Occupational Exposure to Airborne Asbestos Fibers in Serpentine Quarries and a Steel Mill

사문석 채석장과 제철소 내 사문석 취급 근로자의 공기 중 석면 노출 평가

  • Kwon, Jiwoon (Occupational Safety and Health Research Institute, Korea Occupational Safety & Health Agency) ;
  • Seo, Hoe-Kyeong (Occupational Safety and Health Research Institute, Korea Occupational Safety & Health Agency) ;
  • Kim, Kab Bae (Occupational Safety and Health Research Institute, Korea Occupational Safety & Health Agency) ;
  • Chung, Eun Kyo (Occupational Safety and Health Research Institute, Korea Occupational Safety & Health Agency)
  • 권지운 (한국산업안전보건공단 산업안전보건연구원) ;
  • 서회경 (한국산업안전보건공단 산업안전보건연구원) ;
  • 김갑배 (한국산업안전보건공단 산업안전보건연구원) ;
  • 정은교 (한국산업안전보건공단 산업안전보건연구원)
  • Published : 2013.03.31

Abstract

Objectives: Asbestos contents of crushed serpentine rocks and airborne fiber concentrations of workers were determined at two serpentine quarries and a steel mill. Methods: Bulk samples of uncrushed and crushed serpentine rocks were collected and analyzed by PLM and TEM. Airborne asbestos samples were collected from the breathing zone of workers and the vicinity of working area and analyzed by PCM and TEM. Results: Chrysotile was identified with antigorite, lizardite and non-asbestiform actinolite in bulk samples. The arithmetic means of chrysotile contents in crushed serpentines were 0.11, 0.01, 0.42%(W/W) by quarry A, quarry B and a steel mill, respectively. The asbestos concentrations of all personal samples were less than 0.1 f/cc which is the permissible exposure limit of workers in Korea. The arithmetic means of airborne asbestos concentrations were 0.017 f/cc and 0.009 f/cc in personal samples collected from two serpentine quarries. The asbestos concentrations of all personal samples collected from a steel mill were less than LODs by PCM analysis but asbestos was detected in area samples by TEM. By the job tasks of serpentine quarries, crusher/separator operation generated the highest exposure to airborne asbestos. Conclusions: Although chrysotile contents in crushed serpentines of quarries were less the permissible level, the highest exposure of workers in serpentine quarries reached up to 76% of the permissible level of airborne asbestos. There were also possibilities of occupational exposure to airborne asbestos in a steel mill. The present exposure study should encourage further survey and occupational control of quarries producing serpentine or other types of asbestos-bearing rocks.

Keywords

References

  1. American Standard Testing and Materials (ASTM), Standard test method for microvacuum sampling and indirect analysis of dust by transmission electron microscopy for asbestos mass surface loading. ASTM Standard D 5756-02. 2003.
  2. Asian Citizen's Center for Environment and Health (ACCEH). POSCO & HYUNDAI Steel use asbestos contaminated serpentine. ACCEH Publication 2011-04. 2011.
  3. Asian Citizen's Center for Environment and Health (ACCEH). Survey report on asbestos in school playgrounds. ACCEH Publication 2011-19. 2011.
  4. Asian Citizen's Center for Environment and Health (ACCEH). Survey report on asbestos in baseball stadiums nationwide. ACCEH Publication 2011-23. 2011.
  5. Cattaneo A, Somigliana A, Gemmi M, Bernabeo F, Savoca D et al. Airborne concentrations of chrysotile asbestos in serpentine quarris and stone processing facilities in Valmalenco, Italy. Ann Occup Hyg 2012;56(6):671-683. https://doi.org/10.1093/annhyg/mer119
  6. Choi JK. Cases of occupational disease caused by asbestos in Korea. Korea Occupational Safety and Health Agency (KOSHA). KOSHA Publication Health 97-41-74. 1997:34-44.
  7. Choi JK, Paek DM, Paik NW, Hisanaga N, Sakai K. A study on several minerals contaminated with asbestiform fibers in Korea. Korean Ind Hyg Assoc J 1998;8(2):254-263.
  8. Deer WA, Howie RA, Zussman J. Serpentine. In: Deer WA, Howie RA, Zussman J. An introduction to the rock-forming minerals. 2nd ed. Pearson Education Limited. 1992;344-352.
  9. Environmental Protection Agency (EPA). Method for the determination of asbestos in bulk building materials. EPA 600-R-93-116. 1993.
  10. Kim TW, Koh DH. Atypical asbestos exposure in workers - Cases from occupational safety and health research institute. Korean J Occup Health 2007;46(2):62-73.
  11. Klein C. Serpentine group. In: Klein C. The manual of mineral science. John Wiley & Sons, Inc.. 2002:528-530.
  12. Ministry of Employment and Labor (MOEL). Notification on the work environment monitoring and evaluation of designated work environment monitoring laboratories. Notification of Ministry of Employment and Labor 2011-55. 2011.
  13. Ministry of Employment and Labor (MOEL). Occupational Safety and Health Act. Act 10968. 2011.
  14. Ministry of Environment (MOE). Asbestos Safety Control Act. Act 10613. 2011.
  15. Ministry of Environment (MOE). Hazardous Chemical Control Act. Act 11260. 2012.
  16. Ministry of Environment (MOE). Minerals having the possibility of containing asbestos. Notification of Ministry of Environment 2012-72. 2012.
  17. Ministry of Environment (MOE). Sampling and analytical method on the survey and analysis of minerals having the possibility of containing asbestos. Notification of Ministry of Environment 2012-74. 2012.
  18. National Institute for Occupational Safety and Health (NIOSH). Asbestos by TEM: NMAM 7402. NIOSH Manual of Analytical Methods (NMAM) 4th ed. DHHS (NIOSH) Publication 94-113. 1994.
  19. Rohl AN, Langer AM, Selikoff IJ. Environmental asbestos pollution related to use of quarried serpentine rock. Science 1977:1319-1322.
  20. Sakai K, Hisanaga N, Kohyama N, Shibata E, Takeuchi Y. Airborne fiber concentration and size distribution of mineral fibers in area with serpentinite outcrops in Aichi prefecture, Japan. Industrial Health 2011;39:132-140.