Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Simultaneous removal of Pb(II) and Cr(III) by magnetite nanoparticles using various synthesis conditions

  • Wang, Ting (School of Environmental Science and Engineering, Fujian Normal University) ;
  • Jin, Xiaoying (School of Environmental Science and Engineering, Fujian Normal University) ;
  • Chen, Zuliang (School of Environmental Science and Engineering, Fujian Normal University) ;
  • Megharaj, Mallavarapu (Centre for Environmental Risk Assessment and Remediation, University of South Australia) ;
  • Naidu, Ravendra (Centre for Environmental Risk Assessment and Remediation, University of South Australia)
  • Received : 2013.11.02
  • Accepted : 2013.12.17
  • Published : 2014.09.25
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Abstract

This study concerns the removal of Pb(II) and Cr(III) using magnetite nanoparticles synthesized by co-precipitation methods with (NCM) or without (CM) nitrogen gas passing through. Removal of Pb(II) significantly decreased from 80.56 to 41.41% when Cr(III) was co-presented, while decrease of Cr(III) was negligible when Pb(II) was present, falling from 42.37 to 38.48%. The characterizations indicated that the removal mechanism occurred through adsorption rather than chemical redox reaction. A co-adsorption mechanism is based on Pb(II) involved surface complexation, while Cr(III) was firstly adsorbed onto magnetite, followed by a partially substitution of Cr(III) for Fe(III) in $Cr-Fe_3O_4$ through ion exchanges.

Keywords

Acknowledgement

Supported by : Fujian Normal University

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