Korean Journal of Chemical Engineering

The Korean Institute of Chemical Engineers (한국화학공학회)
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Blends of polyurethane-polymethyl methacrylate/$TiO_2$-based composites

  • Published : 2013.08.01
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Abstract

Polyurethanes (PUs) prepolymer was prepared by the reaction of toluene-2,4-diisocyanate (TDI) and poly caprolactone diols and the chain was further extended with 1,4-butane diol (1,4-BDO) to get final polyurethane (PU). FTIR spectra of the monomers, PU prepolymer, chain extender and final PU confirmed the reaction progress. A series of blends were prepared by varying the percent compositions of prepared PU, procured polymethyl methacylates (PMMA) and titanium dioxide ($TiO_2$). Pellets were formed from the prepared blends (PU-PMMA/$TiO_2$) using a self-designed mechanical tool. Scanning electron microscope (SEM) images were also taken to confirm the incorporation of the $TiO_2$ contents into the prepared blends. Mechanical properties such as hardness and compressive strength were studied and discussed. The results of the study reveal that the blended sample having 80% PU, 20% PMMA content with 2.5 g $TiO_2$ in 100 g mixture of PU and PMMA is very suitable for suggesting dental materials.

Keywords

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