DOI QR코드

DOI QR Code

Mass transfer kinetics using two-site interface model for removal of Cr(VI) from aqueous solution with cassava peel and rubber tree bark as adsorbents

  • Vasudevan, M. (Civil Engineering Department, Bannari Amman Institute of Technology) ;
  • Ajithkumar, P.S. (Support In Sports (ME) LLC) ;
  • Singh, R.P. (Civil Engineering Department, Motilal Nehru National Institute of Technology) ;
  • Natarajan, N. (Civil Engineering Department, Maharaja Vijayaram Gajapathi Raj College of Engineering)
  • Received : 2015.12.22
  • Accepted : 2016.02.18
  • Published : 2016.06.30

Abstract

Present study investigates the potential of cassava peel and rubber tree bark for the removal of Cr (VI) from aqueous solution. Removal efficiency of more than 99% was obtained during the kinetic adsorption experiments with dosage of 3.5 g/L for cassava peel and 8 g/L for rubber tree bark. By comparing popular isotherm models and kinetic models for evaluating the kinetics of mass transfer, it was observed that Redlich-Peterson model and Langmuir model fitted well ($R^2$ > 0.99) resulting in maximum adsorption capacity as 79.37 mg/g and 43.86 mg/g for cassava peel and rubber tree bark respectively. Validation of pseudo-second order model and Elovich model indicated the possibility of chemisorption being the rate limiting step. The multi-linearity in the diffusion model was further addressed using multi-sites models (two-site series interface (TSSI) and two-site parallel interface (TSPI) models). Considering the influence of interface properties on the kinetic nature of sorption, TSSI model resulted in low mass transfer rate (5% for cassava peel and 10% for rubber tree bark) compared to TSPI model. The study highlights the employability of two-site sorption model for simultaneous representation of different stages of kinetic sorption for finding the rate-limiting process, compared to the separate equilibrium and kinetic modeling attempts.

