DOI QR코드

DOI QR Code

Fracture toughness and surface morphology of polysulfone-modified epoxy resin

  • Jin, Hu (School of Resources and Environment Engineering, Jilin Institute of Chemical Technology) ;
  • Yang, Baoqing (Jilin City Scientific & Technological Information Institute) ;
  • Jin, Fan-Long (Department of Polymer Materials, Jilin Institute of Chemical Technology) ;
  • Park, Soo-Jin (Department of Chemistry, Inha University)
  • Received : 2014.07.30
  • Accepted : 2014.10.18
  • Published : 2015.05.25

Abstract

The thermal stability, fracture toughness, flexural strength, and surface morphology of a polysulfone (PSF)-modified epoxy resin were investigated using several techniques. The thermal stability of the PSF-modified epoxy resin was similar to that of the neat epoxy resin. The flexural strength of the epoxy resin decreased with the addition of the PSF. The fracture toughness of the PSF-modified epoxy resin significantly improved compared to that of the neat epoxy resin. The SEM micrograph of the modified epoxy resin showed a relatively rough surface with shear deformation and tortuous cracks, thereby inducing higher fracture toughness in the PSF-modified epoxy system.

Keywords

Acknowledgement

Grant : 분자촉매 설계 및 응용연구 사업단

References

  1. R.S. Bauer, Epoxy Resin Chemistry, Advanced in Chemistry Series, No. 114, American Chemical Society, Washington, DC, 1979.
  2. Y. Zhao, Z.K. Chen, Y. Liu, H.M. Xiao, Q.P. Feng, S.Y. Fu, Composites A: Appl. Sci. Manuf. 55 (2013) 178. https://doi.org/10.1016/j.compositesa.2013.09.005
  3. W. Dong, H.C. Liu, S.J. Park, F.L. Jin, J. Ind. Eng. Chem. 20 (2014) 1220. https://doi.org/10.1016/j.jiec.2013.06.053
  4. S. Chandrasekaran, N. Sato, F. Tolle, R. Mulhaupt, B. Fiedler, K. Schulte, Compos. Sci. Technol. 97 (2014) 90. https://doi.org/10.1016/j.compscitech.2014.03.014
  5. P.S.S. Gouda, V. Chatterjee, P.K. Barhai, D. Jawali, S. Rahatekar, M.R. Wisnom, Mater. Des. 62 (2014) 320. https://doi.org/10.1016/j.matdes.2014.05.018
  6. V. Eskizeybek, A. Avci, A. Gulce, Composites A: Appl. Sci. Manuf. 63 (2014) 94. https://doi.org/10.1016/j.compositesa.2014.04.013
  7. I. Giannotti, M.S. Solsona, M.J. Galante, P.A. Oyanguren, J. Appl. Polym. Sci. 89 (2003) 405. https://doi.org/10.1002/app.12100
  8. C.B. Bucknall, A.H. Gilbert, Polymer 30 (1989) 213. https://doi.org/10.1016/0032-3861(89)90107-9
  9. I. Martinez, M.D. Martin, A. Eceiza, P. Oyanguren, I. Mondragon, Polymer 41 (2000) 1027. https://doi.org/10.1016/S0032-3861(99)00238-4
  10. M.A. Andre's, J. Garmendia, A. Valea, A. Eceiza, I. Mondragon, J. Appl. Polym. Sci. 69 (1998) 183. https://doi.org/10.1002/(SICI)1097-4628(19980705)69:1<183::AID-APP21>3.0.CO;2-#
  11. X. Xie, H. Yang, Mater. Des. 22 (2001) 7. https://doi.org/10.1016/S0261-3069(00)00027-3
  12. S.J. Park, H.C. Kim, J. Polym. Sci., B: Polym. Phys. 39 (2001) 121. https://doi.org/10.1002/1099-0488(20010101)39:1<121::AID-POLB110>3.0.CO;2-N
  13. F.L. Jin, S.J. Park, Polym. Degrad. Stab. 97 (2012) 2148. https://doi.org/10.1016/j.polymdegradstab.2012.08.015
  14. F.L. Jin, S.J. Park, Bull. Korean Chem. Soc. 30 (2009) 334. https://doi.org/10.5012/bkcs.2009.30.2.334
  15. S.J. Park, F.L. Jin, Polym. Degrad. Stab. 86 (2004) 515. https://doi.org/10.1016/j.polymdegradstab.2004.06.003
  16. F.L. Jin, C.J. Ma, S.J. Park, Mater. Sci. Eng. A 528 (2011) 8517. https://doi.org/10.1016/j.msea.2011.08.054
  17. J.L. Chen, F.L. Jin, S.J. Park, Macromol. Res. 18 (2010) 862. https://doi.org/10.1007/s13233-010-0911-4
  18. M.I. Giannotti, C.R. Bernal, P.A. Oyanguren, M.J. Galante, Polym. Eng. Sci. 45 (2005) 1312. https://doi.org/10.1002/pen.20407
  19. R.J. Varley, J.H. Hodgkin, G.P. Simon, Polymer 42 (2001) 3847. https://doi.org/10.1016/S0032-3861(00)00491-2
  20. W. Jiang, F.L. Jin, S.J. Park, J. Ind. Eng. Chem. 18 (2012) 594. https://doi.org/10.1016/j.jiec.2011.11.140
  21. F.L. Jin, S.J. Park, J. Ind. Eng. Chem. 14 (2008) 564. https://doi.org/10.1016/j.jiec.2008.04.003
  22. S.J. Park, F.L. Jin, J.R. Lee, Macromol. Chem. Phys. 205 (2004) 2048. https://doi.org/10.1002/macp.200400214
  23. S.J. Park, F.L. Jin, J.R. Lee, Mater. Sci. Eng. A 374 (2004) 109. https://doi.org/10.1016/j.msea.2004.01.002
  24. M.I. Giannotti, M.L. Foresti, I. Mondragon, M.J. Galante, P.A. Oyanguren, J. Polym. Sci., B: Polym. Phys. 42 (2004) 3953. https://doi.org/10.1002/polb.20192
  25. S.J. Park, F.L. Jin, J.R. Lee, Macromol. Res. 13 (2005) 8. https://doi.org/10.1007/BF03219009
  26. J.R. Lee, F.L. Jin, S.J. Park, J.M. Park, Surf. Coat. Technol. 180-181C (2004) 650.
  27. S.J. Park, F.L. Jin, C. Lee, Mater. Sci. Eng. A 402 (2005) 335. https://doi.org/10.1016/j.msea.2005.05.015

