Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Improvement single-wall carbon nanotubes (SWCNTs) based on functionalizing with monomers 2-hydroxyethylmethacryate (HEMA) and N-vinylpyrrolidone (NVP) for pharmaceutical applications as cancer therapy

  • Abbaszadeh, Fatemeh (Department of Chemistry, Shahre Qods Branch, Islamic Azad University) ;
  • Moradi, Omid (Department of Chemistry, Shahre Qods Branch, Islamic Azad University) ;
  • Norouzi, Mehdi (Department of Virology, School of Public Health, Tehran University of Medical Sciences) ;
  • Sabzevari, Omid (Department of Toxicology and Pharmacology, Faculty of Pharmacy, Tehran University of Medical Sciences)
  • Received : 2013.10.18
  • Accepted : 2013.11.04
  • Published : 2014.09.25
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Abstract

The functionalized carbon nanotubes play significant roles in the fields such as preparation of composite materials and biological technologies. This paper explains the covalent functionalization of single-wall carbon nanotubes (SWCNTs) with biomedical important monomers, 2-hydroxyethylmethacryate (HEMA) and N-vinylpyrrolidone (NVP) by chemical grafting of HEMA and PVP monomers via free radical polymerization. To get carboxylic acid functionalized SWCNTs, first the nanotubes were oxidized with a mixture of nitric acid and sulfuric acid (1:3). Then, the binding of HEMA and NVP onto the surface of SWCNTs was performed by chemical functionalization of HEMA, NVP with acid chloride-bound carbon nanotube by esterification reaction. These results were confirmed by FT-IR and SEM. The cell culture experiments conducted for pharmaceutical applications were used as cancer therapy.

Keywords

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