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Spectral characteristics of minerals associated with skarn deposits: a case study of Weondong skarn deposit, South Korea

  • Jeong, Yongsik (Department of Astronomy, Space Science and Geology, Chungnam National University) ;
  • Yu, Jaehyung (Department of Geology and Earth Environmental Sciences, Chungnam National University) ;
  • Koh, Sang-Mo (Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources) ;
  • Heo, Chul-Ho (Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources) ;
  • Lee, Jeonga (Department of Astronomical Science and Geology, Chungnam National University)
  • Received : 2015.05.23
  • Accepted : 2015.07.06
  • Published : 2016.04.01

Abstract

This study examined the spectral characteristics of minerals occurring at Weondong skarn deposit located in South Korea and assessed the effectiveness of VNIR-SWIR spectroscopic approaches in zone definition characterizing skarn deposits based on XRD, XRF, and petrographic studies. The spectroscopic analyses identified intrusive rock, garnet-clinopyroxene skarn, clinopyroxene-garnet skarn, W-ore, and host rock zones. The assessment results for VNIR-SWIR spectroscopy in skarn exploration illustrated that the spectral approaches would be very useful for attaining skarn mineral information such as calcite, chlorite, clinopyroxene, garnet, scapolite, vesuvianite, and wollastonite and clay minerals. Furthermore, the rock-forming minerals such as K-feldspar, plagioclase, quartz, fluorite, and tungsten-bearing minerals like scheelite may require supplementary mineral analysis. A combined analysis of spectrometry, XRD, XRF, UV lamp scanning, and petrographic studies reveals that the skarn mineralization of the study area related to W mineral of the study core is defined as proximal endoskarn to proximal exoskarn, which could be defined by spectroscopic approaches.