Cited by

  1. Exploration of Epoxy Resins, Hardening Systems, and Epoxy/Carbon Nanotube Composite Designed for High Performance Materials: A Review vol.55, pp.3, 2015, https://doi.org/10.1080/03602559.2015.1070874
  2. Influence of thermoplastic spacer on the mechanical, electrical, and thermal properties of carbon black filled epoxy adhesives vol.28, pp.3, 2015, https://doi.org/10.1002/pat.3894
  3. Modification of epoxy resin by silane-coupling agent to improve tensile properties of viscose fabric composites vol.75, pp.1, 2015, https://doi.org/10.1007/s00289-017-2022-2
  4. Polyimide incorporated cyanate ester/epoxy copolymers for high‐temperature molding compounds vol.56, pp.21, 2015, https://doi.org/10.1002/pola.29214
  5. Enhancing the Mechanical and Thermal Properties of Epoxy Resin via Blending with Thermoplastic Polysulfone vol.11, pp.3, 2015, https://doi.org/10.3390/polym11030461
  6. Recent Trends of Foaming in Polymer Processing: A Review vol.11, pp.6, 2015, https://doi.org/10.3390/polym11060953
  7. Effect of Surface Modification on Thermal Stability, Flexural Properties, and Impact Strength of Epoxy/Graphene Nanocomposites vol.40, pp.10, 2019, https://doi.org/10.1002/bkcs.11858
  8. High‐performance epoxy nanocomposites via constructing rigid structured interphase with epoxy‐rich graphene oxide vol.137, pp.45, 2015, https://doi.org/10.1002/app.49402
  9. Mechanical and Thermal Properties of Epoxy Resins Modified by a Novel Thermoplastic-polyimide vol.22, pp.1, 2015, https://doi.org/10.1007/s12221-021-9142-x
  10. Evaluation of the Mechanical Properties of Polyether Sulfone-Toughened Epoxy Resin for Carbon Fiber Composites vol.22, pp.1, 2021, https://doi.org/10.1007/s12221-021-9261-4
  11. Polymer matrix wave-transparent composites: A review vol.75, pp.None, 2015, https://doi.org/10.1016/j.jmst.2020.09.017