Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Synthesis and Characteristics of Blue Ceramic Pigments Using Electric Arc Furnace Dust

제강분진을 활용한 고온발색 청색무기안료 합성 및 특성에 관한 연구

  • Son, Bo-Ram (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Kim, Jin-Ho (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Han, Kyu-Sung (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Cho, Woo-Suk (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET)) ;
  • Hwang, Kwang-Taek (Icheon Branch, Korea Institute of Ceramic Engineering & Technology (KICET))
  • 손보람 (한국세라믹기술원 이천분원) ;
  • 김진호 (한국세라믹기술원 이천분원) ;
  • 한규성 (한국세라믹기술원 이천분원) ;
  • 조우석 (한국세라믹기술원 이천분원) ;
  • 황광택 (한국세라믹기술원 이천분원)
  • Received : 2014.03.14
  • Accepted : 2014.05.02
  • Published : 2014.05.31
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Abstract

Electric arc furnace dust (EAFD) is a solid waste generated by the steel-scrap recycling process. It mainly consists of zinc oxides (ZnO), alumina ($Al_2O_3$), iron oxides ($Fe_2O_3$), and silica ($SiO_2$). Here we report the preparation and characterization of blue ceramic pigments using EAFD powder as a starting material. $(Zn(EAFD),Co)Al_2O_4$ blue ceramic pigment was prepared by the solid-state reaction method. The color characteristics of the pigment obtained were compared with those of pure $CoAl_2O_4$. The new pigment was characterized using XRD, CIE-$L^*a^*b^*$ color-measurements, SEM, and EDX. The XRD analysis revealed that the $(Zn(EAFD),Co)Al_2O_4$ pigment was composed of mainly the spinel phase of $(Zn,Co)Al_2O_4$. The $Zn(EAFD)_{0.25}Co_{0.75}Al_2O_4$ pigments showed a vivid blue color with a $b^*$ value of -28.64 and a good glaze stability with a transparent glaze.

Keywords

References

  1. M. Cain and R. Morrell, "Nanostructured Ceramics: A Review of Their Potential," Appl. Organomet. Chem., 15 [5] 321-33 (2001). https://doi.org/10.1002/aoc.153
  2. Z. Hu, M. Xue, Q. Zhang, Q. Sheng, and Y. Liu, "Nanocolorants: A Novel Class of Colorants, the Preparation and Performance Characterization," Dyes Pigm., 76 [1] 173-78 (2008). https://doi.org/10.1016/j.dyepig.2006.08.026
  3. P. M. T. Cavalcante, M. Dondi, G. Guaini, M. Raimondo, and G. Baldi, "Colour Performance of Ceramic Nano-pigments," Dyes Pigm., 80 [2] 226-32 (2009). https://doi.org/10.1016/j.dyepig.2008.07.004
  4. S. K. Biswas, D. Dhak, A. Pathak, and P. Pramanik, "Chemical Synthesis of Environment-Friendly Nanosized Yellow Titanate Pigments," Mater. Res. Bull., 43 [3] 665-67 (2008). https://doi.org/10.1016/j.materresbull.2007.04.001
  5. H. T. Wu, M. J. Lee, and H. M. Lin, "Nano-particles Formation for Pigment Red 177 via Continuous Supercritical Anti-solvent Process," J. Supercrit. Fluids, 33 [2] 173-82 (2005). https://doi.org/10.1016/j.supflu.2004.06.001
  6. A. Burgyan, "Characterization and Identification of the Mixed Metal Oxides and Ceramic Pigments Manufactured in the U.S.," Interceram. NR, 1 30-2 (1979).
  7. E. S. Kharashvili, "Trends in Developing Ceramic Pigments," Glass Ceram., 42 [9-10] 459-63 (1985). https://doi.org/10.1007/BF00700679
  8. R. W. Batchelor, "Modern Inorganic Pigment," Trans. Br. Ceram. Soc., 73 [8] 297-30 (1974).
  9. I. H. Gul, A. Maqsood, M. Naeem, and M. N. Ashiq, "Optical, Magnetic and Electric Investigation of Cobalt Ferrite Nanoparticles Synthesized by Co-precipitation Route," J. Alloys Compd., 507 [1] 201-06 (2010). https://doi.org/10.1016/j.jallcom.2010.07.155
  10. Z. Mesikova, P. Sulcova, and M. Trojan, "Preparation and Practical Application of Spinel Pigment $Co_{0.46}Zn_{0.55}(Ti_{0.064}Cr_{0.91})_2O_4$," J. Therm. Anal. Calorim,. 84 [3] 733-36 (2006). https://doi.org/10.1007/s10973-005-7543-5
  11. G. T. Chandrappa, S. Ghosh, and K. C. Pattil, "Synthesis and Properites of Willemite, $Zn_2SiO_4,\;and\;M^{2+}:Zn_2SiO_4$ (M=Co and Ni)," J. Mater. Synth. Process., 7 [5] 273-79 (1999). https://doi.org/10.1023/A:1021816803246
  12. V. Sepelak and K. D. Becker, "Comparison of the Cation Inversion Parameter of the Nanoscale Milled Spinel Ferrites with that of the Quenched Bulk Materials," Mater. Sci. Eng,. A 375 [1-2] 861-86 (2004).
  13. M. Llusar, A. Fores, J. A. Badenes, J. Calbo, M. A. Tena, and G. Monros, "Colour Analysis of Some Cobalt-based Blue Pigment," J. Eur. Ceram. Soc,. 21 [8] 1121-30 (2001). https://doi.org/10.1016/S0955-2219(00)00295-8
  14. M. S. Min, "Thermodynamic Behavior of Zinc in EAF dust," pp. 4-6, Ph.D. Thesis, Yonsei Univ, Seoul, 2002.
  15. H. J. Chang, D. S. Kim, H. G. Kim, M. Y. Cho, and N. K. Won, "Triboelectrostatic Recovery of High Zinc-Containing Particulate Contents from Steel-Making Process Dust," J. Korean Inst. of Resources Recycling, 13 [2] 39-46 (2004).
  16. K. C. Lee, J. W. Yoon, J. H. Kim, K. T. Hwang, and K. S. Han, "Preparation and Characterization of $CoAl_2O_4$ Blue Ceramic Nano Pigments by Attrition Milling," J. Kor. Cryst. Growth and Cryst. Tech., 23 [5] 255-64 (2013). https://doi.org/10.6111/JKCGCT.2013.23.5.255