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Preparation and Characterization of SPEEK/Cellulose Polymer Composite Membranes for Water Electrolysis

수전해용 술폰화 폴리에테르 에테르 케톤과 셀룰로오스 고분자 복합막의 제조 및 특성

  • Received : 2016.07.28
  • Accepted : 2016.10.30
  • Published : 2016.10.30

Abstract

Polyether ether ketone (PEEK) composite membranes have been intensively investigated for polymer electrolyte membrane water electrolysis (PEMWE). Covalently linked (CL) sulfonated polyether ether ketone (SPEEK) and cellulose polymer composite membranes were prepared and characterized. Polyether ether ketone (PEEK) and cellulose were sulfonated and then were covalently linked by 1,4-diiodobutane to produce covalently linked SPEEK and cellulose polymer composite membranes. The composite membranes showed better thermostability and electrochemical properties than SPEEK. The membranes were prepared by sol-gel casting method. CL-SPEEK/Cellulose composite membrane featured 0.2453 S/cm of proton conductivity at $80^{\circ}C$ which was better than that of Nafion.

Keywords

References

  1. M. Conte, A. Iacobazzi, M. Ronchetti, and R. Vellone, "Hydrogen economy for a sustainable development: state-of-the-art and technological perspectives", J. power sources, Vol. 100, 2001, pp. 171-187. https://doi.org/10.1016/S0378-7753(01)00893-X
  2. S. H. Kang, "Analysis of the World Energy Status and Hydrogen Energy Technology R&D of Foreign Countries", Trans. of the Korean Hydrogen and New Energy Society, Vol. 18, No. 2, 2007, pp. 216-223.
  3. S. M. J. Zaidi, S. D. Mikhailenko, G. P. Robertson, and M. D. Guiver, "Proton Conducting Composite Membrane from Polyether ether ketone and Hetero-poly acids for Fuel Cell Applications", J. Membr. Sci., Vol. 173, 2000, pp. 17-34. https://doi.org/10.1016/S0376-7388(00)00345-8
  4. Z. Jiang, X. Zhao, Y. Fu, and A. Manthiram, "Composite membranes based on sulfonated poly (ether ether ketone) and SDBS-adsorbed graphene oxide for direct methanol fuel cells", J. Mater. Chem., Vol. 22, 2012, pp. 24862-24869. https://doi.org/10.1039/c2jm35571j
  5. M. Bruno, and L. Bjorn, "Brief overview on cellulose dissolution / regeneration interactions and mechanisms", Advances in colloid and interface science, 2015, pp. 502-508.
  6. S. Sen, J. D. Martin, and D. S. Argyropoulos, "Review of cellulose non-derivatizing solvent interactions with emphasis on activity in inorganic molten salt hydrates", ACS Sustainable Chemistry & Engineering, 2013, pp. 858-870.
  7. Zhang, Q. Lei, D. Q. Lin, and S. Yao, "Review on biomedical and bioengineering applications of cellulose sulfate", Carbohydrate polymers, Vol. 132, 2015, pp. 311-322. https://doi.org/10.1016/j.carbpol.2015.06.041
  8. G. Chen, "Improved process for the production of cellulose sulfate using sulfuric acid/ethanol solution", Carbohydrate polymers, Vol. 95, 2013, pp. 332-337. https://doi.org/10.1016/j.carbpol.2013.03.003
  9. H. Seo, "Synthesis and characterization of covalently cross-linked SPEEK/Cs-substituted Mosia/Ceria membranes with Mosia for water eletrolysis", Trans. of the Korean Society of Hydrogen Energy, Vol. 26, No. 6, 2015, pp. 524-531. https://doi.org/10.7316/KHNES.2015.26.6.524
  10. F. G. Hellferich, "Ion Exchange", McGraw-Hill Book Co., New York, 1962.
  11. N. Li, Z. Cui, S. Zhang, S. Li, and F. Zhang, "Preparation and evaluation of a proton exchange membrane based on oxidation and water stable sulfonated polyimides", J. Power Sources, Vol. 172, 2007, pp. 511-519. https://doi.org/10.1016/j.jpowsour.2007.07.069