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Densities and surface tensions of binary mixtures of biodiesel, diesel, and n-butanol

  • Yue, Hongya (Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi'an Jiaotong University) ;
  • Liu, Zhigang (Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi'an Jiaotong University)
  • Received : 2015.08.05
  • Accepted : 2015.12.18
  • Published : 2016.05.01

Abstract

Density and surface tension have been measured for mixtures of biodiesel+n-butanol, biodiesel+diesel, and diesel+n-butanol over the entire concentration range at 283.15 K and 293.15 K and atmospheric pressure, with the combined expanded uncertainties of $1.32kg{\cdot}m^{-3}$ and 1%, receptively. Densities were determined by a single-sinker densimeter; surface tensions were measured using the surface laser light scattering method. The experimental data showed that densities and surface tensions decreased as temperature increased. The excess surface tensions and excess densities were all negative, and further fitted to the Redlich-Kister equation.

Keywords

Acknowledgement

Supported by : National Natural Science Foundation of China

References

  1. F. Lujaji, A. Bereczky and M. Mbarawa, Energy Fuels, 24, 4490 (2010). https://doi.org/10.1021/ef100456a
  2. Z. Huang, H. Miao, L. Zhou and D. Jiang, P. I. Mech. Eng. D-J. Aut., 214, 341 (2000). https://doi.org/10.1243/0954407001527466
  3. M. Noboru, O. Hideyuki and O. Kohichi, JASE Review, 19, 154 (1988).
  4. L. Zhu, C. S. Cheung, W. G. Zhang and Z. Huang, Sci. Total Environ., 408, 914 (2010). https://doi.org/10.1016/j.scitotenv.2009.10.078
  5. Z. Bo, F. Weibiao and G. Jingsong, Fuel, 85, 778 (2006). https://doi.org/10.1016/j.fuel.2005.08.042
  6. E. Alptekin and M. Canakci, Renewable Energy, 33, 2623 (2008). https://doi.org/10.1016/j.renene.2008.02.020
  7. N. P. Bahadur, D.G. B. Boocock and S.K. Konar, Energy Fuels, 9, 248 (1995). https://doi.org/10.1021/ef00050a007
  8. P. Deng, R. Huang, Y. Ma and H. Dai, SAE Technical. Paper., 2013-01-2598 (2013).
  9. F. K. Wang, J.T. Wu and Z. G. Liu, Energy Fuels, 20, 2471 (2006). https://doi.org/10.1021/ef060231c
  10. T. Nishio and Y. Nagasaka, Int. J. Thermophysics, 16, 1087 (1995). https://doi.org/10.1007/BF02081277
  11. K.U. Ingrad, Fundamentals of Waves & Oscillations, Great Britain: the University Press, Cambridge, 478 (1988).
  12. K.U. Ingard, Fundamentals of Waves & Oscillations, U.K. (1988).
  13. Y.Y. An, J. F. Liu and Q. H. Li, Optoelectronic Technology, Beijing (2002).
  14. ISO, Guide to the Expression of Uncertainty in Measurement. International Organisation for Standardisation, Switzerland. 9-71 (1995).
  15. G. J. Zhao, Development of Surface Laser Light Scattering Apparatus for Liquid Viscosity and Surface Tension Measurement and Its Applications, Xi'an, Xi'an Jiao Tong University (2006).
  16. C. Valles, E. Perez, M. Cardoso, M. Dominguez and A. M. Mainar, J. Chem. Eng. Data, 49, 1460 (2004). https://doi.org/10.1021/je0498457
  17. T. Reza, M. Hamid and S. John, J. Chem. Eng. Data, 51, 1039 (2006). https://doi.org/10.1021/je050519g
  18. C. Wohlfarth and B. Wohlfarth, Surface Tension of Pure Liquids and Binary Liquid Mixtures, Volume 16, Springer-Verlag (1997).
  19. B. Giner, A. Villares, S. Martin, H. Artigas and C. Lafuente, J. Chem. Eng. Data, 52, 1904 (2007). https://doi.org/10.1021/je700215z
  20. C.R. Pan, Q. F. Ke, G. F. Ouyang, X. H. Zhen, Y.Y. Yang and Z.Q. Huang, J. Chem. Eng. Data, 49, 1839 (2004). https://doi.org/10.1021/je0497294
  21. J. Vijande, M. M. Pineiro, J. Garcia, J. L. Valencia and J. L. Legido, J. Chem. Eng. Data, 51, 1778 (2006). https://doi.org/10.1021/je060179e
  22. O. Redlich and A. Kister, Ind. Eng. Chem., 40, 345 (1948). https://doi.org/10.1021/ie50458a036
  23. A.A. Mohammad, A. K. H. E. Mohammad, M. S. Altuwaim and A. S. Al-Jimaz, J. Chem. Thermodynamics, 56, 106 (2013). https://doi.org/10.1016/j.jct.2012.06.023
  24. N.G. Tsierkezos and A.C. Filippous, J. Chem. Thermodynamics, 38, 952 (2006). https://doi.org/10.1016/j.jct.2005.10.008
  25. F.M.R. Mesquita, F. X. Feitosa, R. S. Santiago and H.B. de Sant'Ana, J. Chem. Eng. Data, 56, 153 (2011). https://doi.org/10.1021/je100721c

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