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Optimal Operation Condition of Pressurized Methanol Fuel Processor for Underwater Environment

수중환경용 가압형 메탄올 연료프로세서의 최적운전 연구

  • JI, HYUNJIN (The 4th R&D Institute, Agency for Defense Development) ;
  • CHOI, EUNYEONG (The 4th R&D Institute, Agency for Defense Development) ;
  • LEE, JUNGHUN (The 4th R&D Institute, Agency for Defense Development)
  • 지현진 (국방과학연구소 제4기술연구본부 4부) ;
  • 최은영 (국방과학연구소 제4기술연구본부 4부) ;
  • 이정훈 (국방과학연구소 제4기술연구본부 4부)
  • Received : 2016.08.08
  • Accepted : 2016.10.30
  • Published : 2016.10.30

Abstract

Recently submarine and unmanned underwater vehicle (UUV) are equipped with a fuel cell system as an air independent propulsion system. Methanol fuel processor can efficiently supply the hydrogen to the fuel cell system to improve the ability to dive. This study investigated the optimal conditions of the methanol fuel processor that may be used in the closed environment. For this purpose, the numerical model based on Gibbs minimization equation was established for steam reformer and three exhaust gas burners. After simulating the characteristics of steam reformer according to the steam-to-carbon ratio (SCR) and the pressure change, the SCR condition was able to narrow down to 1.1 to 1.5. Considering water consumption and the amount of heat recovered from three burners, the optimum condition of the SCR can be determined to be 1.5. Nevertheless, the additional heat supply is required to satisfy the heat balance of the methanol fuel processor in the SCR=1.5. In other to obtain additional amount of heat, the combustion of methanol is better than the increased of SCR in terms of system design.

Keywords

References

  1. J.S. Han and S.M Lee, "High Purity Hydrogen Generator for Fuel Cell Vehicles", Journal of the Korean Hydrogen Energy Society, Vol. 12, No. 4, 2001, p. 277-285.
  2. Psoma A, and Sattler G. "Fuel cell systems for submarines: from the first idea to serial production", Journal of Power Sources, Vol. 106, No. 1-2, 2002, p. 381-383. https://doi.org/10.1016/S0378-7753(01)01044-8
  3. Krummrich S, and Llabres J., "Methanol reformer-The next milestone for fuel cell powered submarines", International Journal of Hydrogen Energy, Vol. 40, No. 15, 2015, p. 5482-5486. https://doi.org/10.1016/j.ijhydene.2015.01.179
  4. "SENER develop methanol reformer for fuel cell submarines", Fuel cells bulletin, Vol. 2012, No. 12, 2012, p. 2.
  5. "UTC Power to develop fuel cell for Spanish sub", Fuel Cells Bulletin, Vol. 2008, No. 1, 2008, p. 4.
  6. K. Strasser, "$H_2/O_2$-PEM-fuel cell module for an air independent propulsion system in a submarine", 2010, Handbook of Fuel Cells.
  7. Rajeev Gautam and Warren D. Seider, "Computation of phase and chemical equilibrium: Part I. Local and constrained minima in Gibbs free energy", AIChE Journal, Vol. 25, Issue 6, 1979, p.991-999. https://doi.org/10.1002/aic.690250610
  8. Gordon S, and McBride BJ., "Computer program for calculation of complex chemical equilibrium compositions and application; I. Analysis", NASA, 1994.
  9. McBride BJ, Zehe MJ, and Gordon S., "NASA Glenn Coefficients for Calculating Thermodynamic Properties of Individual Species", NASA, 2002.
  10. NIST-JANAF Thermochemical Tables, NIST, 2013.