Journal of the Korean Physical Society

Korean Physical Society (한국물리학회)
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Screw-Dislocation-Driven Growth of ZnO Nanotubes Seeded by Self-Perpetuating Spirals during Hydrothermal Processing

  • Kim, Sojin (Department of Materials Science and Engineering, Chosun University) ;
  • Kang, Hyon Chol (Department of Materials Science and Engineering, Chosun University)
  • Received : 2016.08.01
  • Accepted : 2016.08.22
  • Published : 2016.09.13
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Abstract

We report the effects of precursor concentration on the characteristics of ZnO nanostructures during hydrothermal processing. Self-perpetuating surface spirals are fabricated at concentrations of 0.25 and 0.5 M, with samples grown at concentrations of 0.05 and 0.125 M exhibiting ZnO nanorods. This can be explained by a change in the growth mode from an initial columnar growth to a screw-dislocation-driven growth with decreased supersaturation. The screw dislocations nucleate at the V-shaped valleys of the columnar boundaries during the intermediate stage. We demonstrate that continuous screw-dislocation-driven growth leads to the formation of ZnO nanotubes having Burger's vectors of 1.45 nm.

Keywords

Acknowledgement

Supported by : National Research Foundation of Korea (NRF)

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