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Measurement of Heavy Metals Using Portable XRF in Children's Playing Goods

Portable XRF를 이용한 어린이 야외 놀이용품의 중금속 측정

  • Kim, Hyung-Jin (Department of Environment Engineering, Kumoh National Institute of Technology) ;
  • Baek, Young Man (Environmental Health Technology Institute) ;
  • Jung, Kyung Hoon (Environmental Health Technology Institute) ;
  • Hong, Suk Youn (Environmental Health Technology Institute) ;
  • Heo, Hwa Jin (Environmental Health Technology Institute) ;
  • Seong, Jin Uk (Department of Environment Engineering, Kumoh National Institute of Technology) ;
  • Park, Je Chul (Department of Environment Engineering, Kumoh National Institute of Technology)
  • 김형진 (금오공과대학교 환경공학과) ;
  • 백영만 (환경보건기술연구원) ;
  • 정경훈 (환경보건기술연구원) ;
  • 홍석연 (환경보건기술연구원) ;
  • 허화진 (환경보건기술연구원) ;
  • 성진욱 (금오공과대학교 환경공학과) ;
  • 박제철 (금오공과대학교 환경공학과)
  • Received : 2013.01.17
  • Accepted : 2013.04.25
  • Published : 2013.04.30

Abstract

The present study was conducted to judge the applicability of field quality control by children's goods manufacturers by assessing the contents of heavy metals such as Pb and Cd in outdoor play goods for children through measurement using Portable XRF and comparing the results through detailed analyses using ICP. Heavy metal contents of 711 part samples of 505 products were measured using XRF. According to the results, the ratio of products that exceeded the Pb and Cd content standards specified under the Quality Management and Safety Control of Industrial Products Act were 2.4% and 2.6%. Many products certified for self-regulated safety exceeded the standards and thus it was considered that harmful chemical material centered safety management systems would be necessary. Detailed ICP analyses of some products were compared and the results showed deviations of 0.9~80.8% from XRF results. The reasons for this are deviations in the characteristics of measured cross sections and the homogeneity of samples resulting from sample preparation methods, etc. Therefore, it is considered that field quality control will be applicable if measuring methods are efficiently established based on product characteristics and calibration curve preparation methods are established through quality control.

Keywords

References

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Cited by

  1. Future Challenges for Risk-Based Management of 135 Environmental Hazardous Substances in Children's Products vol.23, pp.7, 2014, https://doi.org/10.5322/JESI.2014.23.7.1277