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A Study on Pt Based Catalysts for Water-Gas Shift Reaction to Produce Hydrogen from Waste-Derived Synthesis Gas

폐기물 가스화 합성가스로부터 고순도 수소 생산을 위한 WGS 반응용 백금 촉매 연구

  • Jeong, Dae-Woon (Department of Environmental Engineering, Yonsei University) ;
  • Jang, Won-Jun (Department of Environmental Engineering, Yonsei University) ;
  • Shim, Jae-Oh (Department of Environmental Engineering, Yonsei University) ;
  • Roh, Hyun-Seog (Department of Environmental Engineering, Yonsei University)
  • Published : 2013.01.31

Abstract

Simulated waste-derived synthesis gas has been tested for hydrogen production through water gas shift (WGS) reaction in the temperature range of $240^{\circ}C{\sim}400^{\circ}C$ over supported Pt catalysts prepared by an incipient wetness impregnation method. MG30, MgO, $ZrO_2$, $Al_2O_3$ and $CeO_2$ were employed as supports for WGS reaction in this study. 1 wt.% $Pt/CeO_2$ catalyst exhibited the highest CO conversion as well as 100% $CO_2$ selectivity. This is due to easier reducibility of $Pt/CeO_2$ and high oxygen mobility and oxygen storage capacitiy of $CeO_2$. $Pt/CeO_2$ catalyst can be a promising catalyst for WGS reaction from waste-derived synthesis gas.

Keywords

References

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