DOI QR코드

DOI QR Code

Chemiresistive Sensor Array Based on Semiconducting Metal Oxides for Environmental Monitoring

  • Moon, Hi Gyu (Electronic Materials Research Center, Korea Institute of Science and Technology) ;
  • Han, Soo Deok (Electronic Materials Research Center, Korea Institute of Science and Technology) ;
  • Kang, Min-Gyu (Electronic Materials Research Center, Korea Institute of Science and Technology) ;
  • Jung, Woo-Suk (Electronic Materials Research Center, Korea Institute of Science and Technology) ;
  • Jang, Ho Won (Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University) ;
  • Yoo, Kwang Soo (Department of Materials Science and Engineering, University of Seoul) ;
  • Park, Hyung-Ho (Materials Science and Engineering, Yonsei University) ;
  • Kang, Chong Yun (Electronic Materials Research Center, Korea Institute of Science and Technology)
  • Received : 2013.12.24
  • Accepted : 2014.01.14
  • Published : 2014.01.29

Abstract

We present gas sensing performance based on $2{\times}2$ sensor array with four different elements ($TiO_2$, $SnO_2$, $WO_3$ and $In_2O_3$ thin films) fabricated by rf sputter. Each thin film was deposited onto the selected $SiO_2$/Si substrate with Pt interdigitated electrodes (IDEs) of $5{\mu}m$ spacing which were fabricated on a $SiO_2$/Si substrate using photolithography and dry etching. For 5 ppm $NO_2$ and 50 ppm CO, each thin film sensor has a different response to offers the distinguishable response pattern for different gas molecules. Compared with the conventional micro-fabrication technology, $2{\times}2$ sensor array with such remarkable response pattern will be open a new foundation for monolithic integration of high-performance chemoresistive sensors with simplicity in fabrication, low cost, high reliablity, and multifunctional smart sensors for environmental monitoring.

Keywords

References

  1. N. Barsan, D. Koziej, and U. Weimar, "Metal oxide-based gas sensor research: How to?", Sens. Actuator B-Chem., vol. 121, pp. 18-35, 2007. https://doi.org/10.1016/j.snb.2006.09.047
  2. N. El Barbri, A. Amari, M. Vinaixa, B. Bouchikhi, X. Correig, and E. Llibet, "Building of a metal oxide gas sensorbased electronic nose to assess the freshness of sardines under cold storage", Sens. Actuator B-Chem., vol. 128, pp. 235-244, 2007. https://doi.org/10.1016/j.snb.2007.06.007
  3. A. Kolmakov, D. O. Klenov, Y. Lilach, S. Stemmer, and M. Moskovits, "Enhanced gas sensing by individual $SnO_{2}$ nanowires and nanobelts functionalized with Pd catalyst particles", Nano Lett., vol. 5, pp. 667-673, 2005. https://doi.org/10.1021/nl050082v
  4. C. W. Na, H. S. Woo, I. D. Kim, and J. H. Lee, "Selective detection of $NO_{2}$ and $C_{2}H_{5}OH$ using a $Co_{3}O^{4-}$decorated ZnO nanowire network sensor", Chem. Commun., vol. 47, pp. 5148-5150, 2011. https://doi.org/10.1039/c0cc05256f
  5. G. Korotcenkov, S. H. Han, and B. K. Cho, "Material design for metal oxide chemiresistive gas sensors", J. Sensor Sci. & Tech., vol. 22, no. 1, pp. 1-17, 2013. https://doi.org/10.5369/JSST.2013.22.1.1
  6. H. G. Moon, Y. S. Shim, D. Su, H. H. Park, S. J. Yoon, and H. W. Jang, "Embossed $TiO_{2}$ thin films with tailored links between hollow hemispheres: Synthesis and gas-sensing properties", J. Phys. Chem. C, vol. 115, pp. 9993-9999, 2011.
  7. H. G. Moon, Y. R. Choi, Y. S. Shim, K. I. Choi, J. H. Lee, J. S. Kim, S. J. Yoon, H. H. Park, C. Y. Kang, and H. W. Jang, "Extremely sensitive and selective NO probe based on villi-like $WO_{3}$ nanostructures for application to exhaled breath analyzers", ACS Appl. Mater. Interfaces, vol, 5, pp. 10591-10596, 2013. https://doi.org/10.1021/am402456s
  8. C. M. Hangarter, M. Bangar, A. Mulchandani, and N. V. Myung, "Conducting polymer nanowires for chemiresistive and FET-based bio/chemical sensors", J. Mater. Chem., vol. 20, pp. 3131-3140, 2010. https://doi.org/10.1039/b915717d
  9. N. M. Kiasari, S. Soltanian, B. Gholamkhass and P. Servati, "Room temperature ultra-sensitive resistive humidity sensor based on single zinc oxide nanowire", Sens. Actuator BChem., vol. 182, pp. 101-105, 2012. https://doi.org/10.1016/j.sna.2012.05.041
  10. G. Chen, T. M. Paronyan, E. M. Pigos, and A. R. Harutyunyan, "Enhanced gas sensing in pristine carbon nanotubes under continuous ultraviolet light illumination", Sci Rep 2, vol. 2, pp. 1-7, 2012.
  11. J. L. Zofio and A. M. Prieto, "Environmental efciency and regulatory standards: the case of $CO_{2}$ emissions from OECD industries", Resource and Energy Economics, vol. 23, pp. 63-83, 2001. https://doi.org/10.1016/S0928-7655(00)00030-0

Cited by

  1. A Study on Pattern Analysis of Odorous Substances with a Single Gas Sensor vol.25, pp.6, 2016, https://doi.org/10.5369/JSST.2016.25.6.423