Keywords

References

  1. Valipour M. A comprehensive study on irrigation management in Asia and Oceania. Arch. Acker Pfl Boden. 2015;61:1247-1271.
  2. Valipour M, Ziatabar AM, Raeini-Sarjaz M, et al. Agricultural water management in the world during past half century. Arch. Acker Pfl Boden. 2015;61:657-678.
  3. Valipour M. What is the tendency to cultivate plants for designing cropping intensity in irrigated area. Adv. Water Sci. Tech. 2015;2: 1-12.
  4. Williams CJ, Aderhold D, Edyvean GJ. Comparison between biosorbents for the removal of metal ions from aqueous solutions. Water Res. 1998;32:216-224. https://doi.org/10.1016/S0043-1354(97)00179-6
  5. Kadirvelu K, Thamaraiselvi K, Namasivayam C. Removal of heavy metal from industrial wastewaters by adsorption onto activated carbon prepared from an agricultural solid waste. Bioresour. Technol. 2001;76:63-65. https://doi.org/10.1016/S0960-8524(00)00072-9
  6. Hueper WC, Payne WW. Experimental studies in metal carcinogenesis. Arch. Environ. Health. 1962;5:445-462. https://doi.org/10.1080/00039896.1962.10663311
  7. Shanmugavalli R, Madhavakrishnan S, Kadirvelu K, Rasappan K, Mohanraj R, Pattabhi S. Adsorption studies on removal of Cr (VI) from aqueous solution using silk cotton hull carbon. J. Ind. Pollu. Contr. 2007;23:65-72.
  8. Viraraghavan T, Dronamrajum. Removal of copper, nickel and- zinc from wastewater by adsorption using peat. J. Environ. Sci. HealthPart A. 1993;28:1261. https://doi.org/10.1080/10934529309375941
  9. Namasivayam C, Ranganathan K. Removal of Pb (II), Cd (II) and Ni (II) and mixture of metal ions by adsorption onto waste Fe (III)/Cr (III) hydroxide and fixed bed studies. Environ. Technol. 1995;16:851-860.
  10. Ngah WS, Hanafiah MAKM. Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: A review. Bioresour. Technol. 2008;99:3935-3948. https://doi.org/10.1016/j.biortech.2007.06.011
  11. Netzer A, Hughes DE. Adsorption of Cr, Pb and Co by activated carbon. Water Res. 1984;18:927-933. https://doi.org/10.1016/0043-1354(84)90241-0
  12. Reed BE, Arunachalam S. Use of granular activated carbon columns for lead removal. J. Environ. Eng. 1994;120:416-436. https://doi.org/10.1061/(ASCE)0733-9372(1994)120:2(416)
  13. Masri MS, Friedman M. Effect of chemical modification of woolon metal ion binding. J. Appl. Polym. Sci. 1974;18: 2367-2377. https://doi.org/10.1002/app.1974.070180815
  14. Dikshit VP. Removal of chromium (VI) by adsorption using sawdust. Natl. Acad. Sci. Lett. 1989;12:419-421.
  15. Bryant PS, Petersen JN, Lee JM, Brouns TM. Sorption of heavy metals by untreated red fir sawdust. Appl. Biochem. Biotechnol. 1992;34-35:777-788. https://doi.org/10.1007/BF02920596
  16. Zarraa MA. A study on the removal of chromium (VI) from waste solutions by adsorption on to sawdust in stirred vessels. Adsorption Sci. Technol. 1995;12:129-138. https://doi.org/10.1177/026361749501200205
  17. Selvi K, Pattabhi S, Kadirvelu K. Removal of Cr (VI) from aqueous solution by adsorption onto activated carbon. Bioresour. Technol. 2001;80:87-89. https://doi.org/10.1016/S0960-8524(01)00068-2
  18. Baral SS, Das SN, Rath P. Hexavalent chromium removal from aqueous solution by adsorption on treated sawdust. Biochem. Eng. J. 2006;31:216-222. https://doi.org/10.1016/j.bej.2006.08.003
  19. Argun ME, Dursun S, Ozdemir C, Karatas M. Heavy metal adsorption by modified oak sawdust: thermodynamics and kinetics. J. Hazard. Mater. B2007;141:77-85. https://doi.org/10.1016/j.jhazmat.2006.06.095
  20. Bansal M, Singh D, Garg VK, Rose P. Mechanisms of Cr (VI) removal from synthetic wastewater by low cost adsorbents. J. Environ. Res. Dev. 2008;3:228-243.
  21. Vinodhini V, Das N. Mechanisms of Cr (VI) biosorption by Neem sawdust. Amer. Euras. J. Scientif. Res. 2009;4:324-329.
  22. Orhan Y, Buyukgungor H. The removal of heavy metals by using agricultural wastes. Water Sci. Technol. 1993;28:247-255. https://doi.org/10.2166/wst.1993.0114
  23. Sharma DC, Forster CF. Removal of hexavalent chromium using sphagnum moss peat. Water Res. 1993;27:1201-1208. https://doi.org/10.1016/0043-1354(93)90012-7
  24. Lee SM, Laldawngliana C, Tiwari D. Iron oxide nano-particles- immobilized-sand material in the treatment of Cu (II), Cd (II) and Pb (II) contaminated waste waters. Chem. Eng. J. 2012;195:103-111.
  25. Periasamy K, Namasivayam C. Removal of nickel (II) from aqueous solution and nickel plating industry wastewater using an agricultural waste: Peanut hulls. Waste Manag. 1995;5:63-68.
  26. Dubey SP, Gopal K. Adsorption of chromium (VI) on low cost adsorbents derived from agricultural waste material: a comparative study. J. Hazard. Mater. 2007;145:465-470 https://doi.org/10.1016/j.jhazmat.2006.11.041
  27. Iqbal M, Saeed A, Akhtar N. Petiolar felt-seath of palm: A new biosorbent for the removal of heavy metals from contaminated water. Bioresour. Technol. 2002;81:151-153. https://doi.org/10.1016/S0960-8524(01)00126-2
  28. Shraim AM. Rice is a potential dietary source of not only arsenic but also other toxic elements like lead and chromium. Arab. J. Chem. 2014
  29. Kurniawan A, Sisnandy VOA, Trilestari K, Sunarso J, Indraswati N, Ismadji S. Performance of durian shell waste as high capacity biosorbent for Cr (VI) removal from synthetic wastewater. Ecol. Eng. 2011;37:940-947. https://doi.org/10.1016/j.ecoleng.2011.01.019
  30. Ghorbel-Abid I, Trabelsi-Ayadi M. Competitive adsorption of heavy metals on local landfill clay. Arab. J. Chem. 2011;8:25-31.
  31. Khan TA, Nazir M, Ali I, Kumar A. Removal of Chromium (VI) from aqueous solution using guar gum-nano zinc oxide biocomposite adsorbent. Arab. J. Chem. 2013.
  32. Rezaei H. Biosorption of chromium by using Spirulina sp. Arab. J Chem. 2013.
  33. Yoganand KS, MJ. Umapathy. Green methodology for the recovery of Cr (VI) from tannery effluent using newly synthesized quaternary ammonium salt. Arab. J Chem. 2013.
  34. Sfaksi ZN, Azzouz A. Abdelwahab. Removal of Cr (VI) from water by cork waste. Arab. J. Chem. 2014;7:37-42. https://doi.org/10.1016/j.arabjc.2013.05.031
  35. Valipour M. Future of agricultural water management in Africa. Arch. Acker Pfl Boden. 2015;61:907-927.
