Journal of Industrial and Engineering Chemistry

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Effect of the addition of carbon black and carbon nanotube to $FeS_2$ cathode on the electrochemical performance of thermal battery

  • Choi, Yusong (Agency for Defense Development) ;
  • Cho, Sungbaek (Agency for Defense Development) ;
  • Lee, Young-Seak (Department of Fine Chemical Engineering and Applied Chemistry, Chungnam National University)
  • Received : 2013.11.06
  • Accepted : 2013.12.17
  • Published : 2014.09.25
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Abstract

Effect of the addition of conductive carbonaceous materials to the $FeS_2$ (pyrite) cathode on electrochemical performance of thermal battery is investigated by adding carbon blacks (CBs) or multi-walled carbon nanotubes (MWCNTs) which has conductive network structures with various amounts from 0.1 to 1 wt.%, compared to the amount of pure $FeS_2$. Among the samples prepared with various amounts of CB or MWCNT addition, the 1 wt.% CB-added sample exhibits the highest electrochemical properties. These results suggest that the improvement in the electrochemical performance of thermal batteries can be achieved by the addition of the conductive carbonaceous materials to pyrite electrode.

Keywords

References

  1. R.A. Guidotti, R. Masset, J. Power Sources 161 (2006) 1443-1449. https://doi.org/10.1016/j.jpowsour.2006.06.013
  2. R.A. Guidotti, P.J. Masset, J. Power Sources 183 (2008) 388-398. https://doi.org/10.1016/j.jpowsour.2008.04.090
  3. P.J. Masset, R.A. Guidotti, J. Power Sources 177 (2008) 595-609. https://doi.org/10.1016/j.jpowsour.2007.11.017
  4. S.S. Wang, R.N. Seefurth, J. Electrochem. Soc. 134 (1987) 530-535. https://doi.org/10.1149/1.2100504
  5. Z. Tomczuk, S.K. Preto, M.F. Roche, J. Electrochem. Soc. 128 (1981) 760-772. https://doi.org/10.1149/1.2127502
  6. R.A. Guidotti, F.W. Reinhardt, J. Dai, J. Roth, D.E. Reisner, J. New Mat. Electrochem. Syst. 5 (2002) 273-279.
  7. D.E. Reisner, T.D. Xiao, J. Dai, R.A. Guidotti, F.W. Reinhardt, J. New Mater. Electrochem. Syst. 2 (1999) 279-283.
  8. X. Huang, X. Li, H. Wang, Z. Pan, M. Qu, Z. Yu, Electrochim. Acta 55 (2010) 7362-7366. https://doi.org/10.1016/j.electacta.2010.07.036
  9. S.R. Sivakkumar, P.C. Howlett, B.W. Jensen, M. Forsyth, D.R. Macfarlane, Electrochim. Acta 54 (2009) 6844-6849. https://doi.org/10.1016/j.electacta.2009.06.091
  10. W. Wei, J. Wang, L. Zhou, J. Yang, B. Schumann, Y. Luli, Electrochem. Commun. 13 (2011) 399-402. https://doi.org/10.1016/j.elecom.2011.02.001
  11. Y. Luli, J. Yang, M. Jiang, Mater. Lett. 62 (2008) 2092-2095. https://doi.org/10.1016/j.matlet.2007.11.022
  12. J.J. Yang, J.H. Choi, H.J. Kim, M. Morita, S.G. Park, J. Ind. Eng. Chem. 19 (2013) 1648-1652. https://doi.org/10.1016/j.jiec.2013.02.003
  13. X.M. Liu, Z.D. Huang, S.W. Oh, B. Zhang, P.C. Ma, M.M.F. Yuen, J.K. Kim, Composites Science and Technology 72 (2012) 121-144. https://doi.org/10.1016/j.compscitech.2011.11.019
  14. L.S. Ying, M.A. bin Mohd Salleh, H.B. Mohamed Yusoff, S.B.A. Rashid, J.B.A. Razak, J. Ind. Eng. Chem. 17 (2013) 367-376. https://doi.org/10.1016/j.jiec.2011.05.007
  15. S. Fujiwara, M. Inaba, A. Tasaka, J. Power Sources 196 (2011) 4012-4018. https://doi.org/10.1016/j.jpowsour.2010.12.009
  16. P. Singh, R.A. Guidotti, D. Reisner, J. Power Sources 138 (2004) 323-326. https://doi.org/10.1016/j.jpowsour.2004.06.038
  17. J.W. Choi, G. Cheruvally, H.J. Ahn, K.W. Kim, J.H. Ahn, J. Power Sources 163 (2006) 158-165. https://doi.org/10.1016/j.jpowsour.2006.04.075
  18. Y.S. Choi, H.R., Yu, H.W., Cheong, S.B., Cho, Y.S. Lee, Accepted in Applied Chem. Engr. Nov. (2013).
  19. G.A. Swift, Proceedinsgs of the 43rd Power Sources Conference 7.1, Sheraton Philadelphia City Center Hotel, Philadelphia, PA 7. 7-7.10, (2008), p. 113.
  20. G.A. Swift, Proceedinsgs of the. 43rd Power Sources Conference P-13, Sheraton Philadelphia City Center Hotel, Philadelphia, PA 7. 7-7.10, (2008), p. 249.
  21. G.A. Swift, Proceedinsgs of the 43rd Power Sources Conference P-14, Sheraton Philadelphia City Center Hotel, Philadelphia, PA 7. 7-7.10, (2008), p. 253.
  22. X.M. Liu, Z.D. Huang, S.W. Oh, B. Zhang, P.C. Ma, M.M.F. Yuen, J.K. Kim, Compos. Sci. Tech. 72 (2012) 121-144. https://doi.org/10.1016/j.compscitech.2011.11.019
  23. J.B. Donnet, Carbon black: Science and Technology, 2nd ed., Taylor & Francis, 1993.
  24. K.S. Chen, in: Proceedings of the 42nd Power Sources Conference 12.4, Wyndham Philadelphia, Philadelphia, PA 6. 12-6.15, (2006), p. 289.
  25. N. Shuster, N. Papadakis, G. Barlow, G. Bayles, in: Proceedings of the 37th Power Sources Conference 12.3, Hilton Cherry Hill, New Jersey 6. 17-6.20, (1996), p. 325.
  26. G.C.S. Freitas, F.C. Peixoto, A.S. Vianna Jr., J. Power Sources 179 (2008) 424-429. https://doi.org/10.1016/j.jpowsour.2007.11.084
  27. S. Schoeffert, J. Power Sources 142 (2005) 361-369. https://doi.org/10.1016/j.jpowsour.2004.09.038
  28. E. Barsoukov, J.H. Kim, C.O. Yoon, H.S. Lee, J. Power Sources 83 (1999) 61-70. https://doi.org/10.1016/S0378-7753(99)00257-8
  29. Z. Galus, Fundamentals of Electrochemical Analysis, Wiley, New York, 1976.

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