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Solubility and Yield Characteristics of KCl in Cement By-Pass Dust

시멘트 바이패스 더스트에 존재하는 염화칼륨의 용해 및 수득 특성

  • Yun, Youngmin (Energy & Environment Div. Korea Institute of Ceramic Eng. & Tech.) ;
  • Jeong, Jaehyun (Energy & Environment Div. Korea Institute of Ceramic Eng. & Tech.) ;
  • Chu, Yongsik (Energy & Environment Div. Korea Institute of Ceramic Eng. & Tech.)
  • 윤영민 (한국세라믹기술원 에너지환경소재본부) ;
  • 정재현 (한국세라믹기술원 에너지환경소재본부) ;
  • 추용식 (한국세라믹기술원 에너지환경소재본부)
  • Received : 2016.04.07
  • Accepted : 2016.06.02
  • Published : 2016.06.30

Abstract

Cement manufacturing plant uses various kinds of industrial/municipal waste. The waste contains considerable amount of potassium, chlorine and small amount of heavy metal. Many researches were performed to fabricate valuable resources from the waste. In this study, various methods, which dissolves and crystallizes potassium/chlorine to extract potassium chloride, were experimented. Especially amount of water, slurry temperature, and stirring time were controlled. Then kind of heavy metal and content of potassium chloride were analyzed. The yield of potassium chloride increased, as the amount of water for slurry increased but it increased slightly, when the water content was over 200%. The yield tended to increase, when the temperature of slurry was over a certain point. The yield did not increase in case of over 10 minutes stirring time. The kind and content of heavy metal in potassium chloride were various according to stirring time. The main heavy metals were Pb, Cu, and $Cr^{6+}$.

시멘트 공장에서는 폐기물 재활용 측면에서 다양한 산업부산물 및 생활폐기물을 사용한다. 이들 폐기물에는 다량의 칼륨과 염소 및 소량의 중금속 등도 함유되어 있으며, 이들 성분을 유가자원으로 활용하기 위한 다양한 시도가 이루어지고 있다. 본 연구에서는 칼륨과 염소를 용해 결정화하여 염화칼륨을 수득하기 위한 다양한 방안을 검토하였다. 특히 혼합수 함량, 슬러리 온도 및 교반시간 등을 제어하였다. 또한 수득 염화칼륨 중에 존재하는 중금속 종류 함량 등도 분석하였다. 염화칼륨 수득량은 혼합수 함량 증가에 따라 증가하였으나, 1 : 2 (더스트:혼합수) 이상에서는 소폭 증가하였다. 슬러리 온도에 따른 수득량은 일정온도 이상에서 증가하는 경향을 나타내었으며, 교반시간 10분 이상에서는 수득량 변화가 관찰되지 않았다. 교반시간 증가에 따라 수득된 염화칼륨의 중금속 종류 함량도 다양하였으며, 주요 중금속은 Pb, Cu 및 $Cr^{6+}$ 등으로 확인되었다.

Keywords

References

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