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Effect of Mixing Shear on Flocculation of Anionic PAM and Cationic Starch Adsorbed PCC and Its Effect on Paper Properties

교반 속도가 음이온성 PAM과 양이온성 전분으로 도포된 경질탄산칼슘의 응집과 종이 물성에 미치는 영향

  • Choi, Do-Chim (Dept. of Paper Science & Engineering, College of Forest & Environmental Sciences, Kangwon National University) ;
  • Won, Jong Myoung (Dept. of Paper Science & Engineering, College of Forest & Environmental Sciences, Kangwon National University) ;
  • Cho, Byoung-Uk (Dept. of Paper Science & Engineering, College of Forest & Environmental Sciences, Kangwon National University)
  • Received : 2015.04.08
  • Accepted : 2015.04.23
  • Published : 2015.04.30

Abstract

The effects of stirring speed during filler modification by dual polymers on flocculation and reflocculation of PCC (precipitated calcium carbonate) particles and its effect on handsheet properties were elucidated. PCC surface was modified by adsorbing A-PAM (anionic polyacrylamide) and C-starch (cationic starch) in series at various stirring speeds. It was found that increasing stirring speed during filler modification decreased the initial floc size of PCC. Continuous stirring with the same speed for filler modification resulted in the decrease of a floc size, eventually reached a steady state. The variations in a floc size was influenced by the stirring speed during filler modification: the lower the stirring speed during filler modification, the larger the floc size variations. Conclusively, the stability of PCC floc could be improved by increasing the stirring speed. In addition, the stirring speed influenced the handsheet properties. The smaller the PCC floc, the lower the strength of handseet. However, too much larger floc size also deteriorated paper strength. There exists an optimum floc size in term of paper strength which shall be controlled by stirring speed during filler modification.

Keywords

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