  36. Valipour M. Land use policy and agricultural water management of the previous half of century in Africa. Ap. Water Sci. 2015;5:367-395. https://doi.org/10.1007/s13201-014-0199-1
  37. Valipour M. Pressure on renewable water resources by irrigation to 2060. Acta Adv. Agri. Sci. 2014;2:32-42.
  38. Seepe L. The use of cassava waste in the removal of cobalt, chromium and vanadium metal ions from synthetic effluents. M.S. Thesis. Johannesburg.: University of Witwatersrand; 2015.
  39. Alinnor IJ, Nwachukwu MA. Adsorption of phenol on surface--Modified cassava peel from its aqueous solution. Int. J. Environ. Sci. Manage. Eng. Res. 2012;1:68-76.
  40. Simate GS, Ndlovu S. The removal of heavy metals in a packed bed column using immobilized cassava peel waste biomass. J. Ind. Eng. Chem. 2015;21:635-643. https://doi.org/10.1016/j.jiec.2014.03.031
  41. Isiuku BO, Horsfall M, Spiff AI. Removal of methyl red from aqueous solution by NaOH-activated cassava peels carbon in a fixed-bed column. Res. J. App. Sci. 2014;9:238-243.
  42. Gin WA, Jimoh A, Abdulkareem AS, Giwa A. Kinetics and Isotherm Studies of Heavy Metal Removals from Electroplating Wastewater Using Cassava Peel Activated Carbon. Int. J. Eng. 2014;3.
  43. Owamah HI. Biosorptive removal of Pb (II) and Cu (II) from wastewater using activated carbon from cassava peels. J. Mater. Cycl. Waste Manage. 2014;16:347-358. https://doi.org/10.1007/s10163-013-0192-z
  44. Hanafiah MA, Ngah KM, Ibrahim WSW, Zakaria SC, Ilias H. Kinetics and thermodynamic study of lead adsorption onto rubber (Heveabrasiliensis) leaf powder. J. Appl. Sci. 2006;6:2762-2767. https://doi.org/10.3923/jas.2006.2762.2767
  45. Kalavathy MH, Karthikeyan T, Rajgopal S, Miranda LR. Kinetics and isotherm studies of Cu(II) adsorption onto H3PO4-activated rubber wood sawdust. J. Colloid Interf. Sci. 2005;292:354-362. https://doi.org/10.1016/j.jcis.2005.05.087
  46. Masae M, Sikong L, Kongsong P, Phoempoon P, Rawangwong S, Sririkun W. Application of rubber wood ash for removal of Nickel and Copper from aqueous solution. Environ. Nat. Resour. 2013;11:17-27.
  47. Abia AA, Didi OB, Asuquo ED. Modeling of $Cd^{2+}$ sorption kinetics from aqueous solutions onto some thiolated agricultural waste adsorbents. J. Appl. Sci. 2006;6:2549-2556. https://doi.org/10.3923/jas.2006.2549.2556
  48. Foo K, Hameed BH. Insights into the modeling of adsorption isotherm systems. Chem. Engg. J. 2010;156:2-10. https://doi.org/10.1016/j.cej.2009.09.013
  49. Rudzinski W, Plazinski W. Theoretical description of the kinetics of solute adsorption at heterogeneous solid/solution interfaces on the possibility of distinguishing between the diffusional and the surface reaction kinetics models. Appl. Surf. Sci. 2007;253:5827-5840. https://doi.org/10.1016/j.apsusc.2006.12.038
  50. Chiban M, Carja G, Lehutu G, Sinan F. Equilibrium and thermodynamic studies for the removal of As (V) ions from aqueous solution using dried plants as adsorbents. Arab. J. Chem. 2011.
  51. Gupta S, Babu BV.Removal of toxic metal Cr (VI) from industrial wastewater using sawdust as adsorbent: equilibrium and, kinetics and regeneration studies. J. Chem. Engg. 2008;141:1-20. https://doi.org/10.1016/j.cej.2007.10.009
  52. Natarajan N, Suresh Kumar G. Numerical modelling and spatial moment analysis of solute transport with Langmuir sorption in a fracture matrix-coupled system. ISH J. Hydrau. Eng. 2015;21:28-41. https://doi.org/10.1080/09715010.2014.939233
  53. Vasudevan M, Suresh Kumar G, Nambi IM. Numerical studies on kinetics of sorption and dissolution and their interactions for estimating mass removal of toluene from entrapped soil pores. Arab. J. Geosci. 2014;8:1-16.
  54. Mohanty K, Jha M, Meikap BC, Biswas MN. Removal of chromium (VI) from dilute aqueous solutions by activated carbon developed from Terminaliaarjuna nuts activated with zinc chloride. Chem. Eng. Sci. 2005;60:3049-3059. https://doi.org/10.1016/j.ces.2004.12.049
  55. Singh RP, Zahra F, Savio W, Prasad SC. Axial dispersion and mass transfer controlled simulation study of chromium (VI) adsorption onto tree leaves and activated carbon. J. Environ. Eng. 2009;135:1071-1083. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000050
  56. Zhou M, Liu Y, Zeng G, Li X, Xu W, Fan T. Kinetic and equilibrium studies of Cr (VI) biosorption by dead Bacillus licheniformis biomass. World J. Microbio.Biotech. 2007;23:43-48. https://doi.org/10.1007/s11274-006-9191-8
  57. Seagren EA, Rittmann BE, Valocchi AJ. A critical evaluation of the local-equilibrium assumption in modeling NAPL-pool dissolution. J. Contam. Hydrol. 1999;39:109-135. https://doi.org/10.1016/S0169-7722(99)00026-1
  58. Wong YC, Szeto YS, Cheung WH, McKay G. Effect of temperature, particle size and percentage deacetylation on the adsorption of acid dyes on chitosan. J. Adsor. 2008;14:11-20. https://doi.org/10.1007/s10450-007-9041-5
  59. Qiu H, Lv L, Pan BC, Zhang QJ, Zhang WM, Zhang QX. Critical review in adsorption kinetic models. J. Zhejiang Univ. Sci. 2009;10:716-724. https://doi.org/10.1631/jzus.A0820524
  60. Lee S, Kim DJ, Choi JW. Comparison of first-order sorption kinetics using concept of two-site sorption model. Environ. Eng. Sci. 2012;29:1002-1007. https://doi.org/10.1089/ees.2011.0301
  61. Machida M, Kikuchi Y, Aikawa M, Tatsumoto H. Kinetics of adsorption and desorption of Pb (II) in aqueous solution on activated carbon by two-site adsorption model. Coll. Surf. A: Physic. Eng. Asp. 2004;240:179-186. https://doi.org/10.1016/j.colsurfa.2004.04.046
  62. Annadurai G, Juang RS, Lee DJ. Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. J. Hazard. Mater. 2002;92:263-274. https://doi.org/10.1016/S0304-3894(02)00017-1
  63. Wu FC, Tseng RL, Juang RS. Adsorption of dyes and phenols from water on the activated carbons prepared from corncob wastes. J. Environ. Technol. 2001;22:205-213. https://doi.org/10.1080/09593332208618296
  64. Ungarish M, Aharoni C. Kinetics of chemisorption: deducing kinetic laws from experimental data. J. Chem. Soc. Faraday Trans. 1981;77:975-985. https://doi.org/10.1039/f19817700975

