Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Characterization of $MoO_3-V_2O_5/Al_2O_3$ catalysts for selective catalytic reduction of NO by $NH_3$

  • Published : 2013.01.25
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Abstract

$MoO_3-V_2O_5/Al_2O_3$ catalysts were characterized by B.E.T., XRD, LRS, XPS and TPR and the effect of $MoO_3$ addition to alumina supported vanadia catalysts on the catalytic activity for the selective catalytic reduction of NO by ammonia was investigated. Upon the addition of $MoO_3$, catalytic activity was enhanced and the particle size of $V_2O_5$ which is shown by the results of B.E.T., XRD and Raman spectroscopy decreased. This was one reason for increased catalytic activity. The results obtained by XPS and TPR showed that $MoO_3$ addition to alumina supported vanadia catalysts increased the reducibility of vanadia and this was the another reason for synergy effect between $MoO_3$ and $V_2O_5$ in $MoO_3-V_2O_5/Al_2O_3$ catalysts.

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References

  1. M.A.L. Vargas, M. Casanova, A. Trovarelli, G. Busca, Applied Catalysis B: Environmental 75 (2007) 303. https://doi.org/10.1016/j.apcatb.2007.04.022
  2. L. Lietti, I. Nova, G. Ramis, G. Busca, E. Giamello, P. Forzatti, F. Bregani, Journal of Catalysis 187 (1999) 419. https://doi.org/10.1006/jcat.1999.2603
  3. Z. Si, D. Weng, X. Wu, J. Li, G. Li, Journal of Catalysis 271 (2010) 43. https://doi.org/10.1016/j.jcat.2010.01.025
  4. L. Lietti, P. Forzatii, F. Bregani, Industrial and Engineering Chemistry Research 35 (1996) 3884. https://doi.org/10.1021/ie960158l
  5. M. Kobayashi, K. Miyoshi, Applied Catalysis B: Environmental 72 (2007) 253. https://doi.org/10.1016/j.apcatb.2006.11.007
  6. L. Lietti, I. Nova, G. Ramis, L. Dall'Acqua, G. Busca, E. Giamell, P. Fozatti, F. Bregani, Journal of Catalysis 187 (1999) 419. https://doi.org/10.1006/jcat.1999.2603
  7. G.B. Busca, L. Lietti, G. Ramis, F. Berti, Applied Catalysis B: Environmental 18 (1998) 1. https://doi.org/10.1016/S0926-3373(98)00040-X
  8. L. Casagrande, L. Lietti, I. Nova, P. Forzatti, A. Baiker, Applied Catalysis B: Environmental 22 (1999) 63. https://doi.org/10.1016/S0926-3373(99)00035-1
  9. L. Lietti, G. Ramis, F. Berti, G. Toledo, D. Robba, G.B. usca, P. Fozatti, Catalysis Today 187 (1999) 419. https://doi.org/10.1006/jcat.1999.2603
  10. G.E. Marnellos, E.A. Efthimiadis, I.A. Vasalos, Applied Catalysis B: Environmental 48 (2004) 1. https://doi.org/10.1016/j.apcatb.2003.09.011
  11. I. Nam, J.W. Eldrige, J.R. Kittrel, Industrial & Engineering Chemistry Product Research and Development 25 (1986) 192.
  12. H.K. Matralis, M. Ciardelli, M. Ruwet, P. Grange, Journal of Catalysis 157 (1995) 368. https://doi.org/10.1006/jcat.1995.1302
  13. V.M. Mastikhin, V.V. Terskikh, O.B. Lapina, M. Seidl, H. Knozinger, Journal of Catalysis 156 (1995) 1. https://doi.org/10.1006/jcat.1995.1225
  14. S. Okazaki, M. Kumasaka, J. Yoshida, K. Kosaka, Industrial & Engineering Chemistry Product Research and Development 20 (1981) 301. https://doi.org/10.1021/i300002a013
  15. G.T. Went, L. Leu, A.T. Bell, Journal of Catalysis 134 (1992) 479. https://doi.org/10.1016/0021-9517(92)90336-G
  16. L. Lietti, P. Forzatti, Journal of Catalysis 147 (1994) 241. https://doi.org/10.1006/jcat.1994.1135
  17. T. Kim, A. Burrows, C.J. Kiely, I.E. Wachs, Journal of Catalysis 246 (2007) 370. https://doi.org/10.1016/j.jcat.2006.12.018
  18. I.E. Wachs, Journal of Catalysis 124 (1990) 570. https://doi.org/10.1016/0021-9517(90)90206-Y
  19. G. Centi, D. Pinelli, F. Ghoussoub, M. Guelton, L. Gengembre, Journal of Catalysis 130 (1991) 238. https://doi.org/10.1016/0021-9517(91)90107-F
  20. M.C. Paganini, L.D. Acqua, E.G.L. Lietti, P. Forzatti, G. Busca, Journal of Catalysis 166 (1997) 195. https://doi.org/10.1006/jcat.1997.1492
  21. M. Inomata, K. Mori, A. Miyamoto, Y. Murakami, Journal of Physical Chemistry 87 (1983) 761. https://doi.org/10.1021/j100228a014
  22. G. Clarebout, M. Ruwet, H. Matralis, P. Grange, Applied Catalysis 76 (1991) L9. https://doi.org/10.1016/0166-9834(91)80043-V

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