물에 포한된 쿠마린 유도체가 광감응 물질임을 확인하였다.

Keywords

References

  1. Park, N. G., "Trend of Dye-Sensitized Solar Cell Technology Development," Sol. Energy, 4(2), 27-43(2005).
  2. Kim, G. S., Kim, Y. S., Kim, H. I., Seo, H. K., Yang, O. B. and Shin, H. S., "The Preparation and Property of Dye Sensitized Solar Cells using $TiO_{2}$," Korean Chem. Eng. Res.(HWAHAK KONGHAK), 44(2), 179-186(2006).
  3. http://shop.solaronix.com/dyes/ruthenium-dyes/ruthenizer-620-1h3 tba.html.
  4. Rhee, S. W. and Kwon, W., "Key Technological Elements in Dyesensitized Solar Cells," Korean J. Chem. Eng., 28(7), 1481-1494 (2011). https://doi.org/10.1007/s11814-011-0148-8
  5. Polo, A. S. and Iha, N. Y. M., "Clean and Renewable Energy from Dye-Sensitized Solar Cells Using Fruit Extracts," RIO 3-World Climate & Energy Event, December, Rio de Janeiro(2003).
  6. Wongcharee, K., Meeyoo, V. and Chavadej, S., "Dye-sensitized Solar Cell Using Natural Dyes Extracted from Rosella and Blue Pea Flowers," Sol. Energy Mater. Sol. Cells, 91(7), 566-571(2007). https://doi.org/10.1016/j.solmat.2006.11.005
  7. Garcia, C. G., Polo, A. S. and Iha, N. Y. M., "Fruit Extracts and Ruthenium Polypyridinic Dyes for Sensitization of $TiO_{2}$ in Photoelectrochemical Solar Cells," J. Photochem. & Photobiol., 160, 87-91(2003). https://doi.org/10.1016/S1010-6030(03)00225-9
  8. Calogero, G. and Di Marco, G., "Red Sicilian Orange and Purple Eggplant Fruits as Natural Sensitizers for Dye-Sensitized Solar Cells," Sol. Energy Mater. Sol. Cells, 92(11), 1341-1346(2008). https://doi.org/10.1016/j.solmat.2008.05.007
  9. Hao, S., Wu, J., Huang, Y. and Lin, J., "Natural Dyes as Photosensitizers for Dye-Sensitized Solar Cell," Sol. Energy, 80(2), 209-214(2006). https://doi.org/10.1016/j.solener.2005.05.009
  10. Hara, K., Kurashige, M., Dan-oh, Y., Kasada, C., Shinpo, A., Suga, S., Sayama, K. and Arakawa, H., "Design of New Coumarin Dyes Having Thiophene Moieties for Highly Efficient Organic- Dye-Sensitized Solar Cells," N. J. Chem., 27(5), 783-785(2003). https://doi.org/10.1039/b300694h
  11. Park, Y. J., "Extracting Method of Natural Pigment for Natural Dye," Korean J. Breeding, 36(1s), 147-149(2004).
  12. Park, S. G., "Coumarin," J. New Hazard Chem., 4(2), 8-12(2009).
  13. Jung, H. W., Choi, J. Y., Lee, J. G., Choi, E. H., Oh, J. S., Kim, D. C., Kim, J. A., Park, S. H., Son, J. K. and Lee, S. H., "Isolation of Melanogenesis Inhibitors from Cinnamomi Cortex," Korean J. Phcog., 38(4), 382-387(2007).
  14. Kang, Y. G., Lee, J. H., Chae, H. J., Kim, D. H., Lee, S. and Park, S. Y., "HPLC Analysis and Extraction Methods of Decursin and Decursinol Angelate in Angelica gigas Roots," Korean J. Phcog, 34(3), 201-205(2003).
  15. Hara, K., Tachibana, Y., Ohga, Y., Shinpo, A., Suga, S., Sayama, K., Sugihara, H. and Arakawa, H., "Dye-Sensitized Nanocrystalline TiO2 Solar Cells Based on Novel Coumarin Dyes," Sol. Energy Mater. Sol. Cells, 77(1), 89-103(2003). https://doi.org/10.1016/S0927-0248(02)00460-9
  16. Lee, S., Lee, Y. S., Jung, S. H., Shin, K. H., Kim, B. K. and Kang, S. S., "Anti-Tumor Activities of Decursinol Angelate and Decursin from Angelica gigas," Arch. Pharm. Res., 26(9), 727- 730(2003). https://doi.org/10.1007/BF02976682

Cited by

  1. 유용 효모균주를 이용한 발효참당귀분말 추출물의 이화학적 특성 및 생리활성 효과 vol.29, pp.10, 2019, https://doi.org/10.5352/jls.2019.29.10.1136