Cited by

  1. Chromium(III) recovery from tanning wastewater by adsorption on activated carbon and elution with sulfuric acid vol.22, pp.2, 2016, https://doi.org/10.4491/eer.2016.070
  2. Simultaneous Removal of Hg(II) and Phenol Using Functionalized Activated Carbon Derived from Areca Nut Waste vol.7, pp.7, 2017, https://doi.org/10.3390/met7070248
  3. Sorption and Desorption Behavior of 4-Nonylphenol and a Branched Isomer on Soils with Long-Term Reclaimed Water Irrigation vol.36, pp.9, 2016, https://doi.org/10.1089/ees.2018.0533
  4. Determination of Kinetic Parameters in the Biosorption of Chromium (VI) in Aqueous Solution vol.16, pp.31, 2016, https://doi.org/10.17230/ingciencia.16.31.6
  5. Cr(VI) removal using Fe2O3-chitosan-cherry kernel shell pyrolytic charcoal composite beads vol.25, pp.3, 2016, https://doi.org/10.4491/eer.2019.112
  6. Application of feed-forward and recurrent neural network in modelling the adsorption of boron by amidoxime-modified poly(Acrylonitrile-co-Acrylic Acid) vol.25, pp.6, 2016, https://doi.org/10.4491/eer.2019.138
  7. Real-time monitoring as an adaptive strategy towards green treatment of textile effluent using biosorbent from Acalypha indica vol.21, pp.5, 2016, https://doi.org/10.2166/ws.2021.033