The Korean Journal of Pesticide Science (농약과학회지)

The Korean Society of Pesticide Science (한국농약과학회)
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Investigation of Resiudal Organochlorine Pesticides in Green Perilla (Perilla frutescens var. japonica Hara) Greenhouse Soil and Its Leaves

들깨 생산단지 시설재배지 중 잔류성유기염소계 농약류 잔류량 조사

  • Lim, Sung-Jin (Chemical Safety Division, National Institute of Agricultural Science, Rural Development Administration) ;
  • Oh, Young-Tak (Chemical Safety Division, National Institute of Agricultural Science, Rural Development Administration) ;
  • Ro, Jin-Ho (Chemical Safety Division, National Institute of Agricultural Science, Rural Development Administration) ;
  • Yang, Ji-Yeon (Chemical Safety Division, National Institute of Agricultural Science, Rural Development Administration) ;
  • Choi, Geun-Hyoung (Chemical Safety Division, National Institute of Agricultural Science, Rural Development Administration) ;
  • Ryu, Song-Hee (Chemical Safety Division, National Institute of Agricultural Science, Rural Development Administration) ;
  • Moon, Byeong-Chul (Chemical Safety Division, National Institute of Agricultural Science, Rural Development Administration) ;
  • Park, Byung-Jun (Chemical Safety Division, National Institute of Agricultural Science, Rural Development Administration)
  • 임성진 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 오영탁 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 노진호 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 양지연 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 최근형 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 류송희 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 문병철 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 박병준 (농촌진흥청 국립농업과학원 화학물질안전과)
  • Received : 2016.08.16
  • Accepted : 2016.09.20
  • Published : 2016.09.30
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Abstract

This study was conducted to investigate residual organochlorine pesticides in green house soil and green perilla leaves. Extraction and clean-up method were developed using the modified QuEChERS method for residual organochlorine pesticides (ROCPs) in soil and green perilla leaves. Recovery and limit of quantitation (LOQ) of ROCPs in greenhouse soil and green perilla leaves were 76.3-113.4 and 79.4-107.3%, 0.03-0.24 and $0.33-0.50{\mu}g/kg$, respectively. Detected ROCPs in greenhouse soil were dieldrin and endosulfan sulfate, the residue were 1.6-9.2 and $22.0-87.8{\mu}g/kg$, respectively. But two pesticides in all green perilla leaf samples were not detected. These results showed that ROCPs residue in greenhouse soil was lower than the level of bioaccumulation occurring.

본 연구에서는 들깨 시설재배지 토양 및 작물 중 잔류성유기염소계 농약의 잔류량을 조사하였다. 토양 및 작물 중 잔류성유기염소계 농약 분석을 위한 추출 및 정제는 QuEChERS 방법을 다소 개선한 방법으로 수행되었다. 들깨 시설재배지 토양 및 농산물 중 잔류성유기염소계 농약의 회수율은 각각 76.3-113.4 및 79.4-107.3%, 정량한계는 각각 0.03-0.24와 $0.33-0.50{\mu}g/kg$ 수준이었다. 들깨 시설재배지 토양에서 dieldirn 및 endosulfan sulfate 2 성분만이 각각 1.6-9.2 및 $22.0-87.8{\mu}g/kg$ 수준으로 검출되었으나 들깻잎의 모든 시료에서는 검출되지 않았다. 이러한 결과는 들깨 시설재배지 토양이 농산물 안전성을 위협할 정도로 잔류성유기염소계 농약으로 오염되지 않았음을 나타냈다.

Keywords

References

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