Keywords

Acknowledgement

Supported by : National Research Foundation of Korea

References

  1. Aboelkhair, H., Ninomiya, Y., Watanabe, Y., and Sato, I., 2010, Processing and interpretation of ASTER TIR data for mapping of rare-metal-enriched albite granitoids in the Central Eastern Desert of Egypt. Journal of African Earth Sciences, 58, 141-151. https://doi.org/10.1016/j.jafrearsci.2010.01.007
  2. Bladridge, A.M., Hook, S.J., Grove, C.I., and Rivera, G., 2009, The ASTER spectral library version 2.0. Remote Sensing of Environment, 113, 711-715. http://speclib.jpl.nasa.gov https://doi.org/10.1016/j.rse.2008.11.007
  3. Chi, S.J., Kang, I.-M., Kim, Y.U., Kim, E.-J., Kim, I.J., Park, S,-W., Lee, J.H., Lee, J.S., Lee, H.Y., Jin, K.M., Heo, C.-H., and Hong, Y.-K., 2011, Evaluation of development possibility for the security of industrial mineral resources (Cu, Pb, Zn, Au etc.) on the domestic mines. GP2010-024-2011(2), Korea Institute of Geoscience and Mineral Resources (KIGAM), Daejeon, 33-216 p.
  4. Chi, S.J., Kang, I.-M., Kim, E.-J., Kim, I.J., Park, S,-W., Lee, J.H., Lee, H.Y., Jin, K.M., Heo, C.-H., Hong, Y.-K., and Lee, J.S., 2012, Evaluation of development possibility for the security of industrial mineral resources (Cu, Pb, Zn, Au etc.) on the domestic mines. GP2010-024-2012(3), Korea Institute of Geoscience and Mineral Resources (KIGAM), Daejeon, 27-88 p.
  5. Clark, R.N., 1999, Chapter 1: Spectroscopy of Rocks and Minerals, and Principles of Spectroscopy. In: Rencz, A.N. (ed.), Manual of Remote Sensing, Volume 3, Remote Sensing for the Earth Sciences. John Wiley and Sons, New York, p. 3-58.
  6. Clark, R.N., Swayze, G.A., Wise, R., Livo, E., Hoefen, T., Kokaly, R., and Sutley, S.J., 2007, USGS digital spectral library splib06a: U.S. Geological Survey, Digital Data Series, 231 p. http://speclab.cr.usgs.gov/spectral.lib06
  7. Hauff, P.L., 2008, An overview of VIS-NIR-SWIR field spectroscopy as applied to precious metals exploration. Spectral International Inc., 80001, 303-403.
  8. Herrmann, W., Blacke, M., and Doyle, M., 2001, Short wavelength infrared (SWIR) spectral analysis of hydrothermal alteration zones associated with based metal sulfide deposits at Rosebery and Western Tharsis, Tasmania, and Highway-Reward, Queensland. Economic Geology, 96, 939-955.
  9. Hinchey, J.G., 2011, Visible/infrared spectroscopy (VIRS) of volcanogenic massive sulfide hydrothermal alteration products, Tulks volcanic belt, Central NewFoundland: An additional exploration technique? Geological Survey, Report, 11-1, 97-108.
  10. Hwang, D.H., 1997, Metallogeny, Geochemistry and mineral exploration of Wondong mine area in Taebaegsan mineralized province, Korea. Ph.D. Thesis, Kyungpook National University, Daegu, 282 p. (in Korean with English abstract)
  11. Hwang, D.H. and Lee, J.Y., 1998, Ore genesis of the Wondong polymetallic mineral deposits in the Taebaegsan metallogenic province. Economic and Environmental Geology, 31, 375-388. (in Korean with English abstract)
  12. Jeong, Y.S., Yu, J.H., Koh, J.-M., and Heo, C.-H., 2014, Spectroscopy of skarn in Dangdu Pb-Zn deposit and assessment of skarn exploration approaches employing portable spectrometer. Journal of Mineralogical Society of Korea, 27, 135-147. (in Korean with English abstract) https://doi.org/10.9727/jmsk.2014.27.3.135
  13. Kerr, A., Rafuse, H., Sparkes, G., Hinchey, J., and Sandeman, H., 2011, Visible/infrared spectroscopy (VIRS) as a research tool in economic geology: background and pilot studies from NewFoundland and Labrador. Geological Survey, Report, 11-1, 145-166.
  14. Lee, J.-H., 2011, The results of drilling in Weondong mine area, the Taebaegsan mineralized district, Republic of Korea. Economic and Environmental Geology, 44, 313-320. (in Korean with English abstract) https://doi.org/10.9719/EEG.2011.44.4.313
  15. Meinert, L.D., Dipple, G.M., and Nicolescu, S., 2005, World skarn deposits. In: Hedenquist, J.W., Thompson, J.F.H., Goldfarb, R.J., and Richards, J.P. (eds.), Economic Geology 100th Anniversary Volume. Society of Economic Geologists, Littleton, p. 299-336.
