Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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The effect of temperature and hydrodynamics on carbon steel corrosion and its inhibition in oxygenated acid-salt solution

  • Hasan, Basim O. (Chemical Engineering Department, Alnahrain University) ;
  • Sadek, Sara A. (Chemical Engineering Department, Alnahrain University)
  • Received : 2012.10.27
  • Accepted : 2013.03.29
  • Published : 2014.01.25
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Abstract

Corrosion of carbon steel in hydrochloric acid (HCl)-sodium sulphate ($Na_2SO_4$) solution mixture was investigated using rotating cylinder electrode (RCE) for a range of rotation velocity, 0-2000 rpm, solution temperature of $32-52^{\circ}C$, and different oxygen concentrations. The corrosion rat was determined by using both weight loss method and electrochemical polarization technique. Different acid and salt concentrations were used ranged from 0.01 to 0.2 M for salt and 0.5 to 5% for acid. The conjoint effect of increased oxygen concentration and high rotational velocity was studied based on experimental measurements of $O_2$ concentration. The effects of operating conditions on indole and cetyl trimethyl ammonium bromides (CTAB) inhibition efficiency were also studied and discussed. The results showed that increasing the rotational velocity leads to an increase in the corrosion rate depending on the concentration of salt and acid. Increasing the temperature and acid concentrations leads to an increase in the corrosion rate while the corrosion rate exhibited unstable trend with salt concentration leads to change of corrosion. It is found that increasing $O_2$ concentration leads to a considerable increase in the corrosion rates especially at high rotational velocity. Indole and CTAB inhibitors exhibited very good inhibition efficiency in most conditions investigated with the former exhibited better inhibition efficiency arriving up to 87% at low rotational velocities. The inhibition efficiency of both inhibitors was found to decrease with increasing velocity. In addition, indole inhibitor reveals excellent inhibition efficiency even at high temperatures while CTAB efficiency decreased appreciably with temperature increase.

Keywords

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