Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Structures and Properties of Two Metal-organic Frameworks Derived from 3-Nitro-1,2-benzenedicarboxylic Acid

  • Xu, Wen-Jia (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Zhang, Ling-Yu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Tang, Jin-Niu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Wang, Dai-Yin (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Pan, Gang-Hong (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Feng, Yu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
  • Received : 2013.04.15
  • Accepted : 2013.05.16
  • Published : 2013.08.20
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Abstract

Two metal-organic frameworks based on the connectivity co-effect between rigid benzenedicarboxylic acid and bridging ligand have been synthesized $[Zn_2(3-NO_2-bdc)_2(4,4'-bpy)_2H_2O]_n$ (1), $[Co(3-NO_2-bdc)(4,4'-bpy)H_2O]_n$ (2) (where $3-NO_2-bdcH_2$ = 3-nitro-1,2-benzenedicarboxylic acid, 4,4'-bpy = 4,4'-bipyridine). The two novel complexes were characterized by IR spectrum, elemental analysis, fluorescent properties, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction (PXRD). X-ray structure analysis reveals that 1 and 2 are two-dimensional (2D) network structures. Complex 1 and complex 2 belong to triclinic crystal with P-1 space group. The luminescence measurements reveal that two complexes exhibit good fluorescent emissions in the solid state at room temperature. Also, thermal decomposition process and powder X-ray diffraction of complexes were investigated.

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References

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