  16. Ninomiya, Y., 2002, Mapping quartz, carbonate minerals, and maficultramafic rocks using remotely sensed multispectral thermal infrared ASTER data. Proceedings of SPIE 4710, Thermosense XXIV, 191 (March 15, 2002). doi:10.1117/12.459566
  17. Ninomiya, Y. and Fu, B., 2002, Quartz Index, Carbonate Index and $SiO_2$ Content Index Defined for ASTER TIR Data. Journal of Remote Sensing Society of Japan, 22, 50-61.
  18. Ninomiya, Y., 2003a, Rock type mapping with indices defined for multispectral thermal infrared ASTER data: case studies. Remote Sensing for Environmental Monitoring, GIS Applications, and Geology II, SPIE, 4886, 123-132.
  19. Ninomiya, Y., 2003b, Advanced remote lithologic mapping in ophiolite zone with ASTER multispectral thermal infrared data. Proceedings of the International Geoscience and Remote Sensing Symposium, 3, 1561-1563.
  20. Ninomiya, Y. and Fu, B., 2010, Regional scale lithologic mapping in western Tibet using ASTER thermal infrared multispectral data. International Archives of the Photogrammetry, Remote Sensing and Spatial Information Science, 38, 454-458.
  21. Park, C.Y., Song, Y.G., Chi, S.J., Kang, I.M., Yi, K.W., and Chung, D.H., 2013, U-Pb(SHRIMP) and K-Ar age dating of intrusive rocks and skarn minerals at the W-skarn in Weondong deposit. Journal of Mineralogical Society of Korea, 26, 161-174. (in Korean with English Abstract) https://doi.org/10.9727/jmsk.2013.26.3.161
  22. Pontual, S., Gamson, P., and Merry, N., 2012, Spectral interpretation field manual: Spectral Analysis Guides for Mineral Exploration, G-Mex Version 3.0. Ausspec International Propriety Limited, Australia, Vol. 1, 191 p.
  23. Rowan, L.C. and Mars, J.C., 2003, Lithologic mapping in the Mountain Pass, California area using advanced spaceborne thermal emission and reflection radiometer (ASTER) data. Remote sensing of Environment, 84, 350-366. https://doi.org/10.1016/S0034-4257(02)00127-X
  24. Son, Y.S., Kang, M.K., and Yoon, W.J., 2014, Lithological and mineralogical survey of the Oyu Tolgoi region, Southeastern Gobi, Mongolia using ASTER reflectance and emissivity data. International Journal of Applied Earth Observation and Geoinformation, 26, 205-216. https://doi.org/10.1016/j.jag.2013.07.004
  25. Sonntag, I., Laukamp, C., and Hagemann, S.G., 2012, Low potassium hydrothermal alteration in low sulfidation epithermal systems as detected by IRS and XRD: An example from the Co-O mine, Eastern Mindanao, Philippines. Ore Geology Reviews. 45, 47-60. https://doi.org/10.1016/j.oregeorev.2011.08.001
  26. Merry, N., Pontual, S., and Gamson, P., 1999, The Spectral Geologist "TSG" v 2.0 user manual. AusSpecInternational Pty. Ltd. 136 p.
  27. Sun, Y., Seccombe, P.K., and Yang, K., 2001, Application of shortwave infrared spectroscopy to define alteration zones associated with the Elura zinc-lead-silver deposit, NSW, Australia. Journal of Geochemical Exploration, 73, 11-26. https://doi.org/10.1016/S0375-6742(01)00167-4
  28. Thompson, A.J.B., Hauff, P.L., and Robitaille, A.J., 1999, Alteration mapping in exploration: application of short-wave infrared (SWIR) spectroscopy. Society of Economic Geology Newsletter, 39, 16-27.
  29. Whitney, D.L. and Evans, B.W., 2010, Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 184-187.
  30. Yang, K., Huntington, J.F., Browne, P.R.L., and Ma, C., 2000, An infrared spectral reflectance study of hydrothermal alteration minerals from the Te Mihi sector of the Wairakei geothermal system, New Zealand. Geothermics, 29, 377-392. https://doi.org/10.1016/S0375-6505(00)00004-3
  31. Yang, K., Browne, P.R.L., Huntington, J.F., and Walshe, J.L., 2001, Characterising the hydrothermal alteration of the Broadlands-Ohaaki geothermal system, New Zealand, using short-wave infrared spectroscopy. Journal of Volcanology and Geothermal Research, 106, 53-65. https://doi.org/10.1016/S0377-0273(00)00264-X
  32. Zadeh, M.H., Tangestani, M.H., Roldan, F.V., and Yusta, I., 2014, Spectral characteristics of minerals in alteration zones associated with porphyry copper deposits in the middle part of Kerman copper belt, SE Iran. Ore Geology Reviews, 62, 191-198. https://doi.org/10.1016/j.oregeorev.2014.03.013

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