Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
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Reactions of Various Ceramic Materials with Cobalt Sulfate Solution

황산코발트 용액에 의한 다양한 세라믹소지의 반응

  • Won, Il-An (Department of Ceramic Design, Kangwon National University) ;
  • Kim, Kyung-Nam (Department of Materials Engineering, Kangwon National University)
  • 원일안 (강원대학교 세라믹디자인과) ;
  • 김경남 (강원대학교 신소재공학과)
  • Received : 2014.01.06
  • Accepted : 2014.02.03
  • Published : 2014.02.27
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Abstract

In this study, a cobalt sulfate ceramic coating was sintered on various clays at $1250^{\circ}C$. The specimen characteristics were investigated by X-ray diffraction(XRD), scanning electron microscopy(SEM), TG-DTA, UV-vis spectrophotometer, and HRDPM. The ceramic coating had a constant thickness of thousands ${\mu}m$, and the surface was confirmed to be densely fused. Other new compounds were produced by the cobalt sulfate sintering process and reactions. These compounds were a $CoAl_2O_4$ phase, $Co_2SiO_4$ phase, anorthite($CaAl_2Si_2O_8$) phase, and $FeAl_2O_4$ phase, respectively. UV properties of the coated specimen were investigated, celadon clay specimen in 530-550 nm band is showing a dark gray color. The white clay and white mix clay specimen in 460-500 nm band is showing a blue color. The cobalt-aluminate($CoAl_2O_4$) spinel and the cobalt-silicate olivine($Co_2SiO_4$) were the strongest of the ceramic pigments, producing a very pure, navy blue color.

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References

  1. Aladar Burgyan and Richard A. Eppler, J. Am. Ceram. Bull., 62(9), 1001 (1983).
  2. Hudson Winbow, K. H. and Cowley, J. Ceram. Eng. Sci. Proc., 17(1), 102 (1996).
  3. H. J. Lim, S. C. Choi, J. Kor. Ceram. Soc. 36(4), 333 (1999).
  4. W. S. Cho and M. Kakihana, J. Alloy and Compounds 287, 87 (1999). https://doi.org/10.1016/S0925-8388(99)00059-6
  5. D. Jonynaite, J. Senvaitiene, A. Beganskiene, A. Kareiva, Vibra. Spectro., 52, 158 (2010). https://doi.org/10.1016/j.vibspec.2009.12.005
  6. S. Djambazov, Y. Ivanova, A. Yoleva, N. Nedelchev, Ceram. Int. 24, 281 (1998). https://doi.org/10.1016/S0272-8842(97)00012-6
  7. M. Llusar, A. Fores, J. A. Badenes, J. Calbo, M.A Tena, G. Monros, J. Euro. Ceram. Soc., 21(8), 1121 (2001). https://doi.org/10.1016/S0955-2219(00)00295-8
  8. S. Meseguer, M. A. Tena, C. Gargori, J. A. Badenes, M. Llusar, G. Monros, Ceram. Int., 33, 843 (2007). https://doi.org/10.1016/j.ceramint.2006.01.024
  9. D. Y. Shin, K. N. Kim & S. M. Han, Mat. Sci. Forum 544-545, 869 (2007). https://doi.org/10.4028/www.scientific.net/MSF.544-545.869
  10. B. Karasu and S. Turan, J. Am. Ceram. Soc. Bull., 80, 41 (2001).
  11. J. Chen, X. H. Shi, Dyes and Pigments, 75, 766 (2007). https://doi.org/10.1016/j.dyepig.2006.08.020
  12. H. S. Souza, T. W. Campos, P. S. Santos, P. K. Kiyohara, Ceram. Inter. 31, 1077 (2005). https://doi.org/10.1016/j.ceramint.2004.10.018
  13. G. Monari, T. Manfredini, Ceram. Eng. Sci. Proc., 17(1), 167 (1996).
  14. S. Sutardi, R. Septawendar & A. Rachman, J. Ceram. Pro. Res. 14(3), 400 (2013).
  15. F. Andreola, L. Bonfatti, T. Manfredini, G. C. Pellacani, and P. Pozzi, Tile & Brick Inter., 8, 341 (1992).
  16. Richard A. Eppler & Douglas R. Eppler, p.127-145, The American Ceramic Society Westerville, Ohio, USA